The Two-Point Function and the Effective Magnetic Field in Diluted Ising Models on the Cayley Tree

Some results on the two-point function and on the analytic structure of the momenta of the effective fugacity at the origin for a class of diluted ferromagnetic Ising models on the Cayley tree are presented.Comment: 22 page

Aspects of Two-Level Systems under External Time Dependent Fields

The dynamics of two-level systems in time-dependent backgrounds is under consideration. We present some new exact solutions in special backgrounds decaying in time. On the other hand, following ideas of Feynman, Vernon and Hellwarth, we discuss in detail the possibility to reduce the quantum dynamics to a classical Hamiltonian system. This, in particular, opens the possibility to directly apply powerful methods of classical mechanics (e.g. KAM methods) to study the quantum system. Following such an approach, we draw conclusions of relevance for ``quantum chaos'' when the external background is periodic or quasi-periodic in time.Comment: To appear in J. Phys. A. Mathematical and Genera

Cooperative effects in the detection of a nitroaliphatic liquid explosive and na explosive taggant in the vapor phase by calix[4]arene-based carbazole-containing conjugated polymers

Two fluorescent molecular receptor based conjugated polymers were used in the detection of a nitroaliphatic liquid explosive (nitromethane) and an explosive taggant (2,3-dimethyl-2,3-dinitrobutane) in the vapor phase. Results have shown that thin films of both polymers display remarkably high sensitivity and selectivity toward these analytes. Very fast, reproducible, and reversible responses were found. The unique behavior of these supramolecular host systems is ascribed to cooperativity effects developed between the calix[4] arene hosts and the phenylene ethynylene-carbazolylene main chains. The calix[4]-arene hosts create a plethora of host-guest binding sites along the polymer backbone, either in their bowl-shaped cavities or between the outer walls of the cavity, to direct guests to the area of the transduction centers (main chain) at which favorable photoinduced electron transfer to the guest molecules occurs and leads to the observed fluorescence quenching. The high tridimensional porous nature of the polymers imparted by the bis-calixarene moieties concomitantly allows fast diffusion of guest molecules into the polymer thin films

Comparative phylogeography of northwest African Natrix maura (Serpentes: Colubridae) inferred from mtDNA sequences

While the comparative phylogeography of European fauna is relatively well understood, with Pleistocene climatic oscillations leading to ‘southern refugia’ for many species, the equivalent pattern has not been determined for North Africa. In this context variation within North African populations of the riverine snake Natrix maura were assessed using mitochondrial DNA sequences. Recent literature regarding North African phylogeographic studies of reptiles was compiled, and several surprising patterns emerged. The most interesting was the extensive movement of species across the Strait of Gibraltar during the Pleistocene. Another is the general pattern of deep genetic divergences between Tunisian and Moroccan populations, often at a level implying the existence of cryptic species. Natrix maura has three distinct lineages in North Africa, however, it apparently did not cross the Strait of Gibraltar during the Pleistocene, but probably did so during the Messinian salinity crisis

Necrotizing Fasciitis and Middle Ear Infection

A fasceíte necrosante (FN) é uma doença rara em pediatria. Na maior parte dos casos surge como complicação de varicela, sendo a pele habitualmente a porta de entrada e o Streptococcus pyogenes o agente mais frequente. Os autores descrevem um caso clínico de uma criança de 8 anos, previamente saudável que, no contexto de uma otite média aguda medicada com um anti-inflamatório não esteróide (AINE), desenvolve uma infecção invasiva a Streptococcus 13 hemoliticus do grupo A

Inherently chiral calix[4]arenes with planar chirality: two new entries to the family

The synthesis of two new inherently chiral calix[4]arenes (ICCs, 1 and 2), endowed with electron-rich concave surfaces, has been achieved through the desymmetrization of a lower rim distal-bridged oxacyclophane (OCP) macrocycle. The new highly emissive ICCs were resolved by chiral HPLC, and the enantiomeric nature of the isolated antipodes proved by electronic circular dichroism (CD). Using time-dependent density functional calculations of CD spectra, their absolute configurations were established. NMR studies with (S)-Pirkle's alcohol unequivocally showed that the host-guest interactions occur in the chiral pocket comprehending the calix-OCP exo cavities and the carbazole moieties

Therapeutic Approach to Parapneumonic Effusions and Empyemas

Face à inexistência de uma metodologia única e consensual na abordagem terapêutica dos derrames pleurais parapneumónicos e empiemas, os autores propõem um protocolo de orientação, que resultou da reflexão baseada na sua experiência e na bibliografia mais recente

Right Cardiac Intracavitary Metastases from a Primary Intracranial Myxofibrosarcoma

Primary intracranial myxofibrosarcoma is exceedingly rare, with less than 10 cases published. We present a case of a 23-year-old man with previous history of a primary low grade myxofibrosarcoma of the left parietal-occipital convexity resected in March 1999. He subsequently underwent several interventions for multiple local recurrent disease until March 2004. At that time, complete remission was documented. About 8 years later, in February 2012, the patient was admitted to the emergency room with refractory acute pulmonary oedema. On work up, sustained monomorphic ventricular tachycardia and hyperechoic myocardial mass with invasion of the right ventricular cavity were detected. Electrical cardioversion was unsuccessful and irreversible cardiac arrest followed. The autopsy confirmed multiple bilateral lung metastases, malignant pulmonary embolism and myocardial invasion by the primary tumour, with intracavitary cardiac thrombosis and absence of intracranial disease. To the best of our knowledge, this is the first report of extracranial metastases of this neoplasm.info:eu-repo/semantics/publishedVersio

Nonlethal, Attenuated, Transfusion-Associated Graft-Versus-Host Disease in an Immunocompromised Child: Case Report and Review of the Literature

Transfusion-associated graft-versus-host disease (TA-GVHD) is a rare complication of transfusion of nonirradiated blood components. It usually affects children in high-risk groups, including those who have primary immunodeficiencies (PIDs). It usually presents with skin, hepatic, digestive, and hematologic involvement and is normally fatal