High temperature behavior of Sr-doped layered cobaltites Y(Ba1-xSrx)Co2O5.5: phase stability and structural properties

In this article we present a neutron diffraction in-situ study of the thermal evolution and high-temperature structure of layered cobaltites Y(Ba, Sr)Co2 O5+{\delta}. Neutron thermodiffractograms and magnetic susceptibility measurements are reported in the temperature range 20 K <= T <= 570 K, as well as high resolution neutron diffraction experiments at selected temperatures. Starting from the as-synthesized samples with {\delta} ~ 0.5, we show that the room temperature phases remain stable up to 550 K, where they start loosing oxygen and transform to a vacancy-disordered "112" structure with tetragonal symmetry. Our results also show how the so-called "122" structure can be stabilized at high temperature (around 450 K) in a sample in which the addition of Sr at the Ba site had suppressed its formation. In addition, we present the structural and magnetic properties of the resulting samples with a new oxygen content {\delta} ~ 0.25 in the temperature range 20 K <= T <= 300 K

Rural Roads: The Challenge of Decentralized Implementation

This paper will review the key elements required for effective decentralized implementation of rural roads programs. It will review the range of options available and the evidence for successful implementation where it exists. Section 2 makes the case for the importance of rural roads and sets out the evidence for the socio-economic benefits. Section 3 addresses the responsibilities for implementation and critical importance of having clarity over network ownership. Section 4 highlights the difficulties of finance, particularly for longer term maintenance, and sets out options for improving allocations and the reliability of receipt for those allocations. Section 5 sets out the project cycle from planning, design, implementation, maintenance and subsequent evaluation. Section 6 summarizes the key issues and highlights the main policy considerations

Substitution site and effects on magnetism in Sr-for-Ca substituted CaBaCo4O7

Under a Creative Commons Attribution (CC BY) license.-- et al.Cationic substitutions in the novel magnetoelectric compound CaBaCo4O7 lead to profound changes in its magnetic and electric behaviors. In this work, we present a structural study of the isovalent substitution Sr-for-Ca in CaBaCo4O7. X-ray diffraction, as well as neutron powder diffraction experiments, are reported for a series of samples Ca1- xSrxBaCo4O7 with 0 ≤ x ≤ 0.10. Special emphasis is given to the identification of the substitution site, as Sr has also been reported to substitute for Ba in this crystal structure. The solubility limit for Sr at the Ca site is shown to be at x ≃ 0.08. The variation of lattice constants with Sr-doping firmly supports the Sr-for-Ca substitution. Rietveld refinements of the Sr-substituted samples are presented, and used as starting point to analyse the local structure around Sr by means of X-ray absorption spectroscopy at the Sr K-edge. Both the near-edge absorption and the extended absorption fine-structure confirm the substitution of Sr for Ca, giving definite support to the proposed nominal formula. In addition, macroscopic magnetization measurements are presented which reveal the striking effects of Sr-substitution over the magnetic landscape of this puzzling compound.This work is part of a research project supported by Agencia Nacional de Promoción Científica y Tecnológica (Argentina), under Grant No. PICT-2011-0752, CONICET under Grant No. PIP 490 2012-2014, and Universidad Nacional de Cuyo. We acknowledge Soleil synchrotron for the beamtime allocation and the MinCyT-Soleil collaboration project for the financial support. We also acknowledge ILL and its staff for the beamtime allocation and technical assistance as well as the MinCyT of Argentina for funding the trip to perform the experiments. G.A. and J.C. thank the CONICET-CSIC program for scientific visits and Grant No. MAT2011-27233-C02-02.Peer Reviewe

Probing phase coexistence and stabilization of the spin-ordered ferrimagnetic state by Calcium addition in the YBa_{1-x}Ca_{x}Co_{2}O_{5.5} layered cobaltites using neutron diffraction

In this article we study the effects of a partial substitution of Ba with the smaller cation Ca in the layered cobaltites YBaCo_2O_{5+\delta} for \delta \approx 0.5. Neutron thermodiffractograms are reported for the compounds YBa_{0.95}Ca_{0.05}Co_2O_{5.5} (x_{Ca}=0.05) and YBa_{0.90}Ca_{0.10}Co_2O_{5.5} (x_{Ca}=0.10) in the temperature range 20 K \leq T \leq 300 K, as well as high resolution neutron diffraction experiments at selected temperatures for the samples x_{Ca}=0.05, x_{Ca}=0.10 and the parent compound x_{Ca}=0. We have found the magnetic properties to be strongly affected by the cationic substitution. Although the "122" perovskite structure seems unaffected by Ca addition, the magnetic arrangements of Co ions are drastically modified: the antiferromagnetic (AFM) long-range order is destroyed, and a ferrimagnetic phase with spin state order is stabilized below T \sim 290 K. For the sample with x_{Ca}=0.05 a fraction of AFM phase coexists with the ferrimagnetic one below T \sim 190 K, whereas for x_{Ca}=0.10 the AFM order is completely lost. The systematic refinement of the whole series has allowed for a better understanding of the observed low-temperature diffraction patterns of the parent compound, YBaCo_2O_{5.5}, which had not yet been clarified. A two-phase scenario is proposed for the x_{Ca}=0 compound which is compatible with the phase coexistence observed in the x_{Ca}=0.05 sample

The colour and golden shine of early silver Islamic lustre

A selection of lustres including 9th century AD polychrome and 10th century AD monochrome Abbasid lustres from Iraq, and 10th to 12th centuries AD Fatimid lustres from Egypt and Syria is studied in the present paper. The selection is based on previous studies that demonstrated that all of them contain metal silver nanoparticles and copper, which, when present, appears either as Cuþ or Cu2þ dissolved in the glaze. They show different colours, green, yellow, amber, and brown, and may also show or lack a golden-like reflectivity, which results mainly from average size and concentration in the layer of the silver nanoparticles. In this paper, a depth profile composition of the lustre layers is determined using Rutheford Backscattering Spectroscopy, allowing the determination of the total silver content, concentration of silver, copper to silver ratio, and thickness of the lustre layers. We show that the enhanced golden-like reflectivity occurs only for layers with a high concentration of silver, and that the addition of PbO to the alkaline glaze helps the formation of more concentrated layers. The results obtained provide new hints concerning the lead enrichment of the glazes during this period.Peer ReviewedPostprint (published version

New multifunctional sulfonato-containing metal phosphonates proton conductors

Anchoring of acidic functional groups to organic linkers acting as ligands in metal phosphonates has been demonstrate to be a valid strategy to develop new proton conductor materials, which exhibit tunable properties and are potentially applicable to proton exchange membranes, such as those used in PEMFCs [1,2]. In this work, the structural and proton conductivity properties of several families of divalent and trivalent metal amino-sulfophosphonates are presented. The chosen ligand, (H2O3PCH2)2-N-(CH2)2-SO3H, was reacted with the appropriate metal salt using highthrough-put screening and/or microwave-assisted synthesis. Different crystal structures haven been solved displaying a variety of metal ligand coordination modes, in whose frameworks acidic groups contribute to create strong H-bond networks; together with lattice and bound water molecules. Proton conductivity values oscillate between 10-4 and 10-2 S.cm-1, at 80 ºC and 95 % relative humidity, most of them showing activation energies characteristic of a Grotthuss-type proton transport mechanism.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. MINECO: MAT2016-77648-R Junta de Andalucía: P-12-FQM-1656 y FQM-11

Alcuni esempi di catalogazione e restauro nell’ambito della Collezione Storica degli Strumenti di Fisica dell’Università di Palermo

In questo articolo presenteremo e discuteremo della catalogazione e restauro e di alcuni strumenti scientifici di particolare interesse storico-didattico appartenenti alla Collezione Storica degli Strumenti di Fisica dell’Università di Palermo. La catalogazione è stata effettuata secondo le indicazioni fornite dell’Istituto Centrale per il Catalogo e la Documentazione, per mezzo della scheda per il patrimonio scientifico-tecnologico. Nell’articolo saranno discussi gli aspetti tecnici degli interventi di restauro effettuati e saranno indicate le linee guida generali per il proseguimento dell’attività avviata.The article deals with the cataloguing and restoration of some scientific instruments of particular historical and didactic interest belonging to the Historical Collection of the Physics Instruments of the University of Palermo. The restoration activities have been carried out side by side the cataloguing, which has been done following the instructions supplied by the Central Institute for Cataloguing and Documentation with the official form for the scientific and technological heritage. In the article, we will discuss the technical aspects of the work carried out and basic guidelines will be given for the continuation of the activity

Desarrollo de un espectrofotómetro de campo para su aplicación en un programa de mejora genética

Se ha desarrollado un espectrofotómetro de campo para uso en programas de mejora del olivo en el marco de un proyecto INIA en el que trabajan conjuntamente el LPFTAG y el IFAPA de Córdoba. La robustez de los modelos en la configuración portátil es muy dependiente del número de variables latentes seleccionadas mediante modelos PLS. Se evalúa el procedimiento PDS de transferencia de calibración para mantener en uso las bases de datos acumuladas con un equipo de sobremesa a lo largo de los últimos cinco años

Proton conductivity and luminiscence properties of lanthanide aminotriphosphonates

Metal phosphonates are multifunctional solids with tunable properties, such as internal H-bond networks, and high chemical and thermal stability [1]. In the present work, we describe the synthesis, structural characterization, luminescent properties and proton conduction performance of a new family of isostructural cationic compounds with general formula [Ln(H4NMP)(H2O)2]Cl·2H2O [Ln = La3+, Pr3+, Sm3+, Gd3+, Tb3+, Dy3+, Ho3+, H6NMP = nitrilotris(methylphosphonic acid)]. These solids are formed by positively charge layers, which consist of isolated LnO8 polyhedra and bridge chelating NMP2- ligands, held apart by chloride ions and water molecules. This arrangement result in extended interlayer hydrogen networks with possible proton transfer pathways. The proton conductivity of Gd3+ sample, selected as prototype of the series, was measured. In the range between range 25º and 80 ºC, the conductivity increase with the temperature up to a maximum value of 3.10-4 S·cm-1, at relative humidity of 95 %. The activation energy obtained from the Arrhenius plot (Figure 1) is in the range corresponding to a Grotthuss transfer mechanism.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. FQM-1656; MAT2013-41836-R