Upper Paleozoic Dikes of the Marão Mountain (Northern Portugal); results of intra orogenic Extension?

[Abstract] In the Marão mountain occur hercynian mafic veins cutting the Schistose Formation of the Landeilian age. The geochemistry of these rocks present high concentrations on Ti ,P, Zr, Nb, Ba, and REE (Ti O2= 1.23-1,39 %, P2O5= 1.32-1,60 %, Zr = 565-641 ppm, Nb= 33-46 ppm, Ba = 2531-3219 ppm, ΣREE = 295-430 ppm) and indicate significant REE fractionation (CeN/ Y bN= 10.46) similar to that reported for alkaline mafic rocks. These characteristics and their patterns in THOMPSON (1984) diagram are typical of alkaline rocks. The dikes intrusion occurred in a late stage of the tectonic evolution of the Centro-Iberian autochthon prior to the granitic magmatic phase. Their intrusion was facilitated, either by the reorientation of the stress field due to the emplacement of the NW Iberian nappe complex or local extensions common in transpressive regimes. This geodynamical context could produce the generation of alkaline magmatism due to partial melting of the upper mantle, induced by adiabatical decompression in the major crustal NW-SE shear zones

Early evolution of a stratospheric volcanic eruption cloud as observed with TOMS and AVHRR

This paper is a detailed study of remote sensing data from the total ozone mapping spectrometer (TOMS) and the advanced very high resolution radiometer (AVHRR) satellite detectors, of the 1982 eruption of El Chichón, Mexico. The volcanic cloud/atmosphere interactions in the first four days of this eruption were investigated by combining ultraviolet retrievals to estimate the mass of sulfur dioxide in the volcanic cloud [Krueger et al., 1995] with thermal infrared retrievals of the size, optical depth, and mass of fine-grained (1–10 μm radius) volcanic ash [Wen and Rose, 1994]. Our study provides the first direct evidence of gravitational separation of ash from a stratospheric, gas-rich, plinian eruption column and documents the marked differences in residence times of volcanic ash and sulfur dioxide in volcanic clouds. The eruption column reached as high as 32 km [Carey and Sigurdsson, 1986] and was injected into an atmosphere with a strong wind shear, which allowed for an observation of the separation of sulfur dioxide and volcanic ash. The upper, more sulfur dioxide-rich part of the cloud was transported to the west in the stratosphere, while the fine-grained ash traveled to the south in the troposphere. The mass of sulfur dioxide released was estimated at 7.1 × 109 kg with the mass decreasing by approximately 4% 1 day after the peak. The mass of fine-grained volcanic ash detected was estimated at 6.5 × 109 kg, amounting to about 0.7% of the estimated mass of the ash which fell out in the mapped ash blanket close to the volcano. Over the following days, 98% of this remaining fine ash was removed from the volcanic cloud, and the effective radius of ash in the volcanic cloud decreased from about 8 μm to about 4 μm

Illuminating Polysulfide Distribution in Lithium Sulfur Batteries; Tracking Polysulfide Shuttle Using Operando Optical Fluorescence Microscopy

High-energy-density lithium sulfur (Li–S) batteries suffer heavily from the polysulfide shuttle effect, a result of the dissolution and transport of intermediate polysulfides from the cathode, into the electrolyte, and onto the anode, leading to rapid cell degradation. If this primary mechanism of cell failure is to be overcome, the distribution, dynamics, and degree of polysulfide transport must first be understood in depth. In this work, operando optical fluorescence microscope imaging of optically accessible Li–S cells is shown to enable real-time qualitative visualization of the spatial distribution of lithium polysulfides, both within the electrolyte and porous cathode. Quantitative determinations of spatial concentration are also possible at a low enough concentration. The distribution throughout cycling is monitored, including direct observation of polysulfide shuttling to the anode and consequent dendrite formation. This was enabled through the optimization of a selective fluorescent dye, verified to fluoresce proportionally with concentration of polysulfides within Li–S cells. This ability to directly and conveniently track the spatial distribution of soluble polysulfide intermediates in Li–S battery electrolytes, while the cell operates, has the potential to have a widespread impact across the field, for example, by enabling the influence of a variety of polysulfide mitigation strategies to be assessed and optimized, including in this work the LiNO3 additive

Law, Liberty and the Rule of Law (in a Constitutional Democracy)

In the hunt for a better--and more substantial--awareness of the “law,” The author intends to analyze the different notions related to the “rule of law” and to criticize the conceptions that equate it either to the sum of “law” and “rule” or to the formal assertion that “law rules,” regardless of its relationship to certain principles, including both “negative” and “positive” liberties. Instead, he pretends to scrutinize the principles of the “rule of law,” in general, and in a “constitutional democracy,” in particular, to conclude that the tendency to reduce the “democratic principle” to the “majority rule” (or “majority principle”), i.e. to whatever pleases the majority, as part of the “positive liberty,” is contrary both to the “negative liberty” and to the “rule of law” itself

Targeting β-catenin in acute myeloid leukaemia: past, present, and future perspectives

Acute myeloid leukaemia (AML) is an aggressive disease of the bone marrow with a poor prognosis. Evidence suggests long established chemotherapeutic regimens used to treat AML are reaching the limits of their efficacy, necessitating the urgent development of novel targeted therapies. Canonical Wnt signalling is an evolutionary conserved cascade heavily implicated in normal developmental and disease processes in humans. For over 15 years it's been known that the central mediator of this pathway, β-catenin, is dysregulated in AML promoting the emergence, maintenance, and drug resistance of leukaemia stem cells (LSC). Yet, despite this knowledge, and subsequent studies demonstrating the therapeutic potential of targeting Wnt activity in haematological cancers, β-catenin inhibitors have not yet reached the clinic. The aim of this review is to summarise the current understanding regarding the role and mechanistic dysregulation of β-catenin in AML and assess the therapeutic merit of pharmacologically targeting this molecule, drawing on lessons from other disease contexts

Community resilience to climate change: an evidence review

How is the resilience of communities to climate change in the UK currently understood and practised? The concept of community resilience to climate change in the UK has a diverse range of meanings and associated activities. This review of evidence and practice explores this varied and contested field to build the evidence base and help support the development of community resilience to climate change

Life satisfaction and confidence in national institutions: evidence from South America

A number of South American countries experienced turbulent democratic, political and economic upheaval over the last 40 years in the form of coup d’états in the 1970s, tumultuous elections, and repeated severe economic crises, some of which happened fairly recently. Starting in 2010, a number of court proceedings across the region have made past military coup d’états the focus of national conversations. South American citizens may, therefore, have lost confidence in national institutions that have repeatedly disappointed their trust and expectations; a situation with potentially detrimental effects on their well-being. Using eight waves of the Gallup World Poll collected between 2009 and 2016 across ten South American countries, we investigate to what extent people’s confidence in financial institutions, the honesty of elections, the military, the judicial system, the national government and the police is associated with people’s current and expectation of future life satisfaction. We find that people who report confidence in these six institutions rate their current and expected life satisfaction, on average, to be higher than those who lack these types of institutional confidence, even after controlling for demographic factors and macroeconomic indicators. In addition, we investigate changes over time for all six measures of confidence in institutions as well as for current and expectation of future life satisfaction. Our results suggest that governments’ investments in well-functioning institutions may contribute positively to subjective well-being in a society. However, our analysis is correlational and we thus cannot rule out reverse causality

A high-resolution versatile focused ion implantation platform for nanoscale engineering

The ability to spatially control and modify material properties on the nanoscale, including within nanoscale objects themselves, is a fundamental requirement for the development of advanced nanotechnologies. The development of a platform for nanoscale advanced materials engineering (P-NAME) designed to meet this demand is demonstrated. P-NAME delivers a high-resolution focused ion beam system with a coincident scanning electron microscope and secondary electron detection of single-ion implantation events. The isotopic mass-resolution capability of the P-NAME system for a wide range of ion species is demonstrated, offering access to the implantation of isotopes that are vital for nanomaterials engineering and nanofunctionalization. The performance of the isotopic mass selection is independently validated using secondary ion mass spectrometry (SIMS) for a number of species implanted into intrinsic silicon. The SIMS results are shown to be in good agreement with dynamic ion implantation simulations, demonstrating the validity of this simulation approach. The wider performance capabilities of P-NAME, including sub-10 nm ion beam imaging resolution and the ability to perform direct-write ion beam doping and nanoscale ion lithography, are also demonstrated

The national inventory of geological heritage: methodological approach and results

A existência de um inventário nacional de património geológico é fundamental para se poderem implementar estratégias de geoconservação. Este trabalho apresenta a metodologia usada no desenvolvimento do mais completo inventário de geossítios, realizado até ao momento em Portugal, assim como os principais resultados obtidos. O inventário vai integrar o Sistema de Informação do Património Natural e o Cadastro Nacional dos Valores Naturais Classificados, ambos geridos pelo Instituto de Conservação da Natureza e da Biodiversidade.The existence of a national inventory of the geological heritage is of paramount importance for the implementation of a geoconservation strategy. This paper presents the methodological approach used to produce the most complete geosites inventory in Portugal, so far, and the obtained results. This inventory will be uploaded into the National Database of Natural Heritage managed by the Portuguese authority for nature conservation.Este trabalho é apoiado pela Fundação para a Ciência e a Tecnologia, através do financiamento plurianual do CGUP e do projecto de investigação “Identificação, caracterização e conservação do património geológico: uma estratégia de geoconservação para Portugal” (PTDC/CTE-GEX/64966/2006).info:eu-repo/semantics/publishedVersio