Redox-active ferrocene-modified Cowpea mosaic virus nanoparticles

A naturally occurring nanoparticle, the plant virus Cowpea mosaic virus, can be decorated with ferrocene derivatives, of various linker lengths with amine and carboxylategroups, on the external surface using a range of conjugation strategies. The multiple, organometallic, redox-active ferrocene moieties on the outer surface of the virus are electrochemically independent with reduction potentials that span a potential window of 0.16 V that are dependent on the site of modification and the nature of the ferrocene derivative. The number of ferrocenes coupled to each virus ranges from about 100 to 240 depending upon the conjugation site and the linker length and these redox active units can provide multielectron reservoirs

Isolating the photovoltaic junction: atomic layer deposited TiO2-RuO2 alloy Schottky contacts for silicon photoanodes

We synthesized nanoscale TiO2-RuO2 alloys by atomic layer deposition (ALD) that possess a high work function and are highly conductive. As such, they function as good Schottky contacts to extract photogenerated holes from n-type silicon while simultaneously interfacing with water oxidation catalysts. The ratio of TiO2 to RuO2 can be precisely controlled by the number of ALD cycles for each precursor. Increasing the composition above 16% Ru sets the electronic conductivity and the metal work function. No significant Ohmic loss for hole transport is measured as film thickness increases from 3 to 45 nm for alloy compositions >= 16% Ru. Silicon photoanodes with a 2 nm SiO2 layer that are coated by these alloy Schottky contacts having compositions in the range of 13-46% Ru exhibit average photovoltages of 525 mV, with a maximum photovoltage of 570 mV achieved. Depositing TiO2-RuO2 alloys on nSi sets a high effective work function for the Schottky junction with the semiconductor substrate, thus generating a large photovoltage that is isolated from the properties of an overlying oxygen evolution catalyst or protection layer

Potential drilling hazards for wells targeting the Cane Creek shale, Pennsylvanian Paradox Formation, Paradox fold and fault belt, southeastern Utah and southwestern Colorado

The Cane Creek shale of the Pennsylvanian Paradox Formation represents a major target for oil and gas in the Paradox fold and fault belt of the northern Paradox Basin of southeastern Utah and southwestern Colorado. Early exploration and development attempts resulted in blowouts due to unexpected gas-bearing intervals and casing collapses caused by salt flowage in the Paradox Formation. These problems represent some of the types of drilling hazards that could be expected when planning Cane Creek wells. Horizontal drilling first used in the early 1990s changed the Cane Creek shale play from one of mostly drilling failures to a more successful commercial play. Depending on the location, exploratory Cane Creek wells may penetrate a section that ranges in age from Cretaceous through Pennsylvanian. Drilling in the region often encounters a wide variety of lithologies (carbonates, shale, mudstone, sandstone, and evaporites) and associated potential hazards that may include: (1) swelling clays, (2) high porosity-permeability or fractured zones resulting in lost circulation or excessive mudcake buildup, (3) “kicks” due to the influx of reservoir fluid (oil, water, or gas) into the wellbore, (4) uranium-rich zones, (5) washouts, (6) hole deviation, sticking, and other well-integrity problems, (7) chert, and (8) overpressured intervals. In addition, natural carbon dioxide, which flows from the partially human-made Crystal Geyser near some Cane Creek wellsites, represents an unusual drilling hazard if encountered in the northernmost part of the fold and fault belt. Using the lessons learned from the recently completed research well, State 16-2 (renamed the State 16-2LN-CC, API No. 43-019-50089, after the horizontal leg was drilled), and other wells in the region, drilling engineers and operators can better plan for potential hazards when exploring for hydrocarbons in the Cane Creek shale or deeper targets (Mississippian Leadville Limestone and Devonian Elbert Formation) in the fairly remote, relatively sparsely explored Paradox fold and fault belt. The goal is to de-risk wells, lower expenses, and mitigate problems before they occur. The expected results are safer and more successful drilling of wells to the Cane Creek shale and deeper reservoirs ultimately leading to additional commercial hydrocarbon discoveries in the region

Dead Horse Point, Southeastern Utah

The Dead Horse Point geosite, within the state park by the same name, is located in the heart of the Canyonlands region of Utah between Canyonlands and Arches National Parks. The views are spectacular, sublime, awe-inspiring, and majestic, and hard to surpass anywhere on the Colorado Plateau. The mood of the vistas changes by season and time of day. Here, one of nature’s engineers, in this instance the Colorado River and its tributaries, has carved and exposed strata of Late Pennsylvanian (307 million years ago [Ma]) to Early Jurassic (200 Ma) age within just the past 5 million years (figures 2 and 3)

Design principles for maximizing photovoltage in metal-oxide-protected water-splitting photoanodes

Metal oxide protection layers for photoanodes may enable the development of large-scale solar fuel and solar chemical synthesis, but the poor photovoltages often reported so far will severely limit their performance. Here we report a novel observation of photovoltage loss associated with a charge extraction barrier imposed by the protection layer, and, by eliminating it, achieve photovoltages as high as 630mV, the maximum reported so far for water-splitting silicon photoanodes. The loss mechanism is systematically probed in metal-insulator-semiconductor Schottky junction cells compared to buried junction p(+) n cells, revealing the need to maintain a characteristic hole density at the semiconductor/insulator interface. A leaky-capacitor model related to the dielectric properties of the protective oxide explains this loss, achieving excellent agreement with the data. From these findings, we formulate design principles for simultaneous optimization of built-in field, interface quality, and hole extraction to maximize the photovoltage of oxide-protected water-splitting anodes

Green River overlook, Island in the Sky District, Canyonlands National Park, southeastern Utah

The stream is still quiet, and we guide along through a strange, weird, grand region. The landscape everywhere, away from the river, is of rock—cliffs of rock, tables of rock, plateaus of rock, terraces of rock, crags of rock—ten thousand strangely carved forms; rocks everywhere, and no vegetation, no soil, no sand. In long, gentle curves the river winds about these rocks. These are the words Major John Wesley Powell used to describe what is called Stillwater Canyon along the Green River on July 17, 1869, on his way to the Grand Canyon during his famous journey exploring the canyons of the Colorado River and its tributaries (Powell, 1895). This same region is spectacularly displayed from the Green River Overlook in the Island in the Sky District of Canyonlands National Park. The exposed rocks consist of Early Permian- (299 million years ago [Ma]) through Early Jurassic-age (176 Ma) rock layers that were uplifted and subjected to massive erosion. Changes in the color, thickness, and composition of the rock layers and erosive work of running water and gravity (i.e., mass wasting) created the magnificent landscape seen at the overlook today. The primitive and remote Maze District of Canyonlands National Park is the area west of the Green River. Prominent features viewed in the Maze District from the Green River Overlook include Ekker Butte, Turks Head, Elaterite Butte, and the Orange Cliffs (figure 2). On a clear day, the 11,000-foot (3350 m), Henry Mountains, which are cored by volcanic remnants (laccoliths) can be seen to the southwest. The Green River Overlook is one of Utah’s most iconic views, often appearing on book covers, scenic calendars, and postcards, and therefore it is fitting as a geosite for its beauty and the exposures of rocks that so much impressed John Wesley Powell over 150 years ago

Spectacular crinkled crust—A detachment fold train in the Carmel Formation, western San Rafael Swell, Utah

Imagine slipping on a small rug overlying a hardwood floor. In the process of sliding along the floor the rug produces a series of small folds and the rug moves forward from its original position. The same could be said for the “crinkled crust,” or folded layers of rocks in a detachment fold train. A spectacular detachment fold train, consisting of over 100 small, regularly spaced convex-upward folds called anticlines in gypsum-rich rock layers of the Middle Jurassic (about 168 million years ago [Ma]) Carmel Formation, is exposed immediately north of Interstate 70 (I-70) in the San Rafael Swell of east-central Utah (figures 1 and 2). The SanRafael Swell, a large anticlinal uplift, is an icon for everything that makes the Colorado Plateau dramatically scenic and geologically classic. However, the fold train is located in drab-colored, relatively featureless rock layers of the Carmel Formation in an area called Reed Wash along the gently dipping west flank of the Swell. After passing magnificent canyons, buttes, and mesas both to the east and west along I-70, the fold train typically goes unnoticed by not only the average tourist but geologists as well. Once the fold train is pointed out, the geologic observer is immediately struck with awe at this large, well-exposed, complex structural feature. Literally hundreds of classic geologic sites are well displayed in the San Rafael Swell; many are easily accessed overlooks and viewpoints. The detachment fold train, by contrast, is chosen as a geosite for its geologic uniqueness, educational instruction, and research opportunities in structural geology

Ancient delta deposits in the Ivie Creek area, Ferron Sandstone member of the Mancos Shale, western San Rafael Swell, east-central Utah

In contrast to the beautiful array of colorful layers and spectacular cliffs of the Triassic and Jurassic (251 to 148 million years ago [Ma]) sections in the San Rafael Swell of east-central Utah, most of the Upper Cretaceous (96 to 86 Ma) Mancos Shale produces a drab, barren landscape. However, lying within the Mancos, the Ferron Sandstone, is the most studied unit in the San Rafael Swell. The Ferron has world-class outcrops of rock layers deposited near the shorelines of a sinking, fluvial- (stream) dominated delta system. Along the west flank of the San Rafael Swell, the 80-mile-long (130 km) Ferron outcrop belt of cliffs and side canyons (e.g., the Coal Cliffs, Molen Reef, and Limestone Cliffs [not actually limestone, just misnamed]) provides a three-dimensional view of vertical and lateral changes in the Ferron’s rock layers (facies and sequence stratigraphy), and, as such, is an excellent model for fluvial-deltaic oil and gas reservoirs worldwide (e.g., Chidsey and others, 2004)

A Breccia Pipe in the Deseret Limestone, South Flank of the Uinta Mountains, Northern Utah

A breccia pipe is a cylindrical- or irregular-shaped mass of brecciated rock. A breccia consists of broken, angular fragments of rock cemented together by a fine-grained matrix. Hydrothermal breccia pipes form when hydrothermal solutions force their way towards the surface through zones of weakness or fracture zones and naturally break up the rocks in the process, i.e., hydrofracturing; breccia pipes can also form by collapse. Hydrothermal breccia pipes can contain ore deposits and, as will be discussed later, are associated with some large oil and gas accumulations in southeastern Utah