176 research outputs found
Aller simple pour l’Union : Croissance comparée en France, Allemagne et Italie sur la décennie quatre-vingt dix.
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Mosaïque révélé : recueil de variantes et de simulations du modèle Mosaïque.
Cette publication n'a pas de résumé
First insights into the synthesis of carbo-phospholane and carbo-phospholene oxides
Fifteen-membered ring carbo-mers of five-membered rings are considered in the heterocyclic series of the phosphole oxide and less unsaturated parents. The synthesis of the first carbo-phospholane oxides is achieved by a [14+1] two-step/one-pot macrocyclization route with 86 % yield. Reduction of the latter phosphora-[5]pericyclyne with SnClÂ2 allowed consistent 1H and 31P NMR characterization of the corresponding carbo-phospholene, produced with 11 % yield. The ultimate carbo-phosphole oxide could not be isolated, but preliminary results on alternative strategies towards this 14 pz-electron HĂĽckel carbo-aromatic are reported.
France: Fin de l'échappée. Perspectives 2002-2003 pour l'économie française.
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Towards fluorescent indolyl-carbo-benzenes
The C18 macro-aromatic carbo-benzene core is a strong chromophoric unit resembling the porphine ring which is prone to quench the emission of fluorophoric substituents. Within the aim of preparing fluorescent carbo-benzenes (and carbo-cyclohexadiene parents) for measurement of their two-photon absorption cross-section by the TPEF method, several indole derivatives were devised and anchored to the C18 macrocycle either directly, p-phenylogously or ethynylogously. Synthesis methodology and spectroscopical measurements are presented in a comparative prospec
modèle France de l'OFCE. La nouvelle version: e-mod.fr.
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Projections macroéconomiques à moyen et long terme : rapport pour le Conseil d'orientation des retraites.
Cette publication n'a pas de résumé
France : Revoir la croissance Ă la baisse.
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First example of ring carbomer of 1,4-cyclohexadiene
While a series of carbo-mers of 1,3-cyclohexadienes was reported through the use of a specifically developed synthetic strategy, no example of their 1,4-regioisomers was known. Inspired by the methodology elaborated for the preparation of the 1,3-isomers, the synthesis of the first example of carbo-mer of 1,4-cyclohexadiene is presented. Comparison of physico-chemical properties of this first representative with those of the recently described 1,4-regioisomer, especially UV-vis absorption properties, is also addressed
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