Luminescence characteristics of quartz from Brazilian sediments and constraints for OSL dating

This study analyzes the optically stimulated luminescence (OSL) characteristics of quartz grains from fluvial, eolian and shallow marine sands of northeastern and southeastern Brazil, with especial focus on the applicability of the single-aliquot regenerative dose (SAR) dating protocol. All analyzed Brazilian sediments presented relatively high OSL sensitivity and good behavior regarding their luminescence characteristics relevant for radiation dose estimation. However, some samples from the Lençóis Maranhenses region in northeastern Brazil showed inadequate OSL sensitivity correction, hampering the implementation of the SAR protocol and their ability to behave as a natural dosimeter. While the shallow marine and eolian samples showed a narrow and reliable dose distribution, the fluvial sample had a wide dose distribution, suggesting incomplete bleaching and natural doses estimates dependent on age models

Aboveground biomass of a "campina" ecosystem in Roraima, Northern of Brazilian Amazonia

The aboveground biomass of a "campina" ecosystem was estimated in Roraima, in the northern portion of Brazilian Amazonia. The biomass was determined from a phytosociological inventory (1 ha) and distributed between two categories: (1) grassy-woody, composed of "herbs+lichens" (Poaceae, Cyperaceae, Eriocaulaceae, Cladonia spp), Bromeliaceae, seedlings, fine and coarse litter and, (2) woody, composed of trees and bushes. The grassy-woody category was estimated by the direct method (cutting and weighing) in 10 1-m² plots, taking advantage of transects of the inventory. The category woody was estimated by the indirect method cutting 98 individuals of different species and diameters. A model was generated to express the relationship among total dry above-ground biomass (kg), base circumference (cm) and total height (m) for the individuals in this category. The equation was applied to the 3,966 ind.ha-1 observed in the inventory. The total biomass was estimated at 15.91 t.ha-1, of which 2.20 ± 0.23 t.ha-1 (13.8%) was in the grassy-woody category and 13.70 ± 7.13 t.ha-1 (86.2%) in woody category. The tree species with the highest biomass was Humiria balsamifera (Aubl.) St. Hill. (8.43 t.ha-1), followed by Pagamea guianensis Aubl. (1.14 t.ha-1). These results are important for refining the calculations of greenhouse-gas emissions from burning and decomposition of above-ground biomass in "campina" ecosystems in the Amazon region.Foi estimada a biomassa (viva + morta) acima do solo de um ecossistema de "campina" localizado em Roraima, norte da Amazônia brasileira. A biomassa foi determinada a partir de um inventário fitossociológico (1 ha amostral) e distribuída em dois estratos(1) gramíneo-lenhoso, composto de "ervas + liquens" (Poaceae, Cyperaceae, Eriocaulaceae, Cladonia spp), Bromeliaceae, plântulas, "litter" fino e grosso e, (2) arbóreo-arbustivo, composto por árvores e arbustos. O estrato gramíneo-lenhoso foi estimado pelo método direto (corte e pesagem) através de 10 quadras de 1m², aproveitando os transectos do inventário. O estrato arbóreo-arbustivo foi estimado pelo método indireto com o corte de 98 indivíduos de diferentes espécies e diâmetros. Foi gerado um modelo para expressar a relação entre a biomassa seca total (kg), a circunferência de base (cm) e a altura total (m) para os indivíduos deste estrato. A equação foi aplicada nos 3.966 indivíduos.ha-1 observados no inventário. A biomassa total foi estimada em 15,91 t.ha-1, sendo 2,20 ± 0,23 t.ha-1 (13,8%) do estrato gramíneo-lenhoso e 13,70 ± 7,13 t.ha-1 (86,2%) do arbóreo-arbustivo. A espécie arbórea de maior biomassa foi Humiria balsamifera (Aubl.) St. Hill. (8,43 t.ha-1), seguida de Pagamea guianensis Aubl. (1,14 t.ha-1). Estes resultados são importantes para refinar os cálculos de emissão de gases do efeito estufa pela queima e decomposição da biomassa acima do solo em ecossistemas de campinas na Amazônia

KOH activated carbons from Brazil nut shell: Preparation, characterization, and their application in phenol adsorption

Activated carbons named AC105 and AC11 were prepared from Brazil nut shells using the weight ratios of Brazil nut shells: KOH of 1:0.5 and 1:1, respectively. The prepared materials were characterized using different techniques and applied to remove phenol from the aqueous solution through adsorption. The characterization data showed that both materials presented similar properties, with AC11 exhibiting a slightly higher specific surface area (332.2 m2 g–1) than AC105 (314.3 m2 g–1). The kinetic study showed that AC11 reached the process equilibrium faster than AC105, and the Elovich model was best suited to the kinetic data for both adsorbents. The equilibrium data followed the Sips model; the maximum adsorption capacities were 55.16 and 68.52 mg g–1 for AC105 and AC11, respectively. The application of the materials in the treatment of a simulated industrial effluent showed removal efficiencies of 28.05% and 48.20% for AC105 and AC11, respectively. Therefore, through the adsorption results, AC11 proved to be more efficient towards phenol removal and is a promising alternative for treating wastewater containing this contaminant