Geometry-induced pulse instability in microdesigned catalysts: the effect of boundary curvature

We explore the effect of boundary curvature on the instability of reactive pulses in the catalytic oxidation of CO on microdesigned Pt catalysts. Using ring-shaped domains of various radii, we find that the pulses disappear (decollate from the inert boundary) at a turning point bifurcation, and trace this boundary in both physical and geometrical parameter space. These computations corroborate experimental observations of pulse decollation.Comment: submitted to Phys. Rev.

Enhancement of surface activity in CO oxidation on Pt(110) through spatiotemporal laser actuation

We explore the effect of spatiotemporally varying substrate temperature profiles on the dynamics and resulting reaction rate enhancement for the catalytic oxidation of CO on Pt(110). The catalytic surface is "addressed" by a focused laser beam whose motion is computer-controlled. The averaged reaction rate is observed to undergo a characteristic maximum as a function of the speed of this moving laser spot. Experiments as well as modelling are used to explore and rationalize the existence of such an optimal laser speed.Comment: 9 pages, 12 figures, submitted to Phys. Rev.

Cooling of a mirror in cavity optomechanics with a chirped pulse

We investigate the response of a harmonically confined mirror to an optical pulse in cavity optomechanics. We show that when the pulsed coupling strength takes the form of a chirped pulse, thermal fluctuations of the mirror can be significantly transferred to the cavity field. In addition, the frequency modulation of the pulse could enable a better cooling performance by suppressing the sensitivity of the dependence of detuning and pulse areas. Using numerical investigations, we find that the pulsed-cooling is mainly limited by the cavity-field decay rate.Comment: 6 pages, 4 figure

Guiding chemical pulses through geometry: Y-junctions

We study computationally and experimentally the propagation of chemical pulses in complex geometries.The reaction of interest, CO oxidation, takes place on single crystal Pt(110) surfaces that are microlithographically patterned; they are also addressable through a focused laser beam, manipulated through galvanometer mirrors, capable of locally altering the crystal temperature and thus affecting pulse propagation. We focus on sudden changes in the domain shape (corners in a Y-junction geometry) that can affect the pulse dynamics; we also show how brief, localized temperature perturbations can be used to control reactive pulse propagation.The computational results are corroborated through experimental studies in which the pulses are visualized using Reflection Anisotropy Microscopy.Comment: submitted to Phys. Rev.