Does player specialization predict player actions? Evidence from penalty kicks at FIFA World Cup and UEFA Euro Cup

Penalty-kicks are analysed in the literature as `real life experiments' for assessing the use of rational mixed strategies by professional players. However, each penalty kick cannot be considered a repetition of the same event because of the varying background conditions, in particular the heterogeneous ability of different players. Consequently, aggregate statistics over datasets composed of a large number of penalty kicks mediate the behaviour of the players in \emph{different} games, and the properties of optimal mixed strategies cannot be tested directly because of \emph{aggregation bias}. In this paper we model the heterogeneous ability of players. We then test the hypothesis that differently talented players randomise over different actions. To this aim, we study a dataset that collects penalties kicked during shootout series in the last editions of FIFA World-Cup and UEFA Euro-Cup (1994-2012) where kickers are categorized as specialists and non-specialists. The results support our theoretical prediction

Electronic structure, magnetic and dielectric properties of the edge-sharing copper-oxide chain compound NaCu2_{2}O2_{2}

We report an experimental study of \nco, a Mott insulator containing chains of edge-sharing CuO$_4$ plaquettes, by polarized x-ray absorption spectroscopy (XAS), resonant magnetic x-ray scattering (RMXS), magnetic susceptibility, and pyroelectric current measurements. The XAS data show that the valence holes reside exclusively on the Cu$^{2+}$ sites within the copper-oxide spin chains and populate a $d$-orbital polarized within the CuO$_4$ plaquettes. The RMXS measurements confirm the presence of incommensurate magnetic order below a N\'eel temperature of $T_N = 11.5$ K, which was previously inferred from neutron powder diffraction and nuclear magnetic resonance data. In conjunction with the magnetic susceptibility and XAS data, they also demonstrate a new "orbital" selection rule for RMXS that is of general relevance for magnetic structure determinations by this technique. Dielectric property measurements reveal the absence of significant ferroelectric polarization below $T_N$, which is in striking contrast to corresponding observations on the isostructural compound \lco. The results are discussed in the context of current theories of multiferroicity.Comment: 7 pages, 7 figure

Sheep as a silvicultural tool in coastal Douglas-fir forest

The International Hill Land Symposium was held at Oregon State University in April 1983.A study was conducted during 1981 and 1982 to evaluate the feasi­bility of using herded sheep as a silvicultural tool to suppress brush in Douglas-fir plantations of Oregon's coastal mountains. Effects of sheep grazing on vegetation were studied by comparing plants grown on grazed with those on ungrazed portions of five clearcut plantations. Parameters monitored included sheep live weight gains, utilization of vegetation by sheep, soil moisture, and growth of Douglas-fir trees. Browsing of Douglas-fir trees by sheep was most intense in the spring, then declined to low levels by July. Douglas-fir trees apparently benefited from the grazing treatment. Diameter increase of trees growing in grazed plantations was 7 to 14 percent greater than that of ungrazed controls. Height of trees of the end of the year was not affected by grazing. Grazing did reduce, however, the amount of brush present on the study clearcuts compared to ungrazed control areas. At the end of the 1982 growing season, current year growth of browse plants on ungrazed areas was 18 percent to 186 percent less than that in ungrazed areas. Regrowth of herbaceous plants, however, was stimu­lated by grazing. Soil moisture values for spring-grazed plantations were lower in the upper 60 cm of soil, but higher below 60 cm depth when compared to control areas

Ground state properties of heavy alkali halides

We extend previous work on alkali halides by calculations for the heavy-atom species RbF, RbCl, LiBr, NaBr, KBr, RbBr, LiI, NaI, KI, and RbI. Relativistic effects are included by means of energy-consistent pseudopotentials, correlations are treated at the coupled-cluster level. A striking deficiency of the Hartree-Fock approach are lattice constants deviating by up to 7.5 % from experimental values which is reduced to a maximum error of 2.4 % by taking into account electron correlation. Besides, we provide ab-initio data for in-crystal polarizabilities and van der Waals coefficients.Comment: accepted by Phys. Rev.

On the Temperature Dependence of the Lifetime of Thermally Isolated Metastable Clusters

The temperature dependence of the lifetime of the thermally isolated metastable N8 cubane up to its decay into N2 molecules has been calculated by the molecular dynamics method. It has been demonstrated that this dependence significantly deviates from the Arrhenius law. The applicability of the finite heat bath theory to the description of thermally isolated atomic clusters has been proved using statistical analysis of the results obtained.Comment: 14 pages, 4 figure

Correlated ab-initio calculations for ground-state properties of II-VI semiconductors

Correlated ab-initio ground-state calculations, using relativistic energy-consistent pseudopotentials, are performed for six II-VI semiconductors. Valence ($ns,np$) correlations are evaluated using the coupled cluster approach with single and double excitations. An incremental scheme is applied based on correlation contributions of localized bond orbitals and of pairs and triples of such bonds. In view of the high polarity of the bonds in II-VI compounds, we examine both, ionic and covalent embedding schemes for the calculation of individual bond increments. Also, a partitioning of the correlation energy according to local ionic increments is tested. Core-valence ($nsp,(n-1)d$) correlation effects are taken into account via a core-polarization potential. Combining the results at the correlated level with corresponding Hartree-Fock data we recover about 94% of the experimental cohesive energies; lattice constants are accurate to \sim 1%; bulk moduli are on average 10% too large compared with experiment.Comment: 10 pages, twocolumn, RevTex, 3 figures, accepted Phys. Rev.

Social support for and through exercise and sport in a sample of men with serious mental illness.

Social support is important for people experiencing serious mental illness and is also important during the initiation and maintenance of exercise. In this article we draw on interpretive research into the experiences of 11 men with serious mental illness to explore four dimensions of social support both for and through exercise. Our findings suggest that informational, tangible, esteem, and emotional support were both provided for and given by participants through exercise. We conclude that experiences of both receiving and giving diverse forms of support in this way are significant for some people living with and recovering from serious mental illness

Entanglement Measures for Single- and Multi-Reference Correlation Effects

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to the correlation energy can facilitate the decision regarding the optimum quantum chemical method of choice. We propose concepts from quantum information theory as orbital entanglement measures that allow us to evaluate the single- and multi-reference character of any molecular structure in a given orbital basis set. By studying these measures we can detect possible artifacts of small active spaces.Comment: 14 pages, 4 figure