2,934 research outputs found
Entanglement between an electron and a nuclear spin 1/2
We report on the preparation and detection of entangled states between an
electron spin 1/2 and a nuclear spin 1/2 in a molecular single crystal. These
were created by applying pulses at ESR (9.5 GHz) and NMR (28 MHz) frequencies.
Entanglement was detected by using a special entanglement detector sequence
based on a unitary back transformation including phase rotation.Comment: 4 pages, 3 figure
Entangled photons from a strongly coupled quantum dot-cavity system
A quantum dot strongly coupled to a photonic crystal has been recently
proposed as a source of entangled photon pairs [R. Johne et al., Phys. Rev.
Lett. 100, 240404 (2008)]. The biexction decay via intermediate polariton
states can be used to overcome the natural splitting between the exciton states
coupled to the horizontally and vertically polarized light modes, so that high
degrees of entanglement can be expected. We investigate theoretically the
features of realistic dot-cavity systems, including the effect of the different
oscillator strength of excitons resonances coupled to the different
polarizations of light. We show that in this case, an independent adjustment of
the cavity resonances is needed in order to keep a high entanglement degree. We
also consider the case when the biexciton-exciton transition is also strongly
coupled to a cavity mode. We show that a very fast emission rate can be
achieved allowing the repetition rates in the THz range. Such fast emission
should however be paid for by a very complex tuning of the many strongly
coupled resonances involved and by a loss of quantum efficiency. Altogether a
strongly coupled dot-cavity system seems to be very promising as a source of
entangled photon pairs.Comment: 7 pages, 5 figure
Entangled photon pairs produced by a quantum dot strongly coupled to a microcavity
We show theoretically that entangled photon pairs can be produced on demand
through the biexciton decay of a quantum dot strongly coupled to the modes of a
photonic crystal. The strong coupling allows to tune the energy of the mixed
exciton-photon (polariton) eigenmodes, and to overcome the natural splitting
existing between the exciton states coupled with different linear polarizations
of light. Polariton states are moreover well protected against dephasing due to
their lifetime ten to hundred times shorter than that of a bare exciton. Our
analysis shows that the scheme proposed can be achievable with the present
technology
Using of small-scale quantum computers in cryptography with many-qubit entangled states
We propose a new cryptographic protocol. It is suggested to encode
information in ordinary binary form into many-qubit entangled states with the
help of a quantum computer. A state of qubits (realized, e.g., with photons) is
transmitted through a quantum channel to the addressee, who applies a quantum
computer tuned to realize the inverse unitary transformation decoding of the
message. Different ways of eavesdropping are considered, and an estimate of the
time needed for determining the secret unitary transformation is given. It is
shown that using even small quantum computers can serve as a basis for very
efficient cryptographic protocols. For a suggested cryptographic protocol, the
time scale on which communication can be considered secure is exponential in
the number of qubits in the entangled states and in the number of gates used to
construct the quantum network
Geometry of the 3-Qubit State, Entanglement and Division Algebras
We present a generalization to 3-qubits of the standard Bloch sphere
representation for a single qubit and of the 7-dimensional sphere
representation for 2 qubits presented in Mosseri {\it et
al.}\cite{Mosseri2001}. The Hilbert space of the 3-qubit system is the
15-dimensional sphere , which allows for a natural (last) Hopf
fibration with as base and as fiber. A striking feature is, as in
the case of 1 and 2 qubits, that the map is entanglement sensitive, and the two
distinct ways of un-entangling 3 qubits are naturally related to the Hopf map.
We define a quantity that measures the degree of entanglement of the 3-qubit
state. Conjectures on the possibility to generalize the construction for higher
qubit states are also discussed.Comment: 12 pages, 2 figures, final versio
Entanglement of electrons in interacting molecules
Quantum entanglement is a concept commonly used with reference to the
existence of certain correlations in quantum systems that have no classical
interpretation. It is a useful resource to enhance the mutual information of
memory channels or to accelerate some quantum processes as, for example, the
factorization in Shor's Algorithm. Moreover, entanglement is a physical
observable directly measured by the von Neumann entropy of the system. We have
used this concept in order to give a physical meaning to the electron
correlation energy in systems of interacting electrons. The electronic
correlation is not directly observable, since it is defined as the difference
between the exact ground state energy of the many--electrons Schroedinger
equation and the Hartree--Fock energy. We have calculated the correlation
energy and compared with the entanglement, as functions of the nucleus--nucleus
separation using, for the hydrogen molecule, the Configuration Interaction
method. Then, in the same spirit, we have analyzed a dimer of ethylene, which
represents the simplest organic conjugate system, changing the relative
orientation and distance of the molecules, in order to obtain the configuration
corresponding to maximum entanglement.Comment: 15 pages, 7 figures, standard late
Synthesis and evaluation of influenza A viral neuraminidase candidate inhibitors based on a bicyclo[3.1.0]hexane scaffold
We describe the synthesis of constrained oseltamivir analogues designed to mimic the proposed boat conformation of the enzymatic transition state
Current Models of Investor State Dispute Settlement Are Bad for Health: The European Union Could Offer an Alternative Comment on "The Trans-Pacific Partnership: Is It Everything We Feared for Health?"
In this commentary, we endorse concerns about the health impact of the trans-pacific partnership (TPP), paying particular attention to its mechanisms for investor state dispute settlement. We then describe the different, judge-led approach being advocated by the European Commission team negotiating the Trans-Atlantic Trade and Investment Partnership, arguing that, while not perfect, it offers significant advantages
Quantum state transfer and entanglement distribution among distant nodes in a quantum network
We propose a scheme to utilize photons for ideal quantum transmission between
atoms located at spatially-separated nodes of a quantum network. The
transmission protocol employs special laser pulses which excite an atom inside
an optical cavity at the sending node so that its state is mapped into a
time-symmetric photon wavepacket that will enter a cavity at the receiving node
and be absorbed by an atom there with unit probability. Implementation of our
scheme would enable reliable transfer or sharing of entanglement among
spatially distant atoms.Comment: 4 pages, 3 postscript figure
Observation of a Tricyclic[4.1.0.0 2,4]heptane During a Michael Addition-Ring Closure Reaction and a Computational Study on Its Mechanism of Formation
We describe the formation of a bis-cyclopropane product, a tricyclic[4.1.0.02,4]heptane, that is formed during a Johnson-Corey-Chaykovsky reaction on a cyclopentenone. Two (of four possible) bicyclic products are selectively formed by addition of a COOEt-stabilized sulfur ylide onto the Michael acceptor. The tricyclic product is formed subsequently via a retro Michael elimination of a hindered ether followed by addition of a further cyclopropyl moiety, affecting only one of the two bicyclic products initially formed. The experimental reaction outcome was rationalized using density functional theory (DFT), investigating the different Michael-addition approaches of the sulfur ylide, the transition state (TS) energies for the formation of possible zwitterionic intermediates and subsequent reactions that give rise to cyclopropanation. Selective formation of only two of the four possible products occurs due to the epimerization of unreactive intermediates from the other two pathways, as revealed by energy barrier calculations. The formation of the tricyclic product was rationalized by evaluation of energy barriers for proton abstraction required to form the intermediate undergoing the second cyclopropanation. The selectivity-guiding factors discussed for the single and double cyclopropanation of this functionalized Michael-acceptor will be useful guidelines for the synthesis of future singly and doubly cyclopropanated compounds
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