Key performance indicators of ‘good practices’ of energy efficiency in industry: application to real cases in Italy and in the European Union

With the publication of the Energy Efficiency Directive (EED) in 2012, energy savings in the Industry processes have gained more and more importance in the European Union (EU). Industry (with building and transport) is one of the three main sectors where Energy consumption and efficiency play a fundamental role, to accomplish the EU energy objectives. Many countries in EU have already adopted schemes and mechanisms to implement the Directive: however deep differences of approaches still remain among the Member States (MSs), especially with respect to the identification of the real benefits of measures and to the assessment of their efficiency and sustainability. As a consequence, a huge amount of the efficiency potential still remains untapped. This paper proposes some criteria for the evaluation of the applied Energy Efficiency measures, leading to the identification of Good Practices of Energy Efficiency. These criteria are taken from the ‘real world’ of industry, and are susceptible to be replicated in other contexts (e.g. different sectors or other countries). The proposed criteria have been developed in the EU H2020 project EU MERCI (nr 693845) and through a national research (part of the ‘Ricerca di Sistema’ national funding system) both coordinated by RSE. The starting point is the harmonization of data sets related to projects developed in different EU countries within local efficiency implementation schemes. The second step is the definition of Key Performance Indicators (KPIs) reflecting the impact of measures against Energy, Environment and Economic aspects. The last step is the extraction of efficiency ‘Good Practices’ ranked according to the identified KPIs and other factors, including social elements. The real added value of this approach is that it is full based on tangibly implemented projects, in opposition to similar attempts, essentially theoretical. Ultimately, it offers a key of assessment of the effectiveness of efficiency measures implementing local and EU policies

Fluorescence suppression using micro-scale spatially offset Raman spectroscopy

We present a new concept of fluorescence suppression in Raman microscopy based on micro-spatially offset Raman spectroscopy which is applicable to thin stratified turbid (diffusely scattering) matrices permitting the retrieval of the Raman signals of sublayers below intensely fluorescing turbid over-layers. The method is demonstrated to yield good quality Raman spectra with dramatically suppressed fluorescence backgrounds enabling the retrieval of Raman sublayer signals even in situations where conventional Raman microscopy spectra are fully overwhelmed by intense fluorescence. The concept performance was studied theoretically using Monte Carlo simulations indicating the potential of up to an order or two of magnitude suppression of overlayer fluorescence backgrounds relative to the Raman sublayer signals. The technique applicability was conceptually demonstrated on layered samples involving paints, polymers and stones yielding fluorescence suppression factors between 12 to above 430. The technique has potential applications in a number of analytical areas including cultural heritage, archaeology, polymers, food, pharmaceutical, biological, biomedical, forensics and catalytic sciences and quality control in manufacture

Synchrotron radiation μ X-ray diffraction in transmission geometry for investigating the penetration depth of conservation treatments on cultural heritage stone materials

The assessment of the penetration depth of conservation treatments applied to cultural heritage stone materials is a burning issue in conservation science. Several analytical approaches have been proposed but, at present, many of them are not fully exhaustive to define in a direct way the composition and location of the conservation products formed after inorganic mineral treatments. Here, we explored, for the first time, the analytical capability of synchrotron radiation m X-ray diffraction in transmission geometry (SR-mTXRD) for the study of the crystal chemistry and penetration depth of the consolidating phases formed after the application of diammonium hydrogen phosphate (DAP) treatments on a porous carbonatic stone (Noto limestone). The SR-mTXRD approach provided unambiguous information on the nature of the newly formed calcium phosphates (hydroxyapatite, HAP, and octacalcium phosphate, OCP) with depth, supplying important indications of the diffusion mechanism and the reactivity of the substrate. Qualitative and semi-quantitative data were obtained at the microscale with a non-destructive protocol and an outstanding signal-to-noise ratio. The SR-mTXRD approach opens a new analytical scenario for the investigation of a wide range of cultural heritage materials, including natural and artificial stone materials, painted stratigraphies, metals, glasses and their decay products. Furthermore, it can potentially be used to characterize the penetration depth of a phase \u201cA\u201d (or more crystalline phases) in a matrix \u201cB\u201d also beyond the cultural heritage field, demonstrating the potential wide impact of the study

Analytical capability of defocused μ-SORS in the chemical interrogation of thin turbid painted layers

© The Author(s) 2015. A recently developed micrometer-scale spatially offset Raman spectroscopy (m-SORS) method provides a new analytical capability for investigating non-destructively the chemical composition of sub-surface, micrometer-scale thickness, diffusely scattering layers at depths beyond the reach of conventional confocal Raman microscopy. Here, we demonstrate experimentally, for the first time, the capability of μ-SORS to determine whether two detected chemical components originate from two separate layers or whether the two components are mixed together in a single layer. Such information is important in a number of areas, including conservation of cultural heritage objects, and is not available, for highly turbid media, from conventional Raman microscopy, where axial (confocal) scanning is not possible due to an inability to facilitate direct imaging within the highly scattering sample. This application constitutes an additional capability for μ-SORS in addition to its basic capacity to determine the overall chemical make-up of layers in a turbid system

Scientific investigation to look into the conservation history of a Tang Dynasty terracotta Dancing Horse

AbstractA terracotta Dancing Horse sculpture dating to the Tang Dynasty (China) and owned by the Cincinnati Art Museum (US) is the topic of the present investigation. Besides its intrinsic artistic and historical values, the peculiarity of this horse concerns its conservation history; it shows extensive breakage signs and restoration and above all, the presence of an odd tassel on the frontal part of the head. Nine tassels are present on the two sides of the body, which is very common for these kinds of sculptures. Here, a scientific survey of this masterpiece is proposed aimed at looking into its conservation history, shedding light into the condition of the body and the tassels and the presence of residual conservation products applied during its troubled history. A comparative molecular, chemical and mineralogical study of the tassels is carried out focused on the identification of original and non-original materials, eventually added during restoration works. The multi-analytical protocol has been optimized for achieving as much information as possible from the available samples, a few mg of powders. X-ray powder diffraction and Raman Spectroscopy techniques have been followed by Fourier Transformed Infrared Spectroscopy and Ionic Chromatography, using the same small aliquot of powders. Scientific investigations highlighted that the odd tassel on the head and other two tassels on the body are not original, but replaced or added in subsequent time. Their composition includes both organic (polyester resin and/or phthalate) and inorganic compounds (sulphates and carbonates). Further data on original terracotta composition, decay substances and applied conservation products, provided new knowledge on past restoration treatments and cultural value. Importantly, the outcomes achieved with X-ray powder diffraction to identify the tassels authenticity were matched by Raman Spectroscopy, a technique that can be also used in situ with portable instruments, paving the way to non-invasive in situ authenticity studies as future perspective

Grazing incidence synchrotron X-ray diffraction of marbles consolidated with diammonium hydrogen phosphate treatments : non-destructive probing of buried minerals

Diammonium hydrogen phosphate (DAP)-based consolidating treatments react with carbonatic stones and form calcium phosphates phases, whose composition depends on the availability of free calcium ions. In this work, an innovative non-destructive approach based on grazing incidence X-ray diffraction (GIXRD) with synchrotron radiation (SR) is used to investigate DAP-treated Carrara marble specimens and to study the influence of the substrate composition on the crystallization of calcium phosphate phases. The outcomes indicate that the presence of compositional micro-heterogeneity of Carrara marble favours the formation of specific phases. Dicalcium phosphate dihydrate, a calcium phosphate with a low Ca/P molar ratio, is formed on carbonatic phases with a low Ca amount, such as dolomite grains and Mg-containing veins. Furthermore, this study highlights the potentialities of SR-GIXRD as a powerful non-destructive tool for the diagnostic of Cultural Heritage objects since it allows investigating the conservation history of stone materials and their interaction with the environment

‘Good Practices’ to Improve Energy Efficiency in the Industrial Sector

Since the introduction of the International Pollution Prevention and Control (IPPC) directive and of the Best Available Techniques Reference (BREF) documents, the best available techniques (BATs) have become a reference both for policies and for companies to compare performance and to identify investment opportunities. Due to the environmental core of the IPPC and the Industrial Emissions Directive (IED), energy efficiency (EE) BATs are not always detailed and often lack energy-performance indicators. The H2020 EU-MERCI project is aimed at fostering and facilitating the implementation of EE projects in the manufacturing industry sectors by selecting and disseminating technological and policy best practices. A set of EE ‘Good Practices’ (GPs) was developed considering both BREF indications and literature analysis, and as innovative approach the outcomes of EE obligation and support measures aimed at the industrial sector. This was implemented through an in-depth analysis of the existing schemes in four countries (Austria, Italy, Poland and UK) and a thorough activity to normalise and compare the data made available by the different schemes. The outcome is available through the European Industrial Energy Efficiency good Practices platform implemented by EU-MERCI Partners. On the platform, a database of EE projects implemented in industry under the existing schemes is available. The database is searchable by country, sector, supporting scheme, implementation year and company size. The complete list is also downloadable as Excel file. Besides, a library divided by sectors is available, in which it is possible to look for the available GPs (both BATs and projects implemented under the national schemes) for each phase of the manufacturing processes. Sectoral and national analyses are finally available. This article will illustrate the methodology used for the project and the main outcomes.This work has been funded partially by the Research Fund for Italian Electric System under the Contract Agreement between RSE and the Italian Ministry of Economic Development and partially by the European Commission under Grant Agreement No. 693845 (EU-MERCI project). The authors would like to thank the other project partners, especially AEA, KAPE, Carbon Trust, CRES and FIRE and the colleagues from RSE for the constant support

Synthesis of calcium oxalate trihydrate: new data by vibrational spectroscopy and synchrotron X-ray diffraction

Calcium oxalate is found in nature in three different crystalline states determined by the number of H2O in the unit formula (whewellite CaC2O4\ub7H2O, COM; weddellite CaC2O4\ub7(2 + x)H2O, COD and caoxite CaC2O4\ub73H2O, COT). The properties of these materials are relevant in the field of biomedicine, cultural heritage and mineralogy. In two previous papers, we have used X-ray diffraction and vibrational spectroscopy (infrared and Raman) to derive information on crystal and molecular structures of COM and COD. In this paper, we complete the synthesis and analysis on the third form, COT, and present a comparative study of the data collected from the three crystalline states. The experiments clearly highlight the role played by the H2O molecules linked within the structure by different kinds of hydrogen bonds. The vibrational assignment of the infrared and Raman bands are critically proposed. The fact relevant for the work in biomedicine, cultural heritage and crystallography is that a simple examination of the spectra allows quickly to determine the chemical nature of the material in an unknown sample even in a minute quantity or in awkward experimental conditions