LASER-ABLATION OF POLYMERIC MATERIALS AT 157 NM

Results are presented on the ablation by 157 nm laser radiation of polytetrafluoroethylene (PTFE), polyimide, polyhydroxybutyrate (PHB), poly(methyl methacrylate) (PMMA), and poly(2-hydroxyethyl methacrylate) with 1% of ethylene glycol dimethacrylate as a crosslinking monomer. Direct photoetching of PHB and undoped PTFE is demonstrated for laser fluences ranging from 0.05 to 0.8 J/cm2. The dependence of the ablation process on the polymer structure is analyzed, and insight into the ablation mechanism is gained from an analysis of the data using Beer-Lambert's law and the kinetic model of the moving interface. Consideration of the absorbed energy density required to initiate significant ablation suggests that the photoetching mechanism is similar for all the polymers studied. © 1995 American Institute of Physics

Effect of pH on the rate of curing and bioadhesive properties of dopamine functionalized poly(ethylene glycol) hydrogels

The remarkable underwater adhesion strategy employed by mussels has inspired bioadhesives that have demonstrated promise in connective tissue repair, wound closure, and local delivery of therapeutic cells and drugs. While the pH of oxygenated blood and internal tissues is typically around 7.4, skin and tumor tissues are significantly more acidic. Additionally, blood loss during surgery and ischemia can lead to dysoxia, which lowers pH levels of internal tissues and organs. Using 4-armed PEG end-capped with dopamine (PEG-D) as a model adhesive polymer, the effect of pH on the rate of intermolecular cross-linking and adhesion to biological substrates of catechol-containing adhesives was determined. Adhesive formulated at an acidic pH (pH 5.7–6.7) demonstrated reduced curing rate, mechanical properties, and adhesive performance to pericardium tissues. Although a faster curing rate was observed at pH 8, these adhesives also demonstrated reduced mechanical and bioadhesive properties when compared to adhesives buffered at pH 7.4. Adhesives formulated at pH 7.4 demonstrated a good balance of fast curing rate, elevated mechanical properties and interfacial binding ability. UV–vis spectroscopy evaluation revealed that the stability of the transient oxidation intermediate of dopamine was increased under acidic conditions, which likely reduced the rate of intermolecular cross-linking and bulk cohesive properties for hydrogels formulated at these pH levels. At pH 8, competing cross-linking reaction mechanisms and reduced concentration of dopamine catechol due to auto-oxidation likely reduced the degree of dopamine polymerization and adhesive strength for these hydrogels. pH plays an important role in the adhesive performance of mussel-inspired bioadhesives and the pH of the adhesive formulation needs to be adjusted for the intended application

Measurement of the lifetimes of promptly produced Ωc0Ω^{0}_{c} and Ξc0Ξ^{0}_{c} baryons

A measurement of the lifetimes of the $\Omega^{0}_{c}$ and $\Xi^{0}_{c}$ baryons is reported using proton-proton collision data at a centre-of-mass energy of $13\text{ TeV}$, corresponding to an integrated luminosity of $5.4\text{ fb}^{-1}$ collected by the LHCb experiment. The $\Omega^{0}_{c}$ and $\Xi^{0}_{c}$ baryons are produced directly from proton interactions and reconstructed in the $pK^{-}K^{-}\pi^{+}$ final state. The $\Omega^{0}_{c}$ lifetime is measured to be $276.5\pm13.4\pm4.4\pm0.7\text{ fs}$, and the $\Xi^{0}_{c}$ lifetime is measured to be $148.0\pm2.3\pm2.2\pm0.2\text{ fs}$, where the first uncertainty is statistical, the second systematic, and the third due to the uncertainty on the $D^{0}$ lifetime. These results confirm previous LHCb measurements based on semileptonic beauty-hadron decays, which disagree with earlier results of a four times shorter $\Omega^{0}_{c}$ lifetime, and provide the single most precise measurement of the $\Omega^{0}_{c}$ lifetime

Measurement of the lifetimes of promptly produced Omega(0)(c) and Xi(9)(c) baryons

A measurement of the lifetimes of the Omega(0)(c) and Xi(0)(c) baryons is reported using proton-proton collision data at a centre-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 5.4 fb(-1) collected by the LHCb experiment. The Omega(0)(c) and Xi(0)(c) baryons are produced directly from proton interactions and reconstructed in the pK(-)K(-)pi(+) final state. The Omega(0)(c) lifetime is measured to be 276.5 +/- 13.4 +/- 4.4 +/- 0.7 fs, and the Xi(0)(c) lifetime is measured to be 148.0 +/- 2.3 +/- 2.2 +/- 0.2 fs, where the first uncertainty is statistical, the second systematic, and the third due to the uncertainty on the D-0 lifetime. These results confirm previous LHCb measurements based on semileptonic beauty-hadron decays, which disagree with earlier results of a four times shorter Omega(c)0 lifetime, and provide the single most precise measurement of the Omega(0 )(c)lifetime. (C) 2021 Science China Press. Published by Elsevier B.V. and Science China Press