2,338 research outputs found
Topological derivation of shape exponents for stretched exponential relaxation
In homogeneous glasses, values of the important dimensionless
stretched-exponential shape parameter beta are shown to be determined by magic
(not adjusted) simple fractions derived from fractal configuration spaces of
effective dimension d* by applying different topological axioms (rules) in the
presence (absence) of a forcing electric field. The rules are based on a new
central principle for defining glassy states: equal a priori distributions of
fractal residual configurational entropy. Our approach and its beta estimates
are fully supported by the results of relaxation measurements involving many
different glassy materials and probe methods. The present unique topological
predictions for beta typically agree with observed values to ~ 1% and indicate
that for field-forced conditions beta should be constant for appreciable ranges
of such exogenous variables as temperature and ionic concentration, as indeed
observed using appropriate data analysis. The present approach can also be
inverted and used to test sample homogeneity and quality.Comment: Original 13 pages lengthened to 21 pages (longer introduction, added
references and discussion of new experimental data published since original
submission
Air data measurement system for space shuttle
It is concluded that air data measurements of angle of attack and sideslip are needed to control the space shuttle vehicles. The basis for this conclusion, along with recommended sensor design and implementation, are described
Determination of solid mass fraction in partially frozen hydrocarbon fuels
Filtration procedures alone are insufficient to determine the amounts of crystalline solid in a partially frozen hydrocarbon distillate fraction. This is due to the nature of the solidification process by which a large amount of liquid becomes entrapped within an interconnected crystalline structure. A technique has been developed to supplement filtration methods with an independent determination of the amount of liquid in the precipitate thereby revealing the actual value of mass percent crystalline solid, %S. A non-crystallizing dye is injected into the fuel and used as a tracer during the filtration. The relative concentrations of the dye in the filtrate and precipitate fractions is subsequently detected by a spectrophotometric comparison. The filtration apparatus was assembled so that the temperature of the sample is recorded immediately above the filter. Also, a second method of calculation has been established which allows significant reduction in test time while retaining acceptable accuracy of results. Data have been obtained for eight different kerosene range hydrocarbon fuels
Viability and performance of demountable composite connectors
AbstractMaterial production, and associated carbon emissions, could be reduced by reusing products instead of landfilling or recycling them. Steel beams are well suited to reuse, but are difficult to reuse when connected compositely to concrete slabs using welded studs. A demountable connection would allow composite performance but also permit reuse of both components at end-of-life. Three composite beams, of 2m, 10m and 5m length, are constructed using M20 bolts as demountable shear connectors. The beams are tested in three-, six- and four-point bending, respectively. The former two are loaded to service, unloaded, demounted and reassembled; all three are tested to failure. The results show that all three have higher strengths than predicted using Eurocode 4. The longer specimens have performance similar to previously published comparable welded-connector composite beam results. This suggests that demountable composite beams can be safely used and practically reused, thus reducing carbon emissions
Temperature in nonequilibrium systems with conserved energy
We study a class of nonequilibrium lattice models which describe local
redistributions of a globally conserved energy. A particular subclass can be
solved analytically, allowing to define a temperature T_{th} along the same
lines as in the equilibrium microcanonical ensemble. The
fluctuation-dissipation relation is explicitely found to be linear, but its
slope differs from the inverse temperature T_{th}^{-1}. A numerical
renormalization group procedure suggests that, at a coarse-grained level, all
models behave similarly, leading to a two-parameter description of their
macroscopic properties.Comment: 4 pages, 1 figure, final versio
Sources of total, non-milk extrinsic, and intrinsic and milk sugars in the diets of older adults living in sheltered accommodation
The WHO recommends limiting non-milk extrinsic sugars (NMES) consumption to ≤ 10 % energy to reduce the risk of unhealthy weight gain and dental caries, and to restrict frequency of intake to ≤ 4 times/d to reduce risk of dental caries. Older adults, especially those from low-income backgrounds, are at increased risk of dental caries, yet there is little information on sugars intake (frequency of intake and food sources) in this age group. The aim of this report is to present baseline data from a community-based dietary intervention study of older adults from socially deprived areas of North East England, on the quantity and sources of total sugars, NMES, and intrinsic and milk sugars, and on frequency of NMES intake. Dietary intake was assessed using two 3-d estimated food diaries, completed by 201 participants (170 female, thirty-one male) aged 65–85 years (mean 76·7 (sd 5·5) years) recruited from sheltered housing schemes. Total sugars represented 19·6 %, NMES 9·3 %, and intrinsic and milk sugars 10·3 % of daily energy intake. Eighty-one (40·3 %) exceeded the NMES intake recommendation. Mean frequency of NMES intake was 3·4 times/d. The fifty-three participants (26·4 %) who exceeded the frequency recommendation ( ≤ 4 times/d) obtained a significantly greater percentage of energy from NMES compared with those participants who met the recommendation. The food groups ‘biscuits and cakes’ (18·9 %), ‘soft drinks’ (13·1 %) and ‘table sugar’ (11·1 %) made the greatest contributions to intakes of NMES. Interventions to reduce NMES intake should focus on limiting quantity and frequency of intake of these food groups
Is there a "native" band gap in ion conducting glasses?
It is suggested that the spectrum of ion site energies in glasses exhibits a
band gap, establishing an analogy between ion conducting glasses and intrinsic
semiconductors. This implies that ion conduction in glasses takes place via
vacancies and interstitial ions (as in crystals).Comment: 3 page
Heat capacity at the glass transition
A fundamental problem of glass transition is to explain the jump of heat
capacity at the glass transition temperature without asserting the
existence of a distinct solid glass phase. This problem is also common to other
disordered systems, including spin glasses. We propose that if is defined
as the temperature at which the liquid stops relaxing at the experimental time
scale, the jump of heat capacity at follows as a necessary consequence
due to the change of system's elastic, vibrational and thermal properties. In
this picture, we discuss time-dependent effects of glass transition, and
identify three distinct regimes of relaxation. Our approach explains widely
observed logarithmic increase of with the quench rate and the correlation
of heat capacity jump with liquid fragility
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