Extragalactic Zeeman Detections in OH Megamasers

We have measured the Zeeman splitting of OH megamaser emission at 1667 MHz from five (ultra)luminous infrared galaxies ([U]LIRGs) using the 305 m Arecibo telescope and the 100 m Green Bank Telescope. Five of eight targeted galaxies show significant Zeeman-splitting detections, with 14 individual masing components detected and line-of-sight magnetic field strengths ranging from ~0.5-18 mG. The detected field strengths are similar to those measured in Galactic OH masers, suggesting that the local process of massive star formation occurs under similar conditions in (U)LIRGs and the Galaxy, in spite of the vastly different large-scale environments. Our measured field strengths are also similar to magnetic field strengths in (U)LIRGs inferred from synchrotron observations, implying that milligauss magnetic fields likely pervade most phases of the interstellar medium in (U)LIRGs. These results provide a promising new tool for probing the astrophysics of distant galaxies.Comment: 32 pages, 14 figures, 8 tables. Accepted for publication in The Astrophysical Journal v680n2, June 20, 2008; corrected 2 typo

NON-FREE VORTEX FLOW EFFECTS IN AN AXIAL FLOW ROTOR

This paper presents the analysis of three-dimensional flow field developing through an industrial axial flow fan rotor of non-free vortex design carried out on the basis of concerted experimental and numerical investigations. The paper focuses on non-free vortex flow effects requiring consideration in rotor blade design theories. The distortion of stream surfaces through the blading has been observed and a quantitative analysis of its effects on the blade loading condition has been carried out in the through-flow core region. The streamlines close to the blades have been modelled fitting to outward and inward conical stream tubes on the blade suction and pressure sides, respectively - termed `cone couple model´. It has been pointed out that the blade lift can be satisfactorily described at midspan on the basis of the cone couple model, with use of pitch-averaged flow data. The loading aspects of the tested axial rotor have been discussed on the basis of both the pressure distribution in the vicinity of the blades and pitch-averaged flow data obtained upstream and downstream of the rotor. Sample calculations suggested that separate optimisation of the blade suction and pressure sides is essential if the three-dimensional blade-to-blade flow is intended to be considered in NFV fan design with use of two-dimensional cascade data

Effect of generation on the electronic properties of light-emitting dendrimers

We have compared the optical and electronic properties of a series of porphyrin centred dendrimers containing stilbene dendrons. The first and second generation dendrimers could be spin-coated from solution to form good quality thin films. Incorporation into single layer light-emitting diodes gave red-light emission with maximum external quantum efficiencies of 0.02% and 0.04% for the first and second generation dendrimers respectively. We have determined by photoluminescence studies that energy can be transferred efficiently from the stilbene dendrons to the porphyrin core and that PL emission is from the core. Cyclic voltammetry studies on the dendrimers show that the reductions are porphyrin centred with the dendrons only affecting the rate of heterogeneous electron transfer between the electrode and the dendrimers. This suggests that charge mobility within a dendrimer film in an LED will be affected by the porphyrin edge to porphyrin edge distance. We have studied the hydrodynamic radii of the dendrimers by gel permeation chromatography and found as expected that the average porphyrin edge to dendron edge distance increases with generation This is consistent with the slowing of heterogeneous electron transfer observed in the cyclic voltammetry on increasing the generation number and suggests that the dendrons are interleaved in the solid state to facilitate charge transport

Statistical Properties of Galactic Starlight Polarization

We present a statistical analysis of Galactic interstellar polarization from the largest compilation available of starlight data. The data comprises ~ 9300 stars of which we have selected ~ 5500 for our analysis. We find a nearly linear growth of mean polarization degree with extinction. The amplitude of this correlation shows that interstellar grains are not fully aligned with the Galactic magnetic field, which can be interpreted as the effect of a large random component of the field. In agreement with earlier studies of more limited scope, we estimate the ratio of the uniform to the random plane-of-the-sky components of the magnetic field to be B_u/B_r = 0.8. Moreover, a clear correlation exists between polarization degree and polarization angle what provides evidence that the magnetic field geometry follows Galactic structures on large-scales. The angular power spectrum C_l of the starlight polarization degree for Galactic plane data (|b| < 10 deg) is consistent with a power-law, C_l ~ l^{-1.5} (where l ~ 180 deg/\theta is the multipole order), for all angular scales \theta > 10 arcmin. An investigation of sparse and inhomogeneous sampling of the data shows that the starlight data analyzed traces an underlying polarized continuum that has the same power spectrum slope, C_l ~ l^{-1.5}. Our findings suggest that starlight data can be safely used for the modeling of Galactic polarized continuum emission at other wavelengths.Comment: 31 pages, 11 figures. Minor corrections and some clarifications included. Matches version accepted for publication by the Astrophysical Journa

Control of mobility in molecular organic semiconductors by dendrimer generation

Conjugated dendrimers are of interest as novel materials for light-emitting diodes. They consist of a luminescent chromophore at the core with highly branched conjugated dendron sidegroups. In these materials, light emission occurs from the core and is independent of generation. The dendron branching controls the separation between the chromophores, We present here a family of conjugated dendrimers and investigate the effect of dendron branching on light emission and charge transport. We apply a number of transport measurement techniques to thin films of a conjugated dendrimer in a light-emitting diode configuration to determine the effect of chromophore spacing on charge transport. We find that the mobility is reduced by two orders of magnitude as the size of the molecule doubles with increased branching or dendrimer generation. The degree of branching allows a unique control of mobility by molecular structure. An increase in chromophore separation also results in a reduction of intermolecular interactions, which reduces the red emission tail in film photoluminescence. We find that the steady-state charge transport is well described by a simple device model incorporating the effect of generation, and use the materials to shed light on the interpretation of transient electroluminescence data. We demonstrate the significance of the ability to tune the mobility in bilayer devices, where a more balanced charge transport can be achieved

Effect of Water Vapor on the Oxidation Behavior of the Eutectic High‐Temperature Alloy Mo‐20Si‐52.8Ti

Herein, the effect of water vapor on the oxidation resistance of the alloy Mo-20Si-52.8Ti (at%) is investigated. The alloy is oxidized in dry, wet, as well as in in situ changing atmospheres at 1100 C. The oxidation kinetics changes from nearly parabolic to linear if water vapor is present in oxidizing atmosphere. Under all conditions, the oxide scales consist of an outer TiO$^{2}$ and a TiO$^{2}$─SiO$^{2}$ duplex layer underneath. In wet atmosphere, the thicknesses of the two regions substantially increase indicating a severe ingress of water vapor. The inferior oxidation resistance in wet environment is primarily rationalized by the fast diffusion of H$^{2}$O through SiO$^{2}$