15,444 research outputs found
Scaling of broadband dielectric data of glass-forming liquids and plastic crystals
The Nagel-scaling and the modified scaling procedure proposed recently by
Dendzik et al. have been applied to broadband dielectric data on two glass-
forming liquids (glycerol and propylene carbonate) and three plastic crystals
(ortho-carborane, meta-carborane, and 1-cyano-adamantane). Our data extend the
upper limit of the abscissa range to considerably higher values than in
previously published analyses. At the highest frequencies investigated,
deviations from a single master curve show up which are most pronounced in the
Dendzik-scaling plot. The loss curves of the plastic crystals do not scale in
the Nagel-plot, but they fall onto a separate master curve in the Dendzik-plot.
In addition, we address the question of a possible divergence of the static
susceptibility near the Vogel-Fulcher temperature. For this purpose, the
low-temperature evolution of the high-frequency wing of the dielectric loss
peaks is investigated in detail. No convincing proof for such a divergence can
be deduced from the present broadband data.Comment: 7 pages including 6 figures submitted to Eur. Phys. J.
The excess wing in the dielectric loss of glass-forming ethanol: A relaxation process
A detailed dielectric investigation of liquid, supercooled liquid, and glassy
ethanol reveals a third relaxation process, in addition to the two processes
already known. The relaxation time of the newly detected process exhibits
strong deviations from thermally activated behavior. Most important, this
process is the cause of the apparent excess wing, which was claimed to be
present in the dielectric loss spectra of glass-forming ethanol. In addition,
marked deviations of the spectra of ethanol from the scaling proposed by Dixon
and Nagel have been detected.Comment: 8 pages including 4 figures submitted to Phys. Rev.
The Excess Wing in the Dielectric Loss of Glass-Formers: A Johari-Goldstein beta-Relaxation?
Dielectric loss spectra of glass-forming propylene carbonate and glycerol at
temperatures above and below T_g are presented. By performing aging experiments
lasting up to five weeks, equilibrium spectra below T_g have been obtained.
During aging, the excess wing, showing up as a second power law at high
frequencies, develops into a shoulder. The results strongly suggest that the
excess wing, observed in a variety of glass formers, is the high-frequency
flank of a beta-relaxation.Comment: submitted to Phys. Rev. Lett., 4 figures, revised version after
referee report
Cantilever-based Resonant Microsensors with Integrated Temperature Modulation for Transient Chemical Analysis
This work introduces a resonant cantilever platform with integrated temperature modulation for real-time chemical sensing. Embedded heaters allow for rapid thermal cycling of individual sensors, thereby enabling real-time transient signal analysis without the need for a microfluidic setup to switch between analyte and reference gases. Compared to traditional mass-sensitive microsensors operating in steady state, the on-chip generation of signal transients provides additional information for analyte discrimination
Compressed Genotyping
Significant volumes of knowledge have been accumulated in recent years
linking subtle genetic variations to a wide variety of medical disorders from
Cystic Fibrosis to mental retardation. Nevertheless, there are still great
challenges in applying this knowledge routinely in the clinic, largely due to
the relatively tedious and expensive process of DNA sequencing. Since the
genetic polymorphisms that underlie these disorders are relatively rare in the
human population, the presence or absence of a disease-linked polymorphism can
be thought of as a sparse signal. Using methods and ideas from compressed
sensing and group testing, we have developed a cost-effective genotyping
protocol. In particular, we have adapted our scheme to a recently developed
class of high throughput DNA sequencing technologies, and assembled a
mathematical framework that has some important distinctions from 'traditional'
compressed sensing ideas in order to address different biological and technical
constraints.Comment: Submitted to IEEE Transaction on Information Theory - Special Issue
on Molecular Biology and Neuroscienc
Unified powered flight guidance
A complete revision of the orbiter powered flight guidance scheme is presented. A unified approach to powered flight guidance was taken to accommodate all phases of exo-atmospheric orbiter powered flight, from ascent through deorbit. The guidance scheme was changed from the previous modified version of the Lambert Aim Point Maneuver Mode used in Apollo to one that employs linear tangent guidance concepts. This document replaces the previous ascent phase equation document
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