Observations of ozone and related species in the northeast Pacific during the PHOBEA campaigns 2. Airborne observations

During late March and April of 1999 the University of Wyoming's King Air research aircraft measured atmospheric concentrations of NO, O3, peroxyacetyl nitrate (PAN), CO, CH4, VOCs, aerosols, and J(NO2) off the west coast of the United States. During 14 flights, measurements were made between 39°-48° N latitude, 125°-129° W longitude, and at altitudes from 0-8 km. These flights were part of the Photochemical Ozone Budget of the Eastern North Pacific Atmosphere (PHOBEA) experiment, which included both ground-based and airborne measurements. Flights were scheduled when meteorological conditions minimized the impact of local pollution sources. The resulting measurements were segregated by air mass source region as indicated by back isentropic trajectory analysis. The chemical composition of marine air masses whose 5-day back isentropic trajectories originated north of 40° N latitude or west of 180° W longitude (WNW) differed significantly from marine air masses whose 5-day back isentropic trajectories originated south of 40° N latitude and east of 180° W longitude (SW). Trajectory and chemical analyses indicated that the majority of all encountered air masses, both WNW and SW, likely originated from the northwestern Pacific and have characteristics of emissions from the East Asian continental region. However, air masses with WNW back trajectories contained higher mixing ratios of NO, NOx, O3, PAN, CO, CH4, various VOC pollution tracers, and aerosol number concentration, compared to those air masses with SW back trajectories. Calculations of air mass age using two separate methods, photochemical and back trajectory, are consistent with transport from the northwestern Pacific in 8-10 days for air masses with WNW back trajectories and 16-20 days for air masses with SW back trajectories. Correlations, trajectory analysis, and comparisons with measurements made in the northwestern Pacific during NASA's Pacific Exploritory Mission-West Phase B (PEM-West B) experiment in 1994 are used to investigate the data. These analyses provide evidence that anthropogenically influenced air masses from the northwestern Pacific affect the overall chemical composition of the northeastern Pacific troposphere. Copyright 2001 by the American Geophysical Union

The Arctic Summer Cloud Ocean Study (ASCOS): overview and experimental design

The climate in the Arctic is changing faster than anywhere else on earth. Poorly understood feedback processes relating to Arctic clouds and aerosol-cloud interactions contribute to a poor understanding of the present changes in the Arctic climate system, and also to a large spread in projections of future climate in the Arctic. The problem is exacerbated by the paucity of research-quality observations in the central Arctic. Improved formulations in climate models require such observations, which can only come from measurements in situ in this difficult-to-reach region with logistically demanding environmental conditions. The Arctic Summer Cloud Ocean Study (ASCOS) was the most extensive central Arctic Ocean expedition with an atmospheric focus during the International Polar Year (IPY) 2007-2008. ASCOS focused on the study of the formation and life cycle of low-level Arctic clouds. ASCOS departed from Longyearbyen on Svalbard on 2 August and returned on 9 September 2008. In transit into and out of the pack ice, four short research stations were undertaken in the Fram Strait: two in open water and two in the marginal ice zone. After traversing the pack ice northward, an ice camp was set up on 12 August at 87°21′ N, 01°29′ W and remained in operation through 1 September, drifting with the ice. During this time, extensive measurements were taken of atmospheric gas and particle chemistry and physics, mesoscale and boundary-layer meteorology, marine biology and chemistry, and upper ocean physics. ASCOS provides a unique interdisciplinary data set for development and testing of new hypotheses on cloud processes, their interactions with the sea ice and ocean and associated physical, chemical, and biological processes and interactions. For example, the first-ever quantitative observation of bubbles in Arctic leads, combined with the unique discovery of marine organic material, polymer gels with an origin in the ocean, inside cloud droplets suggests the possibility of primary marine organically derived cloud condensation nuclei in Arctic stratocumulus clouds. Direct observations of surface fluxes of aerosols could, however, not explain observed variability in aerosol concentrations, and the balance between local and remote aerosols sources remains open. Lack of cloud condensation nuclei (CCN) was at times a controlling factor in low-level cloud formation, and hence for the impact of clouds on the surface energy budget. ASCOS provided detailed measurements of the surface energy balance from late summer melt into the initial autumn freeze-up, and documented the effects of clouds and storms on the surface energy balance during this transition. In addition to such process-level studies, the unique, independent ASCOS data set can and is being used for validation of satellite retrievals, operational models, and reanalysis data sets

Short-Lived Trace Gases in the Surface Ocean and the Atmosphere

The two-way exchange of trace gases between the ocean and the atmosphere is important for both the chemistry and physics of the atmosphere and the biogeochemistry of the oceans, including the global cycling of elements. Here we review these exchanges and their importance for a range of gases whose lifetimes are generally short compared to the main greenhouse gases and which are, in most cases, more reactive than them. Gases considered include sulphur and related compounds, organohalogens, non-methane hydrocarbons, ozone, ammonia and related compounds, hydrogen and carbon monoxide. Finally, we stress the interactivity of the system, the importance of process understanding for modeling, the need for more extensive field measurements and their better seasonal coverage, the importance of inter-calibration exercises and finally the need to show the importance of air-sea exchanges for global cycling and how the field fits into the broader context of Earth System Science

Sealing performance of a turbine rim chute seal under rotationally-induced ingestion

This study focuses on the sealing capability of a turbine rim seal subject to hot gas ingestion driven purely by the rotor disc pumping effect rather than that induced by mainstream features such as vane and rotor blade passing. The aim is to provide useful data for conditions in which rotation dominates, and to clarify the flow physics involved in rim sealing. Experimental measurements of sealing effectiveness for a chute seal are presented for the first time without and with an axial, axisymmetric mainstream flow external to the seal. The test matrix covers a range of rotational Reynolds number, Re, from 1.5x106 to 3x106, and non-dimensional flow rate, Cw, from 0 to 4x104 with the mainstream flow (when present) scaled to match engine representative conditions of axial Reynolds number, Reax. Results from steady pressure and gas concentration measurements within the rotor-stator disc cavity and the rim seal gap are presented and compared to published data for other seal designs. Sealing performance of the chute seal is somewhat similar to that of axial clearance seals with the same minimum clearance

Sealing performance of a turbine rim chute seal under rotationally-induced ingestion

This study focuses on the sealing capability of a turbine rim seal subject to hot gas ingestion driven purely by the rotor disc pumping effect rather than that induced by mainstream features such as vane and rotor blade passing. The aim is to provide useful data for conditions in which rotation dominates, and to clarify the flow physics involved in rim sealing. Experimental measurements of sealing effectiveness for a chute seal are presented for the first time without and with an axial, axisymmetric mainstream flow external to the seal. The test matrix covers a range of rotational Reynolds number, Re, from 1.5x106 to 3x106, and non-dimensional flow rate, Cw, from 0 to 4x104 with the mainstream flow (when present) scaled to match engine representative conditions of axial Reynolds number, Reax. Results from steady pressure and gas concentration measurements within the rotor-stator disc cavity and the rim seal gap are presented and compared to published data for other seal designs. Sealing performance of the chute seal is somewhat similar to that of axial clearance seals with the same minimum clearance

Performance of a turbine rim seal subject to rotationally-driven and pressure-driven ingestion

This experimental study considered the performance of a chute rim seal downstream of turbine nozzle guide vanes (but without rotor blades). The experimental setup reproduced rotationally-driven ingestion without vanes and conditions of pressure-driven ingestion with vanes. The maximum rotor speed was 9000 rpm corresponding to a rotational Reynolds number of 3.3 × 106 with a flow coefficient of 0.45. Measurements of mean pressures in the annulus and the disk rim cavity as well as values of sealing effectiveness deduced from gas concentration data are presented. At high values of flow coefficient (low rotational speeds), the circumferential pressure variation generated by the vanes drove relatively high levels of ingestion into the disk rim cavity. For a given purge flow rate, increasing the disk rotational speed led to a reduction in ingestion, shown by higher values of sealing effectiveness, despite the presence of upstream vanes. At Uax=(Ωb) = 0:45, the sealing effectiveness approached that associated with purely rotationally-driven ingestion. A map of sealing effectiveness against non-dimensional purge flow summarizes the results and illustrates the combined rotational and pressure-driven effects on the ingestion mechanism. The results imply that flow coefficient is a relevant parameter in rim sealing and that rotational effects are important in many applications, especially turbines with low flow coefficient

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this manuscript, the state of the science concerning biosynthesis, transport, and chemical transformation of hydrocarbons emitted by the terrestrial biosphere is reviewed. In particular, the focus is on isoprene, monoterpenes, and oxygenated hydrocarbons. The generated science during the last 10 years is reviewed to explain and quantify hydrocarbon emissions from vegetation and to discern impacts of biogenic hydrocarbons on local and regional atmospheric chemistry. Furthermore, the physiological and environmental processes controlling biosynthesis and production of hydrocarbon compounds are reported on. Many advances have been made on measurement and modeling approaches developed to quantify hydrocarbon emissions from leaves and forest ecosystems. A synthesis of the atmospheric chemistry of biogenic hydrocarbons and their role in the formation of oxidants and aerosols is presented. The integration of biogenic hydrocarbon kinetics and atmospheric physics into mathematical modeling systems is examined to assess the contribution of biogenic hydrocarbons to the formation of oxidants and aerosols, thereby allowing us to study their impacts on the earth's climate system and to develop strategies to reduce oxidant precursors in affected regions

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this manuscript, the state of the science concerning biosynthesis, transport, and chemical transformation of hydrocarbons emitted by the terrestrial biosphere is reviewed. In particular, the focus is on isoprene, monoterpenes, and oxygenated hydrocarbons. The generated science during the last 10 years is reviewed to explain and quantify hydrocarbon emissions from vegetation and to discern impacts of biogenic hydrocarbons on local and regional atmospheric chemistry. Furthermore, the physiological and environmental processes controlling biosynthesis and production of hydrocarbon compounds are reported on. Many advances have been made on measurement and modeling approaches developed to quantify hydrocarbon emissions from leaves and forest ecosystems. A synthesis of the atmospheric chemistry of biogenic hydrocarbons and their role in the formation of oxidants and aerosols is presented. The integration of biogenic hydrocarbon kinetics and atmospheric physics into mathematical modeling systems is examined to assess the contribution of biogenic hydrocarbons to the formation of oxidants and aerosols, thereby allowing us to study their impacts on the earth's climate system and to develop strategies to reduce oxidant precursors in affected regions