Nanosecond electro-optics of nematic liquid crystal with negative dielectric anisotropy

We study a nanosecond electro-optic response of a nematic liquid crystal in a geometry where an applied electric field $\textbf{E}$ modifies the tensor order parameter but does not change the orientation of the optic axis (director $\hat{\textbf{N}}$). We use a nematic with negative dielectric anisotropy with the electric field applied perpendicularly to $\hat{\textbf{N}}$. The field changes the dielectric tensor at optical frequencies (optic tensor) due to the following mechanisms: (a) nanosecond creation of the biaxial orientational order; (b) uniaxial modification of the orientational order that occurs over timescales of tens of nanoseconds, and (c) the quenching of director fluctuations with a wide range of characteristic times up to milliseconds. We develop a model to describe the dynamics of all three mechanisms. We design the experimental conditions to selectively suppress the contributions from fluctuations quenching (c) and from the biaxial order effect (a) and thus, separate the contributions of the three mechanisms in the electro-optic response. As a result, the experimental data can be well fitted with the model. The analysis provides a detailed physical picture of how the liquid crystal responds to a strong electric field on a timescale of nanoseconds. This work provides a useful guide in the current search of the biaxial nematic phase. Namely, the temperature dependence of the biaxial susceptibility allows one to estimate the temperature of the potential uniaxial-to-biaxial phase transition. An analysis of the fluctuations quenching indicates that on a timescale of nanoseconds, the classic model with constant viscoelastic material parameters might reach its limit of validity. The effect of nanosecond electric modification of the order parameter (NEMOP) can be used in applications in which one needs to achieve ultrafast (nanosecond) changes of optical characteristics.Comment: 42 pages, 13 figures, 2 appendice

Nematic Twist-Bend Phase with Nanoscale Modulation of Molecular Orientation

Peer reviewedPublisher PD

Nematic twist-bend phase with nanoscale modulation of molecular orientation

A state of matter in which molecules show a long-range orientational order and no positional order is called a nematic liquid crystal. The best known and most widely used (for example, in modern displays) is the uniaxial nematic, with the rod-like molecules aligned along a single axis, called the director. When the molecules are chiral, the director twists in space, drawing a right-angle helicoid and remaining perpendicular to the helix axis; the structure is called a chiral nematic. Here using transmission electron and optical microscopy, we experimentally demonstrate a new nematic order, formed by achiral molecules, in which the director follows an oblique helicoid, maintaining a constant oblique angle with the helix axis and experiencing twist and bend. The oblique helicoids have a nanoscale pitch. The new twist-bend nematic represents a structural link between the uniaxial nematic (no tilt) and a chiral nematic (helicoids with right-angle tilt)

Review: The influence of genotypic and phenotypic factors on the comfort and welfare rates of cows during the period of global climate changes

Saabunud / Received 21.03.2021 ; Aktsepteeritud / Accepted 04.06.2021 ; Avaldatud veebis / Published online 04.06.2021 ; Vastutav autor / Corresponding author: Oleksandr O. Borshch [email protected] study of the influence of weather phenomena on behavioural and physiological processes plays an important role in the development of highly effective methods of dairy farming management. Climate and weather factors have important signification in the system of interaction "organism-environment". One of the main factors of cows’ comfort improvement in different types of premises, on ground runs and pastures is the creation of such indicators of microclimate that would best meet the biological needs of dairy cows, depending on the season and productivity. Due to the constant metabolic processes, the body of cattle is very hurtable to ambient temperature. This is especially felt during periods of prolonged low or high-temperature shocks. Disorders of metabolic and thermoregulatory processes directly affect the duration and nature of behavioural and physiological reactions and cause stress in animals. Prolonged temperature stress is the reason for fluctuations in productivity, quality of milk and problems with reproduction and together significantly affect the profitability of production. To reduce the impact of temperature stress on the body of dairy cows, scientists have proposed management strategies during periods of high and low-temperature shock. These strategies are divided into genotypic: the selection of heat-resistant individuals of different breeds and phenotypic: the use of microclimate control methods and modernization of feeding management methods. The effect of temperature stress on the body of dairy cows can be minimized due to genotypic (breeding of heat-resistant breeds) and phenotypic factors (water irrigation systems, ventilation, and the use of shade shaded shelters in summer and insulation of side curtains in winter), or a combination thereof. The purpose of this article is to summarize existing knowledge about the effects of temperature stress on the health, productivity and comfort rates of cows and to discuss management strategies that would mitigate the effects of these factors

Bioenergetic and ethological features of the first-calf heifers of different genotypes

The aim of this work was to study bioenergetic and ethological indicators in crossbred first-calf heifers compared to purebred first-calf heifers. The research was conducted on the first-calf heifers of Ukrainian Black-Pied dairy breed and first-generation crossbreeds obtained as a result of crossing with Brown Swiss breed, as well as, on the first-calf heifers of Ukrainian Red-Pied dairy breed and first-generation crossbreeds obtained as a result of crossing Ukrainian Red-Pied dairy with Montbéliarde breed. The purebred Black-and Red-Pied first-calf heifers prevailed over crossbreed first-calf heifers on the indicator of milk yield for 305 days of lactation by 106.45 and 218.36 kg, respectively. Accordingly, the indicators of average daily milk yield were also higher by 0.35 and 0.72 kg and the indicators of average daily milk yield adjusted by 4 % fat content per 0.15 and 0.16 kg. At the same time, the indicator of average fat content in milk prevailed in crossbreeds of Black-Pied and Brown Swiss breed by 0.08 % compared to purebred Black-Pied breeds, and in Red-Pied crossbreeds with Montbéliarde breed by 0.16 % compared to purebred Red-Pied breeds. The purebred Black-Pied first-calf heifers had an advantage by 2.04 MJ compared to crossbreeds, while the Red-Pied first-calf heifers had a slight advantage by 0.06 MJ compared to crossbreed first-calf heifers on the indicator of daily cost of exchange energy (EE). The purebred Black-and Red-Pied first-calf heifers had higher cost of exchange energy allocated with milk compared to crossbreed first-calf heifers by 0.42 and 0.82 MJ. They also had higher cost of exchange energy rates for heat products by 0.79 and 0.25 MJ. According to the energy index indicator, purebred Black - and Red-Pied first-calf heifers prevailed over crossbreeds first-calf heifers by 0.16 and 0.07 %, respectively. The same trend was observed in relation to the productive index indicator. The purebred Black-and Red-Pied first-calf heifers had a slight advantage by 0.001 and 0.002 kg adjusted by 4 % of milk fat content per 1 MJ. According to the indicators of daily behavioral reactions, no special differences between a purebred and crossbreed were found