161 research outputs found
Guided flows in coronal magnetic flux tubes
There is evidence for coronal plasma flows to break down into fragments and
to be laminar. We investigate this effect by modeling flows confined along
magnetic channels. We consider a full MHD model of a solar atmosphere box with
a dipole magnetic field. We compare the propagation of a cylindrical flow
perfectly aligned to the field to that of another one with a slight
misalignment. We assume a flow speed of 200 km/s, and an ambient magnetic field
of 30 G. We find that while the aligned flow maintains its cylindrical symmetry
while it travels along the magnetic tube, the misaligned one is rapidly
squashed on one side, becoming laminar and eventually fragmented because of the
interaction and backreaction of the magnetic field. This model could explain an
observation of erupted fragments that fall back as thin and elongated strands
and end up onto the solar surface in a hedge-like configuration, made by the
Atmospheric Imaging Assembly on board the Solar Dynamics Observatory. The
initial alignment of plasma flow plays an important role in determining the
possible laminar structure and fragmentation of flows while they travel along
magnetic channels.Comment: 11 pages, 8 figures, accepted for publication, movies available upon
request to the first autho
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<p>Antibody responses and protection of offspring when mothers were immunized via the IN route and their offspring via the IN route<a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0157041#t004fn001" target="_blank"><sup>a</sup></a>.</p
Highly Efficient and Scalable Compound Decomposition of Two-Electron Integral Tensor and Its Application in Coupled Cluster Calculations
The
representation and storage of two-electron integral tensors
are vital in large-scale applications of accurate electronic structure
methods. Low-rank representation and efficient storage strategy of
integral tensors can significantly reduce the numerical overhead and
consequently time-to-solution of these methods. In this work, by combining
pivoted incomplete Cholesky decomposition (CD) with a follow-up truncated
singular vector decomposition (SVD), we develop a decomposition strategy
to approximately represent the two-electron integral tensor in terms
of low-rank vectors. A systematic benchmark test on a series of 1-D,
2-D, and 3-D carbonāhydrogen systems demonstrates high efficiency
and scalability of the compound two-step decomposition of the two-electron
integral tensor in our implementation. For the size of the atomic
basis set, <i>N</i><sub><i>b</i></sub>, ranging
from ā¼100 up to ā¼2,000, the observed numerical scaling
of our implementation shows O(Nb2.5ā3) versus O(Nb3ā4) cost of performing single CD on the two-electron
integral tensor in most of the other implementations. More importantly,
this decomposition strategy can significantly reduce the storage requirement
of the atomic orbital (AO) two-electron integral tensor from O(Nb4) to O(Nb2ā”log(Nb)) with moderate decomposition thresholds.
The accuracy tests have been performed using ground- and excited-state
formulations of coupled cluster formalism employing single and double
excitations (CCSD) on several benchmark systems including the C<sub>60</sub> molecule described by nearly 1,400 basis functions. The
results show that the decomposition thresholds can be generally set
to 10<sup>ā4</sup> to 10<sup>ā3</sup> to give acceptable
compromise between efficiency and accuracy
A High-Dimensional Nonparametric Multivariate Test for Mean Vector
<p>This work is concerned with testing the population mean vector of nonnormal high-dimensional multivariate data. Several tests for high-dimensional mean vector, based on modifying the classical Hotelling <i>T</i><sup>2</sup> test, have been proposed in the literature. Despite their usefulness, they tend to have unsatisfactory power performance for heavy-tailed multivariate data, which frequently arise in genomics and quantitative finance. This article proposes a novel high-dimensional nonparametric test for the population mean vector for a general class of multivariate distributions. With the aid of new tools in modern probability theory, we proved that the limiting null distribution of the proposed test is normal under mild conditions when <i>p</i> is substantially larger than <i>n</i>. We further study the local power of the proposed test and compare its relative efficiency with a modified Hotelling <i>T</i><sup>2</sup> test for high-dimensional data. An interesting finding is that the newly proposed test can have even more substantial power gain with large <i>p</i> than the traditional nonparametric multivariate test does with finite fixed <i>p</i>. We study the finite sample performance of the proposed test via Monte Carlo simulations. We further illustrate its application by an empirical analysis of a genomics dataset. Supplementary materials for this article are available online.</p
Electrophilic Rearrangements of Chiral Amides: A Traceless Asymmetric Ī±āAllylation
A one-pot protocol for the asymmetric
Ī±-allylation reaction
is reported relying on a key efficient asymmetric Claisen rearrangement,
triggered by electrophilic activation of chiral pseudoephedrine amides.
Subsequent reduction or hydrolysis of the resulting iminium ions provides
highly enantioenriched Ī±-allylic aldehydes or carboxylic acids
in a traceless manner. Compared to traditional alternatives which
make use of strongly basic conditions, the work presented herein displays
unprecedented functional group tolerance
Direct Observation of the Formation of Liquid Protrusions on Polymer Colloids and their Coalescence
Monodisperse
nonspherical poly (methyl methacrylate) (PMMA) particles
where a central core particle had grown two extra ālobesā,
or protrusions, placed opposite each other were successfully synthesized
by swelling and subsequent polymerization of cross-linked PMMA spheres
with methyl methacrylate and the cross-linker ethylene glycol dimethacrylate.
The use of large (ā¼3 Ī¼m) seed particles allowed for real-time
monitoring of the swelling and deswelling of the cross-linked particles
with optical microscopy. First, a large number of small droplets of
swelling monomers formed simultaneously on the surface of the seed
particles, and then fused together until under certain conditions
two protrusions remained on opposite sides of the seed particles.
The yield of such particles could be made up to 90% with a polydispersity
of 7.0%. Stirring accelerated the transfer of the swelling monomers
to the seed particles. Stirring was also found to induce self-assembly
of the swollen seed particles into a wide variety of <i>n</i>-mers, consisting of a certain number, <i>n</i>, of swollen
seed particles. The formation of these structures is guided by the
minimization of the interfacial free energy between the seed particles,
liquid protrusions and aqueous phase, but stirring time and geometrical
factors influence it as well. By inducing polymerization the structures
could be made permanent. Some control over the topology as well as
overall size of the clusters was achieved by varying the stirring
time before polymerization. 3D models of possible particle structures
were used to identify all projections of the structures obtained by
scanning electron microscopy. These models also revealed that the
seed particles inside the central coalesced body were slightly compressed
after polymerization. By extending the synthesis of the monodisperse
particles with <i>n</i> = 1 to (slightly) different monomers
and/or different cores, an important class of patchy particles could
be realized
The Litvinenko case and its reflection in The Daily Telegraph
This bachelor thesis studies the manner in which the case of the former Russian spy Alexander LitvinÄnko's poisoning was handled in 2006 by the British newspaper The Daily Telegraph. Both quantitative and qualitative analyses have been used for that purpose. The theoretical part of the thesis explains the factors influencing the process of encoding of the meanings into mediated contents, and the process of their subsequent decoding by the public. The analytical part presents a detailed description of how the concrete news texts on the Litvinenko case published by The Daily Telegraph could have been perceived by their recipient. Hypotheses have been set for the analysis; the confirmation or denial of their validity outlines The Daily Telegraph's methods of news reporting production and the terms in which the news texts are conceived in this newspaper
Direct Observation of the Formation of Liquid Protrusions on Polymer Colloids and their Coalescence
Monodisperse
nonspherical poly (methyl methacrylate) (PMMA) particles
where a central core particle had grown two extra ālobesā,
or protrusions, placed opposite each other were successfully synthesized
by swelling and subsequent polymerization of cross-linked PMMA spheres
with methyl methacrylate and the cross-linker ethylene glycol dimethacrylate.
The use of large (ā¼3 Ī¼m) seed particles allowed for real-time
monitoring of the swelling and deswelling of the cross-linked particles
with optical microscopy. First, a large number of small droplets of
swelling monomers formed simultaneously on the surface of the seed
particles, and then fused together until under certain conditions
two protrusions remained on opposite sides of the seed particles.
The yield of such particles could be made up to 90% with a polydispersity
of 7.0%. Stirring accelerated the transfer of the swelling monomers
to the seed particles. Stirring was also found to induce self-assembly
of the swollen seed particles into a wide variety of <i>n</i>-mers, consisting of a certain number, <i>n</i>, of swollen
seed particles. The formation of these structures is guided by the
minimization of the interfacial free energy between the seed particles,
liquid protrusions and aqueous phase, but stirring time and geometrical
factors influence it as well. By inducing polymerization the structures
could be made permanent. Some control over the topology as well as
overall size of the clusters was achieved by varying the stirring
time before polymerization. 3D models of possible particle structures
were used to identify all projections of the structures obtained by
scanning electron microscopy. These models also revealed that the
seed particles inside the central coalesced body were slightly compressed
after polymerization. By extending the synthesis of the monodisperse
particles with <i>n</i> = 1 to (slightly) different monomers
and/or different cores, an important class of patchy particles could
be realized
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Five-axis contour error estimation based on multi-Information dynamic time warping
No description supplied</p
Five-axis contour error estimation based on multi-Information dynamic time warping
Contour accuracy is crucial for machining precision in five-axis computer numerical control (CNC) machining. This paper addresses the challenge of improving contour accuracy by proposing a novel contour error estimation and compensation method based on dynamic time warping (DTW). By incorporating time information and geometric characteristics of the machining path, the proposed method introduces a multiple-information fusion algorithm to define distance characteristics between the planned and actual trajectory sequences. This allows the calculation of a distortion path and the establishment of a mapping model between the two sequences. To mitigate the effect of DTW singularity on contour error estimation, a mapping model is established between line segments to determine reference points. The position contour error and the direction contour error of the five-axis tool are accurately estimated using segmented Hermite interpolation, and a spatial iterative learning framework is employed to compensate for them. Experimental results demonstrate the effectiveness of the proposed method in dealing with estimation errors in complex trajectories and its good performance in improving contour accuracy. Note to Practitioners āThis paper proposes an effective strategy for the estimation of contour errors in five-axis machining. Currently, most methods for contour error estimation in five-axis machining are based on the nearest point principle. However, this approach fails to accurately estimate contour errors for complex trajectories with significant curvature variations, leading to ineffective contour error compensation in subsequent stages. Therefore, we introduce a contour error estimation algorithm based on DTW. This algorithm takes into account the time information and geometric features of the machining path. Experimental results validate the feasibility and advantages of this approach.</p
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