6 research outputs found
Peelback of highly oriented cellulosic fibres
International audienc
Rheological behavior of cellulose/monohydrate of N-methylmorpholine N-oxide solutions. Part 2. Glass transition domain
International audienc
Improvement of adhesion between polyethylene and regenerated cellulose fibers by surface fibrillation
International audienc
Rheological behavior of cellulose / monohydrate of N-methyl morpholine N-oxide solutions. Part I: liquid state
International audienc
Anisotropy of structure and transport properties in sulfonated polyimide membranes
cited By 56International audienceAn original analysis of the structure of ionomer films along the three dimensions using micro small-angle X-ray scattering (microSAXS) technique is reported. While the in-plane structure appeared as isotropic, a significant SAXS anisotropy was observed in the transverse direction, revealing a multiscale structural anisotropy from the molecular level to several tens of nanometers. Using transmission and scanning electron microscopy (TEM and SEM, respectively), a layered structure was identified up to micrometer scales. This structural anisotropy was used to interpret the conductivity data as a function of the ion content. Moreover, the diffusion coefficients of the counterions, were determined along the planar and transverse directions using pulse field gradient spin echo-NMR (PFGSE-NMR) in order to correlate structure and transport properties. © 2002 Elsevier Science B.V. All rights reserved