Starburst and cirrus models for submillimeter galaxies

We present radiative transfer models for submillimeter galaxies with spectroscopic redshifts and mid-infrared spectroscopy from Spitzer/IRS and analyze available Spitzer/MIPS 24, 70 and 160mu data. We use two types of starburst models, a cirrus model and a model for the emission of an AGN torus in order to investigate the nature of these objects. We find that for three of the objects (25%) cirrus emission alone can account for the mid-infrared spectrum and the MIPS and submillimeter data. For the remaining objects we find that we need a combination of starburst and cirrus in order to fit simultaneously the multi--wavelength data. We find that the typical submillimeter galaxy has comparable luminosity in the starburst (median L=10^12.5 Lo) and cirrus (median L=10^12.4 Lo) components. This could arise if the galaxies have been forming stars continuously for the last 250Myr with the star formation occurring in the last 5Myr being shrouded by high-optical-depth molecular cloud dust, whereas the rest of the starlight is attenuated by diffuse dust or cirrus with an Av of about 1mag.Comment: 9 pages, AA accepte

Carbon–Carbon Bond-Forming Reactions of α-Thioaryl Carbonyl Compounds for the Synthesis of Complex Heterocyclic Molecules

Strategies for the formation of carbon–carbon bonds from the α-thioaryl carbonyl products of substituted lactams are described. Although direct functionalization is possible, a two step process of oxidation and magnesium-sulfoxide exchange has proven optimal. The oxidation step results in the formation of two diastereomers that exhibit markedly different levels of stability toward elimination, which is rationalized on the basis of quantum mechanical calculations and X-ray crystallography. Treatment of the sulfoxide with <i>i</i>-PrMgCl results in the formation of a magnesium enolate that will undergo an intramolecular Michael addition reaction to form two new stereogenic centers. The relationship between the substitution patterns of the sulfoxide substrate and the efficiency of the magnesium exchange reaction are also described

Carbon–Carbon Bond-Forming Reactions of α-Thioaryl Carbonyl Compounds for the Synthesis of Complex Heterocyclic Molecules

Strategies for the formation of carbon–carbon bonds from the α-thioaryl carbonyl products of substituted lactams are described. Although direct functionalization is possible, a two step process of oxidation and magnesium-sulfoxide exchange has proven optimal. The oxidation step results in the formation of two diastereomers that exhibit markedly different levels of stability toward elimination, which is rationalized on the basis of quantum mechanical calculations and X-ray crystallography. Treatment of the sulfoxide with <i>i</i>-PrMgCl results in the formation of a magnesium enolate that will undergo an intramolecular Michael addition reaction to form two new stereogenic centers. The relationship between the substitution patterns of the sulfoxide substrate and the efficiency of the magnesium exchange reaction are also described