13 research outputs found
(2S)-2-[(2S*,5R*,6R*)-5,6-Dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl]-1-[(S)-1,1-dimethylethylsulfonyl]aziridine
The reaction of a sulfur ylide with a chiral non-racemic sulfinyl imine afforded the desired aziridine in excellent yield and subsequent oxidation of the sulfinyl moiety dissolved in anhydrous dichloromethane using a 75% aqueous solution of 3-chloroperoxybenzoic acid afforded the title compound, C14H27NO6S. The configuration of the newly formed stereogenic center at the point of attachment of the 1,4-dioxane ring to the aziridine ring is S. The configurations of the pre-existing sites 2-, 5-, and 6-positions of the 1,4-dioxane ring prior to reaction of sulfinyl imine with the sulfur ylide are S, R, and R, respectively. The C—N bond lengths of the aziridine are 1.478 (2) and 1.486 (2) Å
Measurement of p + d -> 3He + eta in S(11) Resonance
We have measured the reaction p + d -> 3He + eta at a proton beam energy of
980 MeV, which is 88.5 MeV above threshold using the new ``germanium wall''
detector system. A missing--mass resolution of the detector system of 2.6% was
achieved. The angular distribution of the meson is forward peaked. We found a
total cross section of (573 +- 83(stat.) +- 69(syst.))nb. The excitation
function for the present reaction is described by a Breit Wigner form with
parameters from photoproduction.Comment: 8 pages, 2 figures, corrected typos in heade