7 research outputs found
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Technoeconomic and life-cycle analysis of single-step catalytic conversion of wet ethanol into fungible fuel blendstocks
Technoeconomic and life-cycle analyses are presented for catalytic conversion of ethanol to fungible hydrocarbon fuel blendstocks, informed by advances in catalyst and process development. Whereas prior work toward this end focused on 3-step processes featuring dehydration, oligomerization, and hydrogenation, the consolidated alcohol dehydration and oligomerization (CADO) approach described here results in 1-step conversion of wet ethanol vapor (40 wt% in water) to hydrocarbons and water over a metal-modified zeolite catalyst. A development project increased liquid hydrocarbon yields from 36% of theoretical to >80%, reduced catalyst cost by an order of magnitude, scaled up the process by 300-fold, and reduced projected costs of ethanol conversion 12-fold. Current CADO products conform most closely to gasoline blendstocks, but can be blended with jet fuel at low levels today, and could potentially be blended at higher levels in the future. Operating plus annualized capital costs for conversion of wet ethanol to fungible blendstocks are estimated at 1.44/GJ in the future, similar to the unit energy cost of producing anhydrous ethanol from wet ethanol (100 per barrel but not at 60 per barrel. Life-cycle greenhouse gas emission reductions for CADO-derived hydrocarbon blendstocks closely follow those for the ethanol feedstock
Exploring Comparative Energy and Environmental Benefits of Virgin, Recycled, and Bio-Derived PET Bottles
Polyethylene terephthalate (PET)
is a common plastic resin used
to produce packaging, notably plastic bottles. Most PET bottles are
produced from fossil fuel-derived feedstocks. Bio-derived and recycling-based
pathways to PET bottles, however, could offer lower greenhouse gas
(GHG) emissions than the conventional route. In this paper, we use
life-cycle analysis to evaluate the GHG emissions, fossil fuel consumption,
and water consumption of producing one PET bottle from virgin fossil
resources, recycled plastic, and biomass, considering each supply
chain stage. We considered two routes to produce bottles from biomass:
one in which all PET precursors (ethylene glycol and teraphthalic
acid) are bio-derived and one in which only ethylene glycol is bio-derived.
Bio-derived and recycled PET bottles offer both GHG emissions and
fossil fuel consumption reductions ranging from 12% to 82% and 13%
to 56%, respectively, on a cradle-to-grave basis compared to fossil
fuel-derived PET bottles assuming PET bottles are landfilled. However,
water consumption is lower in the conventional pathway to PET bottles.
Water demand is high during feedstock production and conversion in
the case of biomass-derived PET and during recycling in the case of
bottles made from recycled PET
Techno-Economic Analysis and Life-Cycle Analysis of Two Light-Duty Bioblendstocks: Isobutanol and Aromatic-Rich Hydrocarbons
Isobutanol
and aromatic-rich hydrocarbons (ARHC) are two biomass-derived
high-octane blendstocks that could be blended with petroleum gasoline
for use in optimized spark-ignition engines in light-duty vehicles,
potentially increasing engine efficiency. To evaluate technology readiness,
economic viability, and environmental impacts of these technologies,
we use detailed techno-economic analysis (TEA) and life-cycle analysis
(LCA). We assumed isobutanol is produced via biochemical conversion
of an herbaceous feedstock blend while ARHC is produced via thermochemical
conversion of a woody feedstock blend. The minimum estimated fuel
selling price (MFSP) of isobutanol ranged from 0.045/MJ) based on todayās technology to
0.034/MJ) with technology advancements. The MFSP of ARHC
could decline from 0.042/MJ) based on todayās technology
to 0.034/MJ) as technology improves. Both isobutanol and
ARHC offer about 73% greenhouse gas (GHG) emission reduction relative
to petroleum gasoline per LCA of these two bioblendstocks. On the
other hand, water consumption in the production of both bioblendstocks
exceeds that of conventional gasoline although process engineering
offers routes to cutting water consumption. Over their life-cycles,
both isobutanol and ARHC emit more NO<sub><i>x</i></sub> and PM<sub>2.5</sub> than petroleum gasoline. Improving the energy
efficiency and lowering air emissions from agricultural equipment
will reduce the life-cycle air pollutant emissions of these bioblendstocks
Sustainable Aviation Fuel from High-Strength Wastewater via Membrane-Assisted Volatile Fatty Acid Production: Experimental Evaluation, Techno-economic, and Life-Cycle Analyses
To reduce emissions from combustion of fossil fuels,
sustainable
aviation fuels (SAFs) have the potential to decarbonize the aviation
sector. Redirecting wastes from conventional waste management practices
and using them as cost-effective feedstocks for low-carbon fuels can
reduce emissions from both waste disposal and fuel combustion. One
approach is to upgrade wet wastes to SAF precursors, such as volatile
fatty acids (VFAs). In this study, novel membrane-assisted arrested
methanogenesis was developed to convert high-strength wastewater to
VFAs. Based on experimental results of VFA production, techno-economic
and life-cycle analyses were conducted to estimate the potential economic
and environmental benefits of SAF production from high-strength wastewater
via VFAs. By evaluating three proposed scenarios for VFA production,
a minimum production cost of VFA is achieved at 4.64/gasoline gallon
equivalent. The life-cycle analysis shows that up to a 71% reduction
in greenhouse gas emissions can be achieved relative to its fossil-counterpart
along with lower water and fossil-fuel consumption
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Technoeconomic and life-cycle analysis of single-step catalytic conversion of wet ethanol into fungible fuel blendstocks
Environmental, Economic, and Scalability Considerations and Trends of Selected Fuel Economy-Enhancing Biomass-Derived Blendstocks
Twenty-four
biomass-derived compounds and mixtures, identified
based on their physical properties, which could be blended into fuels
to improve spark ignition engine fuel economy, were assessed for their
economic, technology readiness, and environmental viability. These
bio-blendstocks were modeled to be produced biochemically, thermochemically,
or through hybrid processes. To carry out the assessment, 17 metrics
were developed for which each bio-blendstock was determined to be
favorable, neutral, or unfavorable. Cellulosic ethanol was included
as a reference case. Overall economic and, to some extent, environmental
viability is driven by projected yields for each of these processes.
The metrics used in this analysis methodology highlight the near-term
potential to achieve these targeted yield estimates when considering
data quality and current technical readiness for these conversion
strategies. Key knowledge gaps included the degree of purity needed
for use as a bio-blendstock. Less stringent purification requirements
for fuels could cut processing costs and environmental impacts. Additionally,
more information is needed on the blending behavior of many of these
bio-blendstocks with gasoline to support the technology readiness
evaluation. Overall, the technology to produce many of these blendstocks
from biomass is emerging, and as it matures, these assessments must
be revisited. Importantly, considering economic, environmental, and
technology readiness factors, in addition to physical properties of
blendstocks that could be used to boost engine efficiency and fuel
economy, in the early stages of project research and development can
help spotlight those most likely to be viable in the near term