Encapsulation of polyaniline in zeolite Y and mordenite

Synthetic strategies to encapsulate polyaniline in the crystalline channel system of faujasite (three-dimensional) and mordenite (one-dimensional) have been explored. The adsorption of anilinium precursor into the zeolite host and its successful oxidation to polyaniline have been studied utilizing FTIR, Fourier Transform Raman, and electronic spectroscopies. The dimensionality of the host channel system and the concentratio

Zeolite crystal layers coupled to piezoelectric sensors

Microporous zeolite crystals were successfully coupled onto the gold electrodes of quartz crystal microbalances (QCM). A self-assembled monolayer of thiol-alkoxysilane coupling agent on the gold surface was used as the interfacial layer to promote adhesion of the zeolite crystals to the QCM. The resulting, densely packed single layers of zeolite crystals were stable to at least 625 K. Transient sorption behavior of organic vapor pulses, dynamic vapor sorption isotherms and nitrogen sorption isotherms at liquid nitrogen temperature were examined to characterize the zeolite-coated QCMs. Depending on the type of zeolite coating, the resonance frequency response to vapor pulses could be increased up to 500-fold compared to the bare QCM. The regular micropores (0.3-0.8 nm) of the QCM-attached zeolite crystals were found to control molecular access into the extensive intrazeolite volume. Selectivity of the frequency response in excess of 100:1 toward molecules of different size and/or shape could be demonstrated. An additional recognition mechanism based upon intrazeolite diffusion rates was also established

Substrate effect on the growth of iron clusters in Y zeolite

Investigation of the decomposition process and of the thermolytic products obtained from Fe(CO)5/faujasite adducts by thermogravimetric, IR-spectroscopic, Mössbauer spectroscopic and X-ray absorption measurements (EXAFS) provides evidence for a substrate effect on the growth process of iron clusters. CsY substrate increases the Fe---CO bond strength. The stabilized intermediates generated by this effect upon thermolysis at 500 K are easily oxidized to small iron(III) oxide clusters, whereas with NaY substrate to a large extent iron(O) particles are generated. The latter show Mössbauer effect and EXAFS spectra comparable to those obtained from bulk iron. An inner oxidation process is assumed to be involved in the generation of the zeolite-supported iron oxide

Intrazeolite synthesis of polythiophene chains

Adsorption of thiophene and 3-methylthiophene into the channel system of transition metal-containing zeolites Y and mordenite results in oxidative polymerization to give encapsulated chains of polythiophene and poly(3-methylthiophene)