13 research outputs found
Twenty-first century fumerist : Bridget Christie and the backlash against feminist comedy
This article engages with the work of comedian Bridget Christie in relation to definitions of feminist and post-feminist comedy. The year 2013 was a highpoint in coverage and acclaim for feminist comedy and this article will explore how, at a time when the majority of female comedians operate from a post-feminist standpoint, Christie’s work seeks to politicise and galvanise her audience. The evolution of Christie’s work is explored in relation to the changes in her delivery style and the implications this has on the accessibility of her material to wider audiences. Additionally, the response of the wider U.K. comedy industry to the higher profile of feminist comedy and the reassertion of patriarchal masculinity in comedy is considered
Electronic structure, charge transfer, and intrinsic luminescence of gadolinium oxide nanoparticles: Experiment and theory
The cubic (c) and monoclinic (m) polymorphs of Gd2O3 were studied using the
combined analysis of several materials science techniques - X-ray diffraction
(XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy
(XPS), and photoluminescence (PL) spectroscopy. Density functional theory (DFT)
based calculations for the samples under study were performed as well. The
cubic phase of gadolinium oxide (c-Gd2O3) synthesized using a precipitation
method exhibits spheroidal-like nanoclusters with well-defined edges assembled
from primary nanoparticles with an average size of 50 nm, whereas the
monoclinic phase of gadolinium oxide (m-Gd2O3) deposited using explosive
pyrolysis has a denser structure compared with natural gadolinia. This phase
also has a structure composed of three-dimensional complex agglomerates without
clear-edged boundaries that are ~21 nm in size plus a cubic phase admixture of
only 2 at. % composed of primary edge-boundary nanoparticles ~15 nm in size.
These atomic features appear in the electronic structure as different defects
([Gd...O-OH] and [Gd...O-O]) and have dissimilar contributions to the
charge-transfer processes among the appropriate electronic states with
ambiguous contributions in the Gd 5p - O 2s core-like levels in the valence
band structures. The origin of [Gd...O-OH] defects found by XPS was
well-supported by PL analysis. The electronic and atomic structures of the
synthesized gadolinias calculated using DFT were compared and discussed on the
basis of the well-known joint OKT-van der Laan model, and good agreement was
established.Comment: 27 pages, 10 figures, accepted in Appl. Surf. Sc