Analysis of rock mechanical parameters from well log data and Dipole Shear sonic Imager. Application to Algerian sahara "Algeria"

The use of 'DSI' (Dipole Shear sonic Imager), in the Tin Fouye Tabankort area in Algeria allowed the exploitation of the rock mechanics properties in the field of drilling having for objective determination of the margin of ability of the well. The tool 'DSI' has a considerable advantage by its application which makes it possible to combine the technology of monopole and of dipole and to offer an effective method for the determination of the acoustic dynamic mechanical properties in - situ. The practical results of this study showed that: 1 - The phenomenon of BIOT is less when the medium is impermeable, 2- There is a significant effect of the petrophysic properties on the mechanical properties expressed by the effect of the coefficient of BIOT on the variation of the values of the density of mud. The beach of variation of the stability of the well obtained starting from the tool 'DSI' lies between the values 1.40 g/cc and 1.80 g/cc. On the other hand the results obtained by the application of Leake-off test and the successive increase in the density of mud vary from 1.50 g/cc with 1.90 g/cc. With the base of these results, it is necessary to note that the result obtained by tool DSI is almost closer than the practical methods and the percentage of error obtained by the application of this tool is due to the difference between the dynamic and static mechanical properties. The finality of this study is to determine a field of application of this new technique in the study of the stability of the well during drillin

COMPETING MECHANISMS OF MOLECULAR HYDROGEN FORMATION IN CONDITIONS RELEVANT TO THE INTERSTELLAR MEDIUM

International audienceThe most efficient mechanism of the formation of molecular hydrogen in the current universe is by association of hydrogen atoms on the surface of interstellar dust grains. The details of the processes of its formation and release from the grain are of great importance in the physical and chemical evolution of the space environmentswhere it takes place. Themain puzzle is still the fate of the 4.5 eV released in H2 formation and whether it goes into internal energy (rovibrational excitation), translational kinetic energy, or heating of the grain. The modality of the release of this energy affects the dynamics of the ISM and its evolution toward star formation.We present results of the detection of the rovibrational states of the just-formed H2 as it leaves the surface of a silicate.We find that rovibrationally excited molecules are ejected into the gas phase immediately after formation over a much wider range of grain temperatures than anticipated. Our results can be explained by the presence of twomechanisms ofmolecule formation that operate in partially overlapping ranges of grain temperature. A preliminary analysis of the relative importance of these two mechanisms is given. These unexpected findings, which will be complemented with experiments on the influence of factors such as silicate morphology, should be of great interest to the astrophysics and astrochemistry communities

Ab initio simulations of the kinetic properties of the hydrogen monomer on graphene

The understanding of the kinetic properties of hydrogen (isotopes) adatoms on graphene is important in many fields. The kinetic properties of hydrogen-isotope (H, D and T) monomers were simulated using a composite method consisting of density functional theory, density functional perturbation theory and harmonic transition state theory. The kinetic changes of the magnetic property and the aromatic $\pi$ bond of the hydrogenated graphene during the desorption and diffusion of the hydrogen monomer was discussed. The vibrational zero-point energy corrections in the activation energies were found to be significant, ranging from 0.072 to 0.205 eV. The results obtained from quantum-mechanically modified harmonic transition state theory were compared with the ones obtained from classical-limit harmonic transition state theory over a wide temperature range. The phonon spectra of hydrogenated graphene were used to closely explain the (reversed) isotope effects in the prefactor, activation energy and jump frequency of the hydrogen monomer. The kinetic properties of the hydrogen-isotope monomers were simulated under conditions of annealing for 10 minutes and of heating at a constant rate (1.0 K/s). The isotope effect was observed; that is, a hydrogen monomer of lower mass is desorbed and diffuses more easily (with lower activation energies). The results presented herein are very similar to other reported experimental observations. This study of the kinetic properties of the hydrogen monomer and many other involved implicit mechanisms provides a better understanding of the interaction between hydrogen and graphene.Comment: Accepted by J. Phys. Chem.

A sedimentological approach to refining reservoir architecture using the well log data and core analysis in the saharan platform of algeria

Improved reservoir characterisation in the mature oil applied to Gourara Field of Sahara in Algeria, aimed at maximising both in-field and near-field hydrocarbon potential, requires a clearer understanding of sub-seismic stratigraphy and facies distributions. In this context, we present a regional, high-resolution sequence stratigraphic framework for the Oued Namouss Field based on extensive sedimentological re-interpretation of core and wireline log data, combined with core analysis and published literature. This framework is used to place individual reservoirs in an appropriate regional context, thus resulting in the identification of subtle sedimentological and tectono-stratigraphic features of reservoir architecture that have been previously overlooked. We emphasise the following insights gained from our regional, high-resolution sequence stratigraphic synthesis: (1) improved definition of temporal and spatial trends in deposition both within and between individual reservoirs, (2) development of regionally consistent, predictive sedimentological models for two enigmatic reservoir intervals (the Formations I and II), and (3) recognition of subtle local tectono-stratigraphic controls on reservoir architecture, and their links to the regional structural evolution of the Province. We discuss the potential applications of these insights to the identification of additional exploration potential and to improved ultimate recovery.In this research a procedure was developed to assess and quantify uncertainties in hydrocarbon estimates related to depositional facies, petrophysical data and gross reservoir volumes. This procedure was applied to the Gourara Field, which is a mature gas field in the Oued Namous Basin, Algeria. The aim was to investigate the reasons for an unexpectedly high hydrocarbon recovery facto

Facies analysis of triassic formations of the Hassi R’Mel in southern algeria using well logs : recognition of paleosols using log analysis

Well logs are essential in the study of geological formations, in terms of taking into account the nature and the structure of the formations, as well as the sedimentary processes. Qualitative and quantitative interpretations of well logs respond to a sedimentologic need as well as the establishment of lithological columns, according to the response to logging tools. In this study, electrofacies have been defined by manual well-log analysis of ten surveys of Triassic formations in the Hassi R'Mel area of Algeria. The data thus obtained were then matched with sedimentary facies defined by core analysis. The results obtained during the facies analysis made it possible to define ten electrofacies (sands, shale, dolomite, and evaporite, as well as the presence of andesite and clay). The model obtained by the Petrolog software was also developed and tested on other wells. A semi-automatic data processing was then carried out on seven other wells.Our aim is to highlight the added value of this integrated regional-scale to reservoir-scale approach in identifying nearfield exploration potential and additional recovery opportunities in producing reservoirs. Based on this aim, we emphasise the following points using our facies modelling: (1) improved definition of deposition within and between reservoirs, (2) development of regionally sedimentological models for reservoir intervals (the Hassi R’Mel Formations), and (3) recognition of paleosols from well log analysis and controls on reservoir architecture and their links to the Triassic Province of Algeri

Experimental H2O formation on carbonaceous dust grains attemperatures up to 85 K

International audienceWater represents the main component of the icy mantles on dust grains, it is of extreme importance for the formation of new species and it represents the main component for life. Water is observed both in the gas-phase and frozen in the interstellar medium (ISM), where the solid-phase formation route has been proven essential to explain abundances in molecular clouds. So far, experiments have focused on very low temperatures (around 10 K). We present the experimental evidence of solid water formation on coronene, PAH-like surface, for a higher range of temperatures. Water is efficiently formed up to 85 K through the interaction of oxygen and hydrogen atomic beams with a carbonaceous grain analogue. The beams are aimed towards the surface connected to a cryostat exploring temperatures from 10 to 100 K. The results are obtained with a QMS and analysed through a temperature-programmed desorption technique. We observe an efficient water formation on coronene from 10 up to 85 K mimicking the temperature conditions from the dense ISM to translucent regions, where the ice mantle onset is supposed to start. The results show the catalytic nature of coronene and the role of chemisorption processes. The formation of the icy mantles could be happening in less dense and warmer environments, helping explaining oxygen depletion in the ISM. The findings have several applications such as the disappearance of PAHs in translucent regions and the snowlines of protoplanetary discs. We stress on how JWST projects characterizing PAHs can be combined with H2O observations to study water formation at warm temperatures

Efficient formation route of the prebiotic molecule formamide on interstellar dust grains

International audienceInterstellar Complex Organic Molecules are thought to be the building blocks of more complex pre-biotic compounds. In particular, formamide (or methanimide, NH 2 CHO), is presented as a multifunctional pre-biotic precursor, the starting point of both pre-genetic and pre-metabolic species. NH 2 CHO is widely observed in different astrophys-ical media, as well as in comets that may have had a crucial role in the delivery of exogenous material to Earth. In star forming regions, gas phase synthesis of for-mamide is possible, even if it is still debated. In this paper, we present laboratory experiments demonstrating formamide formation in interstellar ice analogues at astronomically relevant temperatures via simultaneous hydrogenation of NO and H 2 CO, two abundant molecules in star-forming regions. Inclusion of the experimental results in an astrochemical gas-grain model confirms the importance of the investigated solid-state reaction channel leading a high yield of formamide in dark interstellar clouds, and adds a valuable perspective about the way this refractory molecule may have been part of the pre-biotic molecular building blocks delivered to the young Earth

Experimental H2O formation on carbonaceous dust grains attemperatures up to 85 K

International audienceWater represents the main component of the icy mantles on dust grains, it is of extreme importance for the formation of new species and it represents the main component for life. Water is observed both in the gas-phase and frozen in the interstellar medium (ISM), where the solid-phase formation route has been proven essential to explain abundances in molecular clouds. So far, experiments have focused on very low temperatures (around 10 K). We present the experimental evidence of solid water formation on coronene, PAH-like surface, for a higher range of temperatures. Water is efficiently formed up to 85 K through the interaction of oxygen and hydrogen atomic beams with a carbonaceous grain analogue. The beams are aimed towards the surface connected to a cryostat exploring temperatures from 10 to 100 K. The results are obtained with a QMS and analysed through a temperature-programmed desorption technique. We observe an efficient water formation on coronene from 10 up to 85 K mimicking the temperature conditions from the dense ISM to translucent regions, where the ice mantle onset is supposed to start. The results show the catalytic nature of coronene and the role of chemisorption processes. The formation of the icy mantles could be happening in less dense and warmer environments, helping explaining oxygen depletion in the ISM. The findings have several applications such as the disappearance of PAHs in translucent regions and the snowlines of protoplanetary discs. We stress on how JWST projects characterizing PAHs can be combined with H2O observations to study water formation at warm temperatures

Hydrogenation of CO-bearing species on grains: Unexpected chemical desorption of CO

International audienc