A holistic multimodal approach to the non-invasive analysis of watercolour paintings

A holistic approach using non-invasive multimodal imaging and spectroscopic techniques to study the materials (pigments, drawing materials and paper) and painting techniques of watercolour paintings is presented. The non-invasive imaging and spectroscopic techniques include VIS-NIR reflectance spectroscopy and multispectral imaging, micro-Raman spectroscopy, X-ray fluorescence spectroscopy (XRF) and optical coherence tomography (OCT). The three spectroscopic techniques complement each other in pigment identification. Multispectral imaging (near infrared bands), OCT and micro-Raman complement each other in the visualisation and identification of the drawing material. OCT probes the microstructure and light scattering properties of the substrate while XRF detects the elemental composition that indicates the sizing methods and the filler content . The multiple techniques were applied in a study of forty six 19th century Chinese export watercolours from the Victoria & Albert Museum (V&A) and the Royal Horticultural Society (RHS) to examine to what extent the non-invasive analysis techniques employed complement each other and how much useful information about the paintings can be extracted to address art conservation and history questions

Prevalence of sulfonamide resistance genes in bacterial isolates from manured agricultural soils and pig slurry in the United Kingdom

Prevalence of three sulfonamide resistance genes, sul1, sul2 and sul3 and sulfachloropyridazine (SCP) resistance was determined in bacteria isolated from UK manured agricultural clay soils and slurry samples, over a two year period. Slurry from tylosin-fed pigs amended with SCP and oxytetracycline (OTC) was used for manuring. Sul gene positive isolates were further screened for the presence of class 1 and 2 integrons. Phenotypic resistance to SCP was significantly higher in pig slurry and post application soil than in pre-application soil. Of 5isolates, 23 % carried sul1, 18 % sul2 and 9 % sul3 only. Two percent of isolates contained all three sul genes. Class 1 and class 2 integrons were identified in 5 % and 11.7 % of sul positive isolates. In previous reports, sul1 was linked to class 1 integrons, but in this study only 8 % of sul1 positive isolates carried the intI1 gene. Sulfonamide resistant pathogens were identified in slurry amended soil and soil leachate, including Shigella flexneri, Aerococcus spp. and Acinetobacter baumanni, suggesting a potential environmental reservoir. Sulfonamide resistance in Psychrobacter, Enterococcus and Bacillus spp. is reported for the first time, and this study also provides the first description of the genotype sul1, sul2 and sul3 outside the Enterobacteriacae, and in the soil environment

Behaviour of composite slab-beam systems at elevated temperatures: Experimental and numerical investigation

This paper presents the experimental observations and results of three one-quarter scale composite slab-beam systems, 3.15 m by 3.15 m in plan, and tested in fire conditions. The tests aimed to examine the effects of unprotected interior secondary beams and edge rotational restraint on the behaviour of floor assemblies. The test results show that continuity of reinforcement in the slab over the supporting beams, and the presence of interior beams, can reduce the slab deflection and enhance its load-bearing capacity. Interior beams can be left unprotected without leading to a structural failure. The interior beams play a major role in helping the slab to move from biaxial bending stage to membrane behaviour, enabling the slab to mobilize higher tensile membrane forces. Rotational restraint along the protected edge beams induces intense stress concentration above these beams, resulting in more severe concrete crushing at the four corners and wide cracks over the edge beams. In addition to the experimental study, a numerical model using ABAQUS has been developed to simulate the tests. The numerical predictions agree well with the experimental results, showing that the proposed model is reliable. A shortcoming of the study is that the fire resistance performance of the specimens cannot be compared with those in practical design because a real furnace fire and small-scale fire tests were used due to limits of the furnace. However, the experimental results do provide basic information on the membrane behaviour in fire and also allow analytical methods and numerical models to be validated

Integron prevalence and diversity in manured soil

Integron abundance and diversity were studied in soil amended with pig slurry. Real-time PCR illustrated a significant increase in class 1 integron prevalence post slurry-application with increased prevalence still evident at 10 months post-application. Culture dependent data revealed 10 genera, including putative human pathogens, carrying class 1 and 2 integrons

Principal Component Analysis with Noisy and/or Missing Data

We present a method for performing Principal Component Analysis (PCA) on noisy datasets with missing values. Estimates of the measurement error are used to weight the input data such that compared to classic PCA, the resulting eigenvectors are more sensitive to the true underlying signal variations rather than being pulled by heteroskedastic measurement noise. Missing data is simply the limiting case of weight=0. The underlying algorithm is a noise weighted Expectation Maximization (EM) PCA, which has additional benefits of implementation speed and flexibility for smoothing eigenvectors to reduce the noise contribution. We present applications of this method on simulated data and QSO spectra from the Sloan Digital Sky Survey.Comment: Accepted for publication in PASP; v2 with minor updates, mostly to bibliograph

Solar System: Sifting through the debris

A quadrillion previously unnoticed small bodies beyond Neptune have been spotted as they dimmed X-rays from a distant source. Models of the dynamics of debris in the Solar System's suburbs must now be reworked.Comment: 3 pages, 1 figure; Nature News and Views on Chang et al. 2006, Nature, 442, 660-66

qq-Trinomial identities

We obtain connection coefficients between $q$-binomial and $q$-trinomial coefficients. Using these, one can transform $q$-binomial identities into a $q$-trinomial identities and back again. To demonstrate the usefulness of this procedure we rederive some known trinomial identities related to partition theory and prove many of the conjectures of Berkovich, McCoy and Pearce, which have recently arisen in their study of the $\phi_{2,1}$ and $\phi_{1,5}$ perturbations of minimal conformal field theory.Comment: 21 pages, AMSLate

Parallax and Distance Estimates for Fourteen Cataclysmic Variable Stars

I used the 2.4 m Hiltner telescope at MDM Observatory in an attempt to measure trigonometric parallaxes for 14 cataclysmic variable stars. Techniques are described in detail. In the best cases the parallax uncertainties are below 1 mas, and significant parallaxes are found for most of the program stars. A Bayesian method which combines the parallaxes together with proper motions and absolute magnitude constraints is developed and used to derive distance estimates and confidence intervals. The most precise distance derived here is for WZ Sge, for which I find 43.3 (+1.6, -1.5) pc. Six Luyten Half-Second stars with previous precise parallax measurements were re-measured to test the techniques, and good agreement is found.Comment: 33 pages, 3 figures. Astronomical Journal, accepte

Socioeconomic indicators of health inequalities and female mortality: a nested cohort study within the United Kingdom Collaborative Trial of Ovarian Cancer Screening (UKCTOCS)

Evidence is mounting that area-level socioeconomic indicators are important tools for predicting health outcomes. However, few studies have examined these alongside individual-level education. This nested cohort study within the control arm of the United Kingdom Collaborative Trial of Ovarian Cancer Screening (UKCTOCS) assesses the association of mutually adjusted individual (education) and area-level (Index of Multiple Deprivation-IMD 2007) socioeconomic status indicators and all-cause female mortality