1,770 research outputs found
Variational calculations on the hydrogen molecular ion
We present high-precision non-relativistic variational calculations of bound
vibrational-rotational state energies for the and molecular
ions in each of the lowest electronic states of , , and
symmetry. The calculations are carried out including coupling between
and states but without using the Born-Oppenheimer or any
adiabatic approximation. Convergence studies are presented which indicate that
the resulting energies for low-lying levels are accurate to about .
Our procedure accounts naturally for the lambda-doubling of the state.Comment: 23 pp., RevTeX, epsf.sty, 5 figs. Enhanced data in Table II, dropped
3 figs. from previous versio
Absorption spectrum in the wings of the potassium second resonance doublet broadened by helium
We have measured the reduced absorption coefficients occurring in the wings
of the potassium 4S-5P doublet lines at 404.414 nm and at 404.720 nm broadened
by helium gas at pressures of several hundred Torr. At the experimental
temperature of 900 K, we have detected a shoulder-like broadening feature on
the blue wing of the doublet which is relatively flat between 401.8 nm and
402.8 nm and which drops off rapidly for shorter wavelengths, corresponding to
absorption from the X doublet Sigma+ state to the C doublet Sigma+ state of the
K-He quasimolecule. The accurate measurements of the line profiles in the
present work will sharply constrain future calculations of potential energy
surfaces and transition dipole moments correlating to the asymptotes He-K(5p),
He-K(5s), and He-K(3d).Comment: 2 figure
Radiative association and inverse predissociation of oxygen atoms
The formation of \mbox{O}_2 by radiative association and by inverse
predissociation of ground state oxygen atoms is studied using
quantum-mechanical methods. Cross sections, emission spectra, and rate
coefficients are presented and compared with prior experimental and theoretical
results. At temperatures below 1000~K radiative association occurs by approach
along the state of \mbox{O}_2 and above 1000~K inverse
predissociation through the \mbox{B}\,{}^3\Sigma_u^- state is the dominant
mechanism. This conclusion is supported by a quantitative comparison between
the calculations and data obtained from hot oxygen plasma spectroscopy.Comment: submitted to Phys. Rev. A (Sept. 7., 1994), 19 pages, 4 figures,
latex (revtex3.0 and epsf.sty
Dependences of the Casimir-Polder interaction between an atom and a cavity wall on atomic and material properties
The Casimir-Polder and van der Waals interactions between an atom and a flat
cavity wall are investigated under the influence of real conditions including
the dynamic polarizability of the atom, actual conductivity of the wall
material and nonzero temperature of the wall. The cases of different atoms near
metal and dielectric walls are considered. It is shown that to obtain accurate
results for the atom-wall interaction at short separations, one should use the
complete tabulated optical data for the complex refractive index of the wall
material and the accurate dynamic polarizability of an atom. At relatively
large separations in the case of a metal wall, one may use the plasma model
dielectric function to describe the dielectric properties of wall material. The
obtained results are important for the theoretical interpretation of
experiments on quantum reflection and Bose-Einstein condensation.Comment: 5 pages, 1 figure, iopart.cls is used, to appear in J. Phys. A
(special issue: Proceedings of QFEXT05, Barcelona, Sept. 5-9, 2005
Rate coefficients for rovibrational transitions in H_2 due to collisions with He
We present quantum mechanical and quasiclassical trajectory calculations of
cross sections for rovibrational transitions in ortho- and para-H_2 induced by
collisions with He atoms. Cross sections were obtained for kinetic energies
between 10^-4 and 3 eV, and the corresponding rate coefficients were calculated
for the temperature range 100<T<4000 K. Comparisons are made with previous
calculations.Comment: 21 pages, 2 figures, AAS, eps
Similitude and scale effects of air entrainment in hydraulic jumps
A hydraulic jump is characterised by some strong turbulence and air entrainment in the roller. New measurements were performed in two channels in which similar experiments with identical inflow Froude numbers and relative channel widths were conducted with a geometric scaling ratio of 2:1. Void fraction distributions showed the presence of an advection/diffusion shear layer in which the data followed an analytical solution of the diffusion equation for air bubbles. The data indicated some scale effects in the small channel in terms of void fraction and bubble count rate. Void fraction distributions implied comparatively greater detrainment at low Reynolds numbers yielding to lesser overall aeration of the jump roller. Dimensionless bubble count rates were significantly lower in the smaller channel especially in the mixing layer. The study is believed to be the first systematic investigation of scale effects affecting air entrainment in hydraulic jumps using an accurate air-water measurement technique
Retarded long-range potentials for the alkali-metal atoms and a perfectly conducting wall
The retarded long-range potentials for hydrogen and alkali-metal atoms in
their ground states and a perfectly conducting wall are calculated. The
potentials are given over a wide range of atom-wall distances and the validity
of the approximations used is established.Comment: RevTeX, epsf, 11 pages, 2 fig
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