Local superconductivity and ferromagnetism interplay in graphite-sulfur composites

The superconductivity of graphite-sulfur composites is highly anisotropic and associated with the graphite planes. The superconducting state coexists with the ferromagnetism of pure graphite, and a continuous crossover from superconducting to ferromagnetic-like behavior could be achieved by increasing the magnetic field or the temperature. The angular dependence of the magnetic moment m(alpha) provides evidence for an interaction between the ferromagnetic and the superconducting order parameters.76276

Indication of Superconductivity at 35 K in Graphite-Sulfur Composites

We report magnetization measurements performed on graphite--sulfur composites which demonstrate a clear superconducting behavior below the critical temperature T$_{c0}$ = 35 K. The Meissner-Ochsenfeld effect, screening supercurrents, and magnetization hysteresis loops characteristic of type-II superconductors were measured. The results indicate that the superconductivity occurs in a small sample fraction, possibly related to the sample surface.Comment: published versio

Interaction Between Superconducting and Ferromagnetic Order Parameters in Graphite-Sulfur Composites

The superconductivity of graphite-sulfur composites is highly anisotropic and associated with the graphite planes. The superconducting state coexists with the ferromagnetism of pure graphite, and a continuous crossover from superconducting to ferromagnetic-like behavior could be achieved by increasing the magnetic field or the temperature. The angular dependence of the magnetic moment m(alpha) provides evidence for an interaction between the ferromagnetic and the superconducting order parameters.Comment: 11 pages, 4 figures, to be published in Phys. Rev.

Extraordinary magnetoresistance in graphite: experimental evidence for the time-reversal symmetry breaking

The ordinary magnetoresistance (MR) of doped semiconductors is positive and quadratic in a low magnetic field, B, as it should be in the framework of the Boltzmann kinetic theory or in the conventional hopping regime. We observe an unusual highly-anisotropic in-plane MR in graphite, which is neither quadratic nor always positive. In a certain current direction MR is negative and linear in B in fields below a few tens of mT with a crossover to a positive MR at higher fields, while in a perpendicular current direction we observe a giant super-linear and positive MR. These extraordinary MRs are respectively explained by a hopping magneto-conductance via non-zero angular momentum orbitals, and by the magneto-conductance of inhomogeneous media. The linear orbital NMR is a unique signature of the broken time-reversal symmetry (TRS) in graphite. While some local paramagnetic centers could be responsible for the broken TRS, the observed large diamagnetism suggests a more intriguing mechanism of this breaking, involving superconducting clusters with unconventional (chiral) order parameters and spontaneously generated normal-state current loops in graphite.Comment: 4 pages, 5 figure

Evidence of Josephson-coupled superconducting regions at the interfaces of Highly Oriented Pyrolytic Graphite

Transport properties of a few hundreds of nanometers thick (in the graphene plane direction) lamellae of highly oriented pyrolytic graphite (HOPG) have been investigated. Current-Voltage characteristics as well as the temperature dependence of the voltage at different fixed input currents provide evidence for Josephson-coupled superconducting regions embedded in the internal two-dimensional interfaces, reaching zero resistance at low enough temperatures. The overall behavior indicates the existence of superconducting regions with critical temperatures above 100 K at the internal interfaces of oriented pyrolytic graphite.Comment: 6 Figures, 5 page

AC conductivity of graphene: from tight-binding model to 2+1-dimensional quantum electrodynamics

We consider the relationship between the tight-binding Hamiltonian of the two-dimensional honeycomb lattice of carbon atoms with nearest neighbor hopping only and the 2+1 dimensional Hamiltonian of quantum electrodynamics which follows in the continuum limit. We pay particular attention to the symmetries of the free Dirac fermions including spatial inversion, time reversal, charge conjugation and chirality. We illustrate the power of such a mapping by considering the effect of the possible symmetry breaking which corresponds to the creation of a finite Dirac mass, on various optical properties. In particular, we consider the diagonal AC conductivity with emphasis on how the finite Dirac mass might manifest itself in experiment. The optical sum rules for the diagonal and Hall conductivities are discussed.Comment: 46 pages, ws-ijmpb, 7 EPS figures; final version published in IJMP

Evolving properties of two dimensional materials, from graphene to graphite

We have studied theoretically, using density functional theory, several materials properties when going from one C layer in graphene to two and three g raphene layers and on to graphite. The properties we have focused on are the elastic constants, electronic structure (energy bands and density of state s), and the dielectric properties. For any of the properties we have investigated the modification due to an increase in the number of graphene layers is within a few percent. Our results are in agreement with the analysis presented recently by Kopelevich and Esquinazi (unpublished)

Intrinsic Superconductivity at 25 K in Highly Oriented Pyrolytic Graphite

High resolution magnetoresistance data in highly oriented pyrolytic graphite thin samples manifest non-homogenous superconductivity with critical temperature $T_c \sim 25$K. These data exhibit: i) hysteretic loops of resistance versus magnetic field similar to Josephson-coupled grains, ii) quantum Andreev's resonances and iii) absence of the Schubnikov-de Haas oscillations. The results indicate that graphite is a system with non-percolative superconducting domains immersed in a semiconducting-like matrix. As possible origin of the superconductivity in graphite we discuss interior-gap superconductivity when two very different electronic masses are present.Comment: 5 pages, 3 figure

Ferromagnetism in Oriented Graphite Samples

We have studied the magnetization of various, well characterized samples of highly oriented pyrolitic graphite (HOPG), Kish graphite and natural graphite to investigate the recently reported ferromagnetic-like signal and its possible relation to ferromagnetic impurities. The magnetization results obtained for HOPG samples for applied fields parallel to the graphene layers - to minimize the diamagnetic background - show no correlation with the magnetic impurity concentration. Our overall results suggest an intrinsic origin for the ferromagnetism found in graphite. We discuss possible origins of the ferromagnetic signal.Comment: 11 figure