Effect of uniaxial strain on plasmon excitations in graphene

Uniaxial strain is known to modify significantly the electronic properties of graphene, a carbon single layer of atomic width. Here, we study the effect of applied strain on the composite excitations arising from the coupling of charge carriers and plasmons in graphene, i.e. the plasmarons. Specifically, we predict that the plasmaron energy dispersion, which has been recently observed experimentally in unstrained graphene, is shifted and broadened by applied uniaxial strain. Thus, strain constitutes an additional parameter which may be useful to tune graphene properties in plasmaronic devices.Comment: Invited oral lecture at the 23rd AIRAPT International Conference on "High Pressure Science and Technology", Mumbai (India), September 25-30, 2011. To be published in J. Phys.: Conf. Series (2012

van der Waals density functionals built upon the electron-gas tradition: Facing the challenge of competing interactions

The theoretical description of sparse matter attracts much interest, in particular for those ground-state properties that can be described by density functional theory (DFT). One proposed approach, the van der Waals density functional (vdW-DF) method, rests on strong physical foundations and offers simple yet accurate and robust functionals. A very recent functional within this method called vdW-DF-cx [K. Berland and P. Hyldgaard, Phys. Rev. B 89, 035412] stands out in its attempt to use an exchange energy derived from the same plasmon-based theory from which the nonlocal correlation energy was derived. Encouraged by its good performance for solids, layered materials, and aromatic molecules, we apply it to several systems that are characterized by competing interactions. These include the ferroelectric response in PbTiO$_3$, the adsorption of small molecules within metal-organic frameworks (MOFs), the graphite/diamond phase transition, and the adsorption of an aromatic-molecule on the Ag(111) surface. Our results indicate that vdW-DF-cx is overall well suited to tackle these challenging systems. In addition to being a competitive density functional for sparse matter, the vdW-DF-cx construction presents a more robust general purpose functional that could be applied to a range of materials problems with a variety of competing interactions

TCP over High Speed Variable Capacity Links: A Simulation Study for Bandwidth Allocation

New optical network technologies provide opportunities for fast, controllable bandwidth management. These technologies can now explicitly provide resources to data paths, creating demand driven bandwidth reservation across networks where an applications bandwidth needs can be meet almost exactly. Dynamic synchronous Transfer Mode (DTM) is a gigabit network technology that provides channels with dynamically adjustable capacity. TCP is a reliable end-to-end transport protocol that adapts its rate to the available capacity. Both TCP and the DTM bandwidth can react to changes in the network load, creating a complex system with inter-dependent feedback mechanisms. The contribution of this work is an assessment of a bandwidth allocation scheme for TCP flows on variable capacity technologies. We have created a simulation environment using ns-2 and our results indicate that the allocation of bandwidth maximises TCP throughput for most flows, thus saving valuable capacity when compared to a scheme such as link over-provisioning. We highlight one situation where the allocation scheme might have some deficiencies against the static reservation of resources, and describe its causes. This type of situation warrants further investigation to understand how the algorithm can be modified to achieve performance similar to that of the fixed bandwidth case

Electron self-energy in A3C60 (A=K, Rb): Effects of t1u plasmon in GW approximation

The electron self-energy of the t1u states in A3C60 (A=K, Rb) is calculated using the so-called GW approximation. The calculation is performed within a model which considers the t1u charge carrier plasmon at 0.5 eV and takes into account scattering of the electrons within the t1u band. A moderate reduction (35 %) of the t1u band width is obtained.Comment: 4 pages, revtex, 1 figure more information at http://www.mpi-stuttgart.mpg.de/dokumente/andersen/fullerene

Flash ionization of the partially ionized wind of the progenitor of SN 1987A

The H II region created by the progenitor of SN 1987A was further heated and ionized by the supernova flash. Prior to the flash, the temperature of the gas was 4000 - 5000 K, and helium was neutral, while the post-flash temperature was only slightly less than 10^5 K, with the gas being ionized to helium-like ionization stages of C, N and O. We have followed the slow post-flash cooling and recombination of the gas, as well as its line emission, and find that the strongest lines are N V 1240 and O VI 1034. Both these lines are good probes for the density of the gas, and suitable instruments to detect the lines are STIS on HST and FUSE, respectively. Other lines which may be detectable are N IV] 1486 and [O III] 5007, though they are expected to be substantially weaker. The relative strength of the oxygen lines is found to be a good tracer of the color temperature of the supernova flash. From previous observations, we put limits on the hydrogen density, n_H, of the H II region. The early N V 1240 flux measured by IUE gives an upper limit which is n_H ~ 180 \eta^{-0.40} cm^{-3}, where \eta is the filling factor of the gas. The recently reported emission in [O III] 5007 at 2500 days requires n_H = (160\pm12) \eta^{-0.19} cm^{-3}, for a supernova burst similar to that in the 500full1 model of Ensman & Burrows (1992). For the more energetic 500full2 burst the density is n_H = (215\pm15) \eta^{-0.19} cm^{-3}. These values are much higher than in models of the X-ray emission from the supernova (n_H ~ 75 cm^{-3}), and it seems plausible that the observed [O III] emission is produced primarily elsewhere than in the H II region. We also discuss the type of progenitor consistent with the H II region. In particular, it seems unlikely that its spectral type was much earlier than B2 Ia.Comment: LaTeX, 23 pages including 4 figures. To appear in ApJ (Main Journal

From electronic structure to catalytic activity: A single descriptor for adsorption and reactivity on transition-metal carbides

Adsorption and catalytic properties of the polar (111) surface of transition-metal carbides (TMC's) are investigated by density-functional theory. Atomic and molecular adsorption are rationalized with the concerted-coupling model, in which two types of TMC surface resonances (SR's) play key roles. The transition-metal derived SR is found to be a single measurable descriptor for the adsorption processes, implying that the Br{\o}nsted-Evans-Polanyi relation and scaling relations apply. This gives a picture with implications for ligand and vacancy effects and which has a potential for a broad screening procedure for heterogeneous catalysts.Comment: 5 pages, 3 figure

Atrial high-rate episodes: prevalence, stroke risk, implications for management, and clinical gaps in evidence

Self-terminating atrial arrhythmias are commonly detected on continuous rhythm monitoring, e.g. by pacemakers or defibrillators. It is unclear whether the presence of these arrhythmias has therapeutic consequences. We sought to summarize evidence on the prevalence of atrial high-rate episodes (AHREs) and their impact on risk of stroke. We performed a comprehensive, tabulated review of published literature on the prevalence of AHRE. In patients with AHRE, but without atrial fibrillation (AF), we reviewed the stroke risk and the potential risk/benefit of oral anticoagulation. Atrial high-rate episodes are found in 10-30% of AF-free patients. Presence of AHRE slightly increases stroke risk (0.8% to 1%/year) compared with patients without AHRE. Atrial high-rate episode of longer duration (e.g. those >24 h) could be associated with a higher stroke risk. Oral anticoagulation has the potential to reduce stroke risk in patients with AHRE but is associated with a rate of major bleeding of 2%/year. Oral anticoagulation is not effective in patients with heart failure or survivors of a stroke without AF. It remains unclear whether anticoagulation is effective and safe in patients with AHRE. Atrial high-rate episodes are common and confer a slight increase in stroke risk. There is true equipoise on the best way to reduce stroke risk in patients with AHRE. Two ongoing trials (NOAH-AFNET 6 and ARTESiA) will provide much-needed information on the effectiveness and safety of oral anticoagulation using non-vitamin K antagonist oral anticoagulants in patients with AHRE.info:eu-repo/semantics/publishedVersio

No trace of a single-degenerate companion in late spectra of SNe 2011fe and 2014J

Left-over, ablated material from a possible non-degenerate companion can reveal itself after about one year in spectra of Type Ia SNe (SNe Ia). We have searched for such material in spectra of SN 2011fe (at 294 days after the explosion) and for SN 2014J (315 days past explosion). The observations are compared with numerical models simulating the expected line emission. The spectral lines sought for are H-alpha, [O I] 6300 and [Ca II] 7291,7324, and the expected width of these lines is about 1000 km/s. No signs of these lines can be traced in any of the two supernovae. When systematic uncertainties are included, the limits on hydrogen-rich ablated gas in SNe 2011fe and 2014J are 0.003 M_sun and 0.0085 M_sun, respectively, where the limit for SN 2014J is the second lowest ever, and the limit for SN 2011fe is a revision of a previous limit. Limits are also put on helium-rich ablated gas. These limits are used, in conjunction with other data, to argue that these supernovae can stem from double-degenerate systems, or from single-degenerate systems with a spun up/spun down super-Chandrasekhar white dwarf. For SN 2011fe, other types of hydrogen-rich donors can likely be ruled out, whereas for SN 2014J a main-sequence donor system with large intrinsic separation is still possible. Helium-rich donor systems cannot be ruled out for any of the two supernovae, but the expected short delay time for such progenitors makes this possibility less likely, especially for SN 2011fe. The broad [Ni II] 7378 emission in SN 2014J is redshifted by about +1300 km/s, as opposed to the known blueshift of roughly -1100 km/s for SN 2011fe. [Fe II] 7155 is also redshifted in SN 2014J. SN 2014J belongs to a minority of SNe Ia that both have a nebular redshift of [Fe II] 7155 and [Ni II] 7378, and a slow decline of the Si II 6355 absorption trough just after B-band maximum.Comment: 13 pages, submitted to A&