753 research outputs found
Preparation and properties of silicon- and titanium-containing hybrid nanocomposite films based on ethyl cellulose
Nanocomposite hybrid films containing silicon and titanium compounds in the polymer matrix are prepared through the sol-gel method via the hydrolytic polycondensation of Si and Ti alkoxides (tetraethoxysilane and titanium tetrabutoxide) in the THF solution of a hydrophobic polymer, ethyl cellulose. Their structure and properties are studied with the use of a complex of physicochemical methods. During the hydrolysis of tetraethoxysilane and the subsequent polycondensation of the reaction products, silicon atoms are incorporated into the polymer and form -O-Si-O-bonds involving hydroxyl groups of ethyl cellulose. In the sol-gel method, titanium alkoxide yields nanosized particles of titanium dioxide that play the role of fillers in the polymer matrix. Titanium-containing films show solubility in THF and, after prolonged contact with the solvent, precipitate titanium dioxide from the solution. Hybrid films containing silicon are insoluble owing to the formation of a chemical network between polymer molecules and Si-OH groups of the products of hydrolysis of silicon alkoxide, as confirmed by the IR data. It is shown that the amounts and types of alkoxides and the diameters of the structures formed in the polymer matrix via the sol-gel procedure affect the hydrophilicity levels of ethyl cellulose hybrid films and their abilities to swell in water and aqueous solutions of organic dyes (brilliant blue and methylene blue). Ethyl cellulose hybrid films are hydrophilic, and they facilitate the removal of dye molecules from aqueous solutions. The best properties are featured by the films containing nanosized particles of titanium dioxide in the polymer matrix. © 2013 Pleiades Publishing, Ltd
Determination of fracture toughness for small-sized specimens with ultrafine grain structure
The results of changing the fracture toughness of materials are given for the VT6 titanium alloy. Its coarse grain structure was reduced down to ultrafine structure by forging. The specific energy of fracture [gamma] for the small-sized chevron-notched specimens was found thanks to the new technique. It is shown that severe plastic deformation reduces [gamma] at room temperature. The structure of the surface fracture of the VT6 alloy’s ultrafine grain structure can be conceived as local zones of strong deformed material with a high concentration of pores. Such kind of structure cannot be formed only by means of crystallographic shears along close-packed planes. That fact proves the cardinal role of rotational modes of deformation in the origination and formation of a crack at various scale levels
Profile of subpopulation composition of regulatory T lymphocytes and intestinal microbiota in patients with irritable bowel syndrome
The following specificcharacteristics of the composition of intestinal microbiota in patients with irritable bowel syndrome (IBS) were identified using a metagenomic analysis (16 S rRNA): 1) an increase in the representation of Actinobacteria, including Bifidobacterium spp., Firmicutes, including representatives of Streptococcaceae (Streptococcus), Lachnosperaceae (Dorea), Veillonellaceae (Dialister), Proteobacteria (Enterobacteriaceae and Desulfovibrionaceae families); 2) a decrease in the population of Bacteroidetes, including representatives of the families Prevotellacea (Prevotella spp.), Bacteroidaceae (Bacteroides spp.). Firmicutes belonging to the families Clostridiaceae and Ruminococcaceae (Fecalibacterium spp.).Flow cytometry in the study of the subpopulation composition of T regulatory (Treg) lymphocytes in patients with IBS revealed an increase in the number of CD45R0+CD62L+ central memory cells (CM), which can regulate the processes of maturation and differentiation of lymphocytes in lymphoid tissue. A decrease in the expression of exonucleases CD39 and CD73 was detected, which can have a significant effect on their activity. A reduction in effector memory cells (EM) Treg was observed.Changes in the expression level of exonucleases CD39 and CD73 were inversely correlated with the content of Proteobacteria and the representation of the genera Bifidobacterium spp. and Faecalibacterium spp. The content of СЫ Treg was directly correlated with the content of Dorea spp.The results may be indicative of impairment in the processes of Treg differentiation, which are closely related to changes in key components of intestinal microbiocenosis in IBS
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Spectroscopy of geo-neutrinos from 2056 days of Borexino data
We report an improved geo-neutrino measurement with Borexino from 2056 days
of data taking. The present exposure is
protonyr. Assuming a chondritic Th/U mass ratio of 3.9, we obtain geo-neutrino events. The null
observation of geo-neutrinos with Borexino alone has a probability of (5.9). A geo-neutrino signal from the mantle is
obtained at 98\% C.L. The radiogenic heat production for U and Th from the
present best-fit result is restricted to the range 23-36 TW, taking into
account the uncertainty on the distribution of heat producing elements inside
the Earth.Comment: 4 pages, 4 figure
Search for electron antineutrino interactions with the Borexino Counting Test Facility at Gran Sasso
Electron antineutrino interactions above the inverse beta decay energy of
protons (E_\bar{\nu}_e>1.8) where looked for with the Borexino Counting Test
Facility (CTF). One candidate event survived after rejection of background,
which included muon-induced neutrons and random coincidences. An upper limit on
the solar flux, assumed having the B solar neutrino energy
spectrum, of 1.1 cm~s (90% C.L.) was set with a 7.8
ton year exposure. This upper limit corresponds to a solar neutrino
transition probability, , of 0.02 (90% C.L.).
Predictions for antineutrino detection with Borexino, including geoneutrinos,
are discussed on the basis of background measurements performed with the CTF.Comment: 10 pages, 9 figures, 5 table
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New experimental limits on the Pauli forbidden transitions in C nuclei obtained with 485 days Borexino data
The Pauli exclusion principle (PEP) has been tested for nucleons () in
with the Borexino detector.The approach consists of a search for
, , and emitted in a non-Paulian transition of
1- shell nucleons to the filled 1 shell in nuclei. Due to the
extremely low background and the large mass (278 t) of the Borexino detector,
the following most stringent up-to-date experimental bounds on PEP violating
transitions of nucleons have been established:
y, y,
y,
y and y, all at 90% C.L. The corresponding upper
limits on the relative strengths for the searched non-Paulian electromagnetic,
strong and weak transitions have been estimated: , and .Comment: 9 pages, 6 figure
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Solar neutrino with Borexino: results and perspectives
Borexino is a unique detector able to perform measurement of solar neutrinos
fluxes in the energy region around 1 MeV or below due to its low level of
radioactive background. It was constructed at the LNGS underground laboratory
with a goal of solar Be neutrino flux measurement with 5\% precision. The
goal has been successfully achieved marking the end of the first stage of the
experiment. A number of other important measurements of solar neutrino fluxes
have been performed during the first stage. Recently the collaboration
conducted successful liquid scintillator repurification campaign aiming to
reduce main contaminants in the sub-MeV energy range. With the new levels of
radiopurity Borexino can improve existing and challenge a number of new
measurements including: improvement of the results on the Solar and terrestrial
neutrino fluxes measurements; measurement of pp and CNO solar neutrino fluxes;
search for non-standard interactions of neutrino; study of the neutrino
oscillations on the short baseline with an artificial neutrino source (search
for sterile neutrino) in context of SOX project.Comment: 15 pages, 4 figure
The Main Results of the Borexino Experiment
The main physical results on the registration of solar neutrinos and the
search for rare processes obtained by the Borexino collaboration to date are
presented.Comment: 8 pages, 8 figgures, To be published as Proceedings of the Third
Annual Large Hadron Collider Physics Conference, St. Petersburg, Russia, 201
New limits on heavy sterile neutrino mixing in -decay obtained with the Borexino detector
If heavy neutrinos with mass 2 are produced in the
Sun via the decay in a side
branch of pp-chain, they would undergo the observable decay into an electron, a
positron and a light neutrino . In the
present work Borexino data are used to set a bound on the existence of such
decays. We constrain the mixing of a heavy neutrino with mass 1.5 MeV 14 MeV to be
respectively. These are tighter limits on the mixing parameters than obtained
in previous experiments at nuclear reactors and accelerators.Comment: 7 pages, 6 figure
Pulse-Shape discrimination with the Counting Test Facility
Pulse shape discrimination (PSD) is one of the most distinctive features of
liquid scintillators. Since the introduction of the scintillation techniques in
the field of particle detection, many studies have been carried out to
characterize intrinsic properties of the most common liquid scintillator
mixtures in this respect. Several application methods and algorithms able to
achieve optimum discrimination performances have been developed. However, the
vast majority of these studies have been performed on samples of small
dimensions. The Counting Test Facility, prototype of the solar neutrino
experiment Borexino, as a 4 ton spherical scintillation detector immersed in
1000 tons of shielding water, represents a unique opportunity to extend the
small-sample PSD studies to a large-volume setup. Specifically, in this work we
consider two different liquid scintillation mixtures employed in CTF,
illustrating for both the PSD characterization results obtained either with the
processing of the scintillation waveform through the optimum Gatti's method, or
via a more conventional approach based on the charge content of the
scintillation tail. The outcomes of this study, while interesting per se, are
also of paramount importance in view of the expected Borexino detector
performances, where PSD will be an essential tool in the framework of the
background rejection strategy needed to achieve the required sensitivity to the
solar neutrino signals.Comment: 39 pages, 17 figures, submitted to Nucl. Instr. Meth.
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