Marine oligotrophication due to fine sediments and nutrient starvation caused by anthropogenic sediment and water retention in large rivers: the Nile damming case

In the last two centuries, human activities have radically reduced the transport of suspended sediment and water to marine systems, mainly in the northern hemisphere, while complete sediment retention has been reported for the Nile River after the construction of the Aswan High Dam (AHD). Here, we focused on changes in the inner-shelf sediments most exposed to the pre-AHD flood plume in the distal part of its littoral cell as a predictor of the ecological response to large river fragmentation. Substantial reductions in fine (15-40%) and increases in coarse (~8 fold) sediment accumulation rates, increases in CaCO3 (~50%), decreases in autochthonous and total organic carbon (OC), and changes in the benthic foraminiferal assemblage toward more OC-sensitive species suggest an enhanced oligotrophication trend. The reduced nutrient fluxes and OC accumulation, and the coarsening of the shelf sediments inhibit the retention of “blue” carbon. Combined with fast climate warming and salinization, river fragmentation may have essential implications for the Eastern Mediterranean ecosystem via benthic oligotrophication processes

Anoxic development of sapropel S1 in the Nile Fan inferred from redox sensitive proxies, Fe speciation, Fe and Mo isotopes

Redox conditions and the mechanisms of redox development are a critical aspect of Eastern Mediterranean sapropels, whose formation in oxygen-depleted waters is closely related to water column stratification at times of global sea level rise and insolation maxima. Sapropels in the Nile Fan formed at relatively shallow water depths under the influence of the monsoon-driven freshwater output from the River Nile. This work evaluates the redox evolution of Holocene sapropel S1 in VALPAMED cruise core MD9509, recovered at 880 mbsl in the NE Nile Fan, using a combination of geochemical element proxies, Fe speciation, Fe and Mo isotopes studies. The productivity and redox proxies (Ba/Al, Mo/Al, U/Al, V/Al, Sb/Al) show well-defined enrichments in the sapropel, but with a marked minimum at ca 8.2 ka indicative of reventilation corresponding to a well known global cooling event. Peak productivity and reducing signals occur close to the initiation of sapropel formation. The proxy signals in sapropel 9509 are stronger and of longer duration than those of a second sapropel S1, recovered at the same depth, but 380 km to the north (MD9501), supporting the notion (suggested in previous studies) of more reduced conditions in the Nile Fan. The MoEF vs. UEF enrichment factor variations in core 9509 infer a transition from open marine suboxic conditions in the enclosing non-sapropel sediments to anoxic non-sulphidic water column conditions in the sapropel. Correspondingly, the highly reactive Fe pool (FeHR) measured in Fe speciation studies is dominated by Fe(oxyhydr) oxide minerals in the background sediments, whereas pyrite (Fepy) becomes the dominant component of the FeHR pool in the sapropel. Maximum Fepy values in the sapropel coincide with peak productivity and reducing conditions, implying a clear link between trace element uptake, diagenetic bacterial sulphate reduction in anoxic porewater and Fe mobilization in the sapropel. Iron isotope compositions (δ56Fe) in the sapropel do not show any departure from primary (marine and detrital) source sediment values, and the absence of an Fe/Al vs. δ56Fe trend strongly argues against an Fe shuttle. Molybdenum isotopes, however, show marked non-conservative fractionation patterns. Background sediment δ98/95Mo values (0.2 to 0.7‰) are compatible with fractionation upon absorptive uptake by Fe (oxyhydr)oxides and pyrite. In contrast, minimum δ98/95Mo values exhibited at peak sapropel (reducing and pyrite producing) conditions are most closely modeled by Mo isotope fractionation during kinetically controlled conversion of aqueous molybdate to thiomolybdate species. The conservative Fe isotope behavior/Mo isotope fractionation minima in the sapropel may be a characteristic of organic-rich sediment diagenesis below an anoxic non-sulphidic water body, without the operation of a benthic Fe shuttle

Constant cosmogenic nuclide concentrations in sand supplied from the Nile River over the past 2.5 m.y.

Quartz sand in the eastern Mediterranean coastal plain is supplied through an extended transport system, which includes the Nile River, east Mediterranean longshore currents, and inland eolian transport. While the concentrations of cosmogenic nuclides (26Al and 10Be), and their ratio, in modern sand deposited along the coast of the eastern Mediterranean refl ect the combined effect of exposure and burial during transport, the concentrations of these nuclides in buried sands are the result of decay of this initial dosing. Samples of modern exposed sand (n = 3) collected from the coastal plain of Israel yield an average 26Al/10Be ratio of 4.8 ± 0.2, significantly lower than the expected ratio of 6.8 for exposed quartz grains at the surface. A similar ratio of 4.5 ± 0.3 was measured in a late Pleistocene sand sample, indicating similar exposure-burial histories during transport in spite of the difference in climatic conditions. The results imply a steady, preburial cosmogenic nuclide ratio related to the Nile River’s ability, through storage and recycling, to buffer the effects of climatic and tectonic perturbations on cosmogenic nuclide concentrations in the transported quartz. All ancient and buried sand samples (n = 11) fall on a decay path that originates from the concentrations and ratio of 26Al and 10Be in modern sand, suggesting steady preburial concentrations of cosmogenic nuclides in quartz sand over the past 2.5 m.y

Late Holocene paleoenvironmental changes in the Seal Beach wetland (California, USA): A micropaleontological perspective

Pollen, benthic foraminifera, diatoms, sediment grain size, and organic matter content from a 230-cm long-AMS dated sediment core (Core SB-51B) were used to reconstruct paleoenvironmental changes and paleoclimatic evolution within the Seal Beach wetland (southern California, USA), during the last ~ 2000 years. A Q-mode cluster analysis based on diatom and foraminiferal data identified three distinct units: 1) the lowest sandy to silty-sand unit deposited before 1838 cal years BP (230 –140 cm in depth) is devoid of microfossils; 2) a clay rich intermediate unit dated between 1838 and 513 cal years BP (140–52 cm) is dominated by brackish and brackish-marine diatoms and foraminifera; and 3) a clay-rich zone deposited after 513 cal years BP(52 cm to the surface) contains high salt marsh adapted microfossils. Fresh-water and salt-tolerant diatoms from Unit 2 indicated several fresh-water influx events at 105 cm, 82 cm, and 75 cm possibly from a nearby stream. A shift from saltmarsh plants to terrestrial plants was inferred by pollen analysis. Throughout the record, the pine pollen increases suggest a shift towards cooler and wetter conditions during the last 300 years. Regional pollen records support our findings indicating a trend from drier conditions during the last 1800 years to the cooler, more mesic conditions of the Little Ice Age. The analyzed sedimentary sequence indicated the possible occurrence of three seismic events during the Late Holocene: E3 and E2 before 1760 cal years BP and E1, which took place just prior to 390 cal years BP