K. Alex M\"uller and his important role in ferroelectricity

In this review we concentrate on the work of K. Alex M\"uller in connection with his activities on oxide perovskites and ferroelectrics which were central to his research career long before he successfully discovered the first high temperature superconductor (HTSC) together with J. G. Bednorz in 1986. Not accidentally, but taking his long experience in perovskite ferroelectrics into account, the first HTSC was an oxide perovskite which had never been considered before to be superconducting.Comment: 8 pages, 4 figure

Tuning the structural instability of SrTiO_3 by Eu doping: The phase diagram of Sr_1-xEu_xTiO_3

The phase diagram of Sr_1-xEu_xTiO_3 is determined experimentally by electron paramagnetic resonance and resistivity measurements and analyzed theoretically within the self-consistent phonon approximation as a function of x ([0.03-1.0]). The transition temperature of the structural instability of the system increases nonlinearly to higher temperatures with increasing x. This is interpreted theoretically by a substantial alteration in the dynamics caused by a change in the double-well potential from broad and shallow to narrow and deep.Comment: 15 pages, 5 figure

Intriguing spin - lattice interactions in EuTiO3

During the last decade the cubic perovskite oxide EuTiO3 (ETO) has attracted enormous novel research activities due to possible multiferroicity, hidden magnetism far above its Néel temperature at TN = 5.5 K, structural instability at TS = 282 K, possible application as magneto-electric optic device, and strong spin–lattice coupling. Here we address a novel highlight of this compound by showing that well below TS a further structural phase transition occurs below 210 K without the application of an external magnetic field, and by questioning the assumed tetragonal symmetry of the structure below TS where tiny deviations from true tetragonality are observed by birefringence and XRD measurements. It is suggested that the competition in the second nearest neighbor spin–spin interaction modulated by the lattice dynamics is at the origin of these new observations