Smart Asset Management for District Heating Systems in the Baltic Sea Region

The purpose of this review is to provide insight and a comparison of the current status of district heating (DH) systems for selected Baltic Sea countries (Denmark, Germany, Finland, Latvia, Lithuania, Poland, and Sweden), especially from viewpoints of application and solutions of novel smart asset management (SAM) approaches. Furthermore, this paper considers European projects ongoing from 2016, involving participants from the Baltic Sea Region, concerning various aspects of DH systems. The review presents the energy sources with particular attention to renewable energy sources (RES), district heating generations, and the exploitation problems of DH systems. The essential point is a comparison of traditional maintenance systems versus SAM solutions for optimal design, operating conditions, and controlling of the DH networks. The main conclusions regarding DH systems in Baltic Sea countries are commitment towards a transition to 4th generation DH, raising the quality and efficiency of heat supply systems, and simultaneously minimizing the costs. The overall trends show that applied technologies aim to increase the share of renewable energy sources and reduce greenhouse gas emissions. Furthermore, examples presented in this review underline the importance of the implementation of a smart asset management concept to modern DH systems

Promising Nanoparticle-Based Heat Transfer Fluids—Environmental and Techno-Economic Analysis Compared to Conventional Fluids

Providing optimal operating conditions is one of the major challenges for effective heating or cooling systems. Moreover, proper adjustment of the heat transfer fluid is also important from the viewpoint of the correct operation, maintenance, and cost efficiency of these systems. Therefore, in this paper, a detailed review of recent work on the subject of conventional and novel heat transfer fluid applications is presented. Particular attention is paid to the novel nanoparticle-based materials used as heat transfer fluids. In-depth comparison of environmental, technical, and economic characteristics is discussed. Thermophysical properties including thermal conductivity, specific heat, density, viscosity, and Prandtl number are compared. Furthermore, the possible benefits and limitations of various transfer fluids in the fields of application are taken into account

Design and Microwave-Assisted Synthesis of TiO₂-Lanthanides Systems and Evaluation of Photocatalytic Activity under UV-LED Light Irradiation

The TiO2-Eu and TiO2-La systems were successfully synthesized using the microwave method. Based on the results of X-ray diffraction analysis, it was found that regardless of the analyzed systems, two crystal structures were noted for the obtained samples: anatase and rutile. The analysis, such as XPS and EDS, proved that the doped lanthanum and europium nano-particles are present only on the TiO2 surface without disturbing the crystal lattice. In the synthesized systems, there were no significant changes in the bandgap energy. Moreover, all the obtained systems were characterized by high thermal stability. One of the key objectives of the work, and a scientific novelty, was the introduction of UV-LED lamps into the metronidazole photo-oxidation pathway. The results of the photo-oxidation study showed that the obtained TiO2 systems doped with selected lanthanides (Eu or La) show high efficiency in the removal of metronidazole, and at the same consuming nearly 10 times less electricity compared to conventional UV lamps (high-pressure mercury lamp). Liquid-chromatography mass-spectrometry (LC-MS) analysis of an intermediate solution showed the presence of fragments of the degraded molecule by m/z 114, 83, and 60, prompting the formulation of a plausible photodegradation pathway for metronidazole

Pilot-Scale Studies of WO3/S-Doped g-C3N4 Heterojunction toward Photocatalytic NOx Removal

Due to the rising concentration of toxic nitrogen oxides (NOx) in the air, effective methods of NOx removal have been extensively studied recently. In the present study, the first developed WO3/S-doped g-C3N4 nanocomposite was synthesized using a facile method to remove NOx in air efficiently. The photocatalytic tests performed in a newly designed continuous-flow photoreactor with an LED array and online monitored NO2 and NO system allowed the investigation of photocatalyst layers at the pilot scale. The WO3/S-doped-g-C3N4 nanocomposite, as well as single components, were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller surface area analysis (BET), X-ray fluorescence spectroscopy (XRF), X-ray photoemission spectroscopy method (XPS), UV–vis diffuse reflectance spectroscopy (DR/UV–vis), and photoluminescence spectroscopy with charge carriers’ lifetime measurements. All materials exhibited high efficiency in photocatalytic NO2 conversion, and 100% was reached in less than 5 min of illumination under simulated solar light. The effect of process parameters in the experimental setup together with WO3/S-doped g-C3N4 photocatalysts was studied in detail. Finally, the stability of the composite was tested in five subsequent cycles of photocatalytic degradation. The WO3/S-doped g-C3N4 was stable in time and did not undergo deactivation due to the blocking of active sites on the photocatalyst’s surface