ROLE OF BIOFILMS IN SURVIVAL AND PRESERVATION OF VIRULENCE OF CHOLERA VIBRIOS IN THE ENVIRONMENT AND HUMAN ORGANISM

Materials regarding biofilms of cholera vibrios are presented. Formation of biofilms is shown to be a significant pathogenicity factor and one of the main strategies, increasing survival of cholera vibrios in human organism and the environment

Stable Sn-Based Hybrid Perovskite-Related Structures with Tunable Color Coordinates via Organic Cations in Low-Temperature Synthesis

Organic-inorganic Pb-free layered perovskites are efficient broadband emitters and thus are promising materials for lighting applications. However, their synthetic protocols require a controlled atmosphere, high temperature, and long preparation time. This hinders the potential tunability of their emission through organic cations, as is instead common practice in Pb-based structures. Here, we present a set of Sn-Br layered perovskite-related structures that display different chromaticity coordinates and photoluminescence quantum yield (PLQY) up to 80%, depending on the choice of the organic monocation. We first develop a synthetic protocol that is performed under air and at 4 °C, requiring only a few steps. X-ray and 3D electron diffraction analyses show that the structures exhibit diverse octahedra connectivity (disconnected and face-sharing) and thus optical properties, while preserving the organic-inorganic layer intercalation. These results provide key insight into a previously underexplored strategy to tune the color coordinates of Pb-free layered perovskites through organic cations with complex molecular configurations

“Ab-Initio” Structure Solution of Nano-Crystalline Minerals and Synthetic Materials by Automated Electron Tomography

Most of the newly discovered mineral phases, as well as many new synthesized industrial materials, appear only in the form of nano crystals, with a size not sufficient for single-crystal x-ray structure analysis. The development of techniques able to investigate the structure of nano crystalline materials is therefore one of the most important frontiers of crystallography. The most widespread technique providing relatively fast and well consolidated routes for structure analysis of bulk materials is x-ray powder diffraction (XRPD). Nevertheless, XRPD suffers from intrinsic 1-dimension reduction of information that greatly limits its applicability in presence of peak broadening and overlapping. Peak broadening is usually caused by very small crystallites, namely less than 50nm. Overlapping of peaks is problematic mainly for intensity integration, but in case of polyphasic mixtures or significant amount of impurities it can be critical also for cell parameter determination and reflection indexing. © 2012 Springer-Verlag Berlin Heidelberg. All rights are reserved