A globally accurate theory for a class of binary mixture models

Using the self-consistent Ornstein-Zernike approximation (SCOZA) results for the 3D Ising model, we obtain phase diagrams for binary mixtures described by decorated models. We obtain the plait point, binodals, and closed-loop coexistence curves for the models proposed by Widom, Clark, Neece, and Wheeler. The results are in good agreement with series expansions and experiments.Comment: 16 pages, 10 figure

Transições de fase sem termodinâmica

As aplicações de transições de fase vão muito além do contexto da termodinâmica de equilíbrio, de onde surgiu. Nós revisamos um dos principais exemplos de uma transição de fase em um sistema sem termodinâmica, o processo de contato (PC), com ênfase no método de campo médio. Apresentamos um estudo de campo médio aplicado a um modelo para a transmissão da malária em uma população. Discutimos também as novas abordagens da distribuição quase-estacionária e o processo de contato conservativo

Critical Dynamics of the Contact Process with Quenched Disorder

We study critical spreading dynamics in the two-dimensional contact process (CP) with quenched disorder in the form of random dilution. In the pure model, spreading from a single particle at the critical point $\lambda_c$ is characterized by the critical exponents of directed percolation: in $2+1$ dimensions, $\delta = 0.46$, $\eta = 0.214$, and $z = 1.13$. Disorder causes a dramatic change in the critical exponents, to $\delta \simeq 0.60$, $\eta \simeq -0.42$, and $z \simeq 0.24$. These exponents govern spreading following a long crossover period. The usual hyperscaling relation, $4 \delta + 2 \eta = d z$, is violated. Our results support the conjecture by Bramson, Durrett, and Schonmann [Ann. Prob. {\bf 19}, 960 (1991)], that in two or more dimensions the disordered CP has only a single phase transition.Comment: 11 pages, REVTeX, four figures available on reques

Theory of the NO+CO surface reaction model

We derive a pair approximation (PA) for the NO+CO model with instantaneous reactions. For both the triangular and square lattices, the PA, derived here using a simpler approach, yields a phase diagram with an active state for CO-fractions y in the interval y_1 < y < y_2, with a continuous (discontinuous) phase transition to a poisoned state at y_1 (y_2). This is in qualitative agreement with simulation for the triangular lattice, where our theory gives a rather accurate prediction for y_2. To obtain the correct phase diagram for the square lattice, i.e., no active state, we reformulate the PA using sublattices. The (formerly) active regime is then replaced by a poisoned state with broken symmetry (unequal sub- lattice coverages), as observed recently by Kortluke et al. [Chem. Phys. Lett. 275, 85 (1997)]. In contrast with their approach, in which the active state persists, although reduced in extent, we report here the first qualitatively correct theory of the NO+CO model on the square lattice. Surface diffusion of nitrogen can lead to an active state in this case. In one dimension, the PA predicts that diffusion is required for the existence of an active state.Comment: 15 pages, 9 figure