Removal of Heavy Metals and Salmonella Pathogens from Sewage Sludge Using a Novel Chelating Agent and Its Reuse as a Fertilizer

The direct use of sewage as fertilizers in agriculture without proper treatment has led to substantial economic environmental and healthy ramifications. Proper treatment as well as adequate environmental management of sewage sludge is a necessity in order to eliminate the negative sequences of its utilization in the agriculture field. In this chapter, a novel organic Schiff base chelator derived from hydroxybenzylidene succinohydrazide (HBSH) has been successfully synthesized and characterized by elemental analysis, 1H-NMR as well as infrared spectroscopy. The effect of sewage treated with varying concentration of the Schiff base chelator (0.8, 1.6 and 2.4 g/L) as well as the untreated sewage on the sludge solid reduction, removal of heavy metals and salmonella pathogens has been investigated. The implementation of raw as well as treated sludge on the growth as well as the heavy metal content of radish plant has been also investigated. It was observed that the treated sample showed a reduction in the total content of Zn, Ni, Cr and Cu and enhancements in the yield, stem length, leaf number and flourishing

Synthesis, Characterization, and Anticancer Activity of New Metal Complexes Derived from 2-Hydroxy-3-(hydroxyimino)-4-oxopentan-2-ylidene)benzohydrazide

Novel metal(II) complexes derived from 2-hydroxy-N′-((Z)-3-(hydroxyimino)-4-oxopentan-2-ylidene)benzohydrazide ligand (H2L) were synthesized and characterized by elemental and thermal analyses (DTA and TGA), IR, UV-VIS, 1H-NMR, ESR and mass spectroscopy, magnetic susceptibilities, and conductivities measurements. The complexes adopt distorted octahedral geometry. The ESR spectra of the solid copper(II) complexes are characteristic to d9 configuration and have an axial symmetry type of a d(x2-y2) ground state. The g values confirmed the tetragonal octahedral geometry with a considerably ionic or covalent environment. The cytotoxic activity of the ligand and its metal complexes showed potent cytotoxicity effect against growth of human liver cancer HepG2 cell lines compared to the clinically used Sorafenib (Nexavar)