The Pulpit Initiative: Fighting to Return America\u27s First Freedom to Her Churches

This Comment looks at the foundational principles of the Pulpit Initiative and examines first, whence the need for a change came, and second, whether it is likely to come about. Part 11 examines the historical developments that resulted in the 1954 amendment banning pastors from speaking on candidates from the pulpit. Part III focuses on the ADF and its rationale for bringing about change along with the constitutional reasoning behind its arguments. Part IV provides some concluding remarks surrounding this initiative\u27s likely future and whether the ADF and its associated pastors stand a chance of succeeding against the United States government

The Pulpit Initiative: Fighting to Return America\u27s First Freedom to Her Churches

This Comment looks at the foundational principles of the Pulpit Initiative and examines first, whence the need for a change came, and second, whether it is likely to come about. Part 11 examines the historical developments that resulted in the 1954 amendment banning pastors from speaking on candidates from the pulpit. Part III focuses on the ADF and its rationale for bringing about change along with the constitutional reasoning behind its arguments. Part IV provides some concluding remarks surrounding this initiative\u27s likely future and whether the ADF and its associated pastors stand a chance of succeeding against the United States government

Ordered arrays of low-dimensional Au and Pd : synthesis and in situ observations

Electrodeposition of metals in templates of nano-porous anodic aluminum oxide (NP-AAO) is a versatile way of fabricating ordered arrays of metal nanowires. Thanks to the self-arranged long-range hexagonal order of the pores, electrodeposition in NP-AAO is an easily scalable bottom-up synthesis route and an attractive alternative to traditional top-down fabrication methods such as electron beam lithography.Since NP-AAO is a non-conductive medium and since it is potentially soluble in non-neutral pH solutions, the electrodeposition of metals in NP-AAO represents a challenge. These aspects are discussed in this thesis, aiming to establish a reproducible and reliable protocol for the electrodeposition of Au and Pd.By using ex situ x-ray diffraction, it has been found that the growth of Au and Pd in the confined environment of nano-pores leads (i) to a deformation of the crystalline structure, as the lattice constant is smaller along the nanowire radius and larger along the nanowire axis, compared to the bulk lattice constant, and (ii) to a crystallite size anisotropy: it is limited by the pore radius in the horizontal direction and it is larger in the direction of growth.The electrochemical growth of Au and Pd nanowires was followed in situ by x-ray scattering methods. In the case of Au nanowires, the time-resolved measurements revealed that the anisotropy of the lattice parameter progresses as a function of time, which suggests that the strain state of the nanomaterials can be artificially selected. This findings might be beneficial in the strain-engineering of Au nanoelectrode arrays for electrocatalysis. In the case of Pd nanowires, the measurements revealed strain variations, as well as phase transitions attributed to the existence of alpha- and beta-phase Pd hydride in the NP-AAO template, due to the exposure of Pd to hydrogen evolved at the working electrode. These findings suggest that Pd in NP-AAO has potential applications in the design of hydrogen storage devices

Supposed Versatile β-TaxOyNz Structures: DFT Studies

Abstract In the last decade, tantalum oxynitride material has been proposed as an interesting photo-catalyst for its spectral response extension in the visible light and good efficiency in water splitting process [1] . The electronic and structural properties of crystalline materials based on s-TaON (baddeleyite-type) have been theoretically investigated (PBE, B3LYP) in the density functional theory (DFT). The effects of Ta-vacancies, together with changes of the stoichiometry ratio Ta:O:N, suggested from experimental literature, are investigated. The electronic properties are valued by changing N and O atom positions in the crystallographic TaON, to reach the most stable form. The s-form of TaON is an n-type semiconductor when O prevails, while is a p-type semiconductor when N prevails. Consideration was given on the formation of acceptors or donors states related to the energetic positions. A structure with the best stability has also been found when a Ta-vacancy is formed in conjunction to an O increase. A model of the crystal structure that fully meets the experimentally observed properties (optical, structural and stoichiometric ratio) is proposed

Impact of compressed air energy storage demands on gas turbine performance

Industrial gas turbines are now required to operate more flexibly as a result of incentives and priorities given to renewable forms of energy. This study considers the extraction of compressed air from the gas turbine; it is implemented to store heat energy at periods of a surplus power supply and the reinjection at peak demand. Using an in-house engine performance simulation code, extractions and injections are investigated for a range of flows and for varied rear stage bleeding locations. Inter-stage bleeding is seen to unload the stage of extraction towards choke, while loading the subsequent stages, pushing them towards stall. Extracting after the last stage is shown to be appropriate for a wider range of flows: up to 15% of the compressor inlet flow. Injecting in this location at high flows pushes the closest stage towards stall. The same effect is observed in all the stages but to a lesser magnitude. Up to 17.5% injection seems allowable before compressor stalls; however, a more conservative estimate is expected with higher fidelity models. The study also shows an increase in performance with a rise in flow injection. Varying the design stage pressure ratio distribution, brought about an improvement in the stall margin utilized, only for high extraction

Genome-wide association study and polygenic risk score analysis for hearing measures in children

Funding information: Deutsche Forschungsgemeinschaft, Grant/Award Number: SCHM 3530/1-1 (418445085); Royal Society, Grant/Award Number: UF150663; UK Medical Research Council and Wellcome, Grant/Award Number: 217065/Z/19/Z; Wellcome Trust, Grant/Award Number: 105621/Z/14/ZAn efficient auditory system contributes to cognitive and psychosocial development. A right ear advantage in hearing thresholds (HTs) has been described in adults and atypical patterns of left/right hearing threshold asymmetry (HTA) have been described for psychiatric and neurodevelopmental conditions. Previous genome-wide association studies (GWASs) on HT have mainly been conducted in elderly participants whose hearing is more likely to be affected by external environmental factors. Here, we investigated HT and HTA in a children population cohort (ALSPAC, n = 6,743). Better hearing was associated with better cognitive performance and higher socioeconomic status. At the group level, HTA suggested a left ear advantage (mean = −0.28 dB) that was mainly driven by females. SNP heritability for HT and HTA was 0.13 and 0.02, respectively (n = 4,989). We found a modest negative genetic correlation between HT and reading ability. GWAS for HT (n = 5,344) did not yield significant hits but polygenic risk scores for higher educational attainment (EA, ß = −1,564.72, p = .008) and schizophrenia (ß = −241.14, p = .004) were associated with lower HT, that is, better hearing. In summary, we report new data supporting associations between hearing measures and cognitive abilities at the behavioral level. Genetic analysis suggests shared biological pathways between cognitive and sensory systems and provides evidence for a positive outcome of genetic risk for schizophrenia.Publisher PDFPeer reviewe

Cavitation over solid surfaces: microbubble collapse, shock waves, and elastic response

We discuss the interaction of the strongly nonlinear fluid motion induced by the collapse of a vapor microbubble over a planar surface and the elastic dynamics of the underlying solid. The fluid is described using an extension of the Navier-Stokes equations endowed with distributed capillary stresses in the context of a diffuse interface approach. The collapse of the bubble is triggered by overpressure in the liquid and leads to an intense jet that pierces the bubble, changing the bubble topology from spheroidal to toroidal, and impinges the solid wall inducing an intense and strongly localized load. Moreover, at bubble collapse, a compression wave is launched into the liquid surrounding the bubble. By propagating along the solid surface, the compression wave combined with the liquid jet excites the dynamics of the elastic solid, producing a complex system of waves, including, longitudinal, transversal, and Rayleigh waves, propagating in the solid. It is conjectured that the intense deformation of the solid induced by the strongly localized liquid jet may lead to the plastic deformation of the solid producing the surface pitting observed in many applications subject to cavitation induced material damage

Diffuse interface modeling of laser-induced nano/micro cavitation bubbles

In the present work, a diffuse interface model has been used to numerically investigate the laser-induced cavitation of nano/microbubbles. The mesoscale approach is able to describe the cavitation process in its entirety, starting from the vapor bubble formation due to the focused laser energy deposition, up to its macroscopic motion.In particular, the simulations show a complete and detailed description of the bubble formation and the subsequent breakdown wave emission with a precise estimation of the energy partition between the shockwave radiating in the liquid and the internal energy of the bubble. The scaling of the ratio between the energy stored in the bubble at its maximum radius and the one deposited by the laser is found in agreement with experimental observation on macroscopic bubble