Effects Of Sample Orientation On The Corrosion Of Zinc In Ammonium Sulfate And Sodium Hydroxide Solutions

The corrosion and electrochemical properties of three zinc single crystal surfaces with different orientations have been investigated. In near-neutral 1 M (NH4)2SO4, the corrosion rates on all three surfaces were found to be similar. However, the SEM morphologies of the corresponding corroded surfaces were markedly different from each other, but consistent with preferential attack of {1120} surfaces. In alkaline 0.5 N NaOH solution, the three sample orientations showed significantly different reactivities, with the (1120) surface exhibiting the highest reactivity and corrosion rate. Here, passivation ultimately occurred and the difference in the corrosion performance of the three surfaces, even for small overvoltages, is attributed to the presence of oxide or hydrated oxide films. © 1991

Corrosion Inhibitors for Sour Oilfield Environment (H2S Corrosion)

Lower-grade steel materials are the most commonly used construction materials for oil and gas wells due to their low cost and high performance. However, they are susceptible to corrosion when they come in contact with corrosive environments that are highly acidic. In oil wells, particularly deep oil wells, hydrogen sulfide (H2S) is commonly found. The dissolution of H2S gas in produced water makes the fluid corrosive. The use of corrosion inhibitors is perhaps the most practical and costeffective means of controlling corrosion of low carbon steels in the sour environment. In this chapter, typical corrosion inhibitors used in oil and gas fields to control the internal corrosion of oilfield equipment caused by H2S are being examined. The inhibitors found to be effective are polar functional compounds, with many being based on nitrogen-containing compounds, such as amines, imidazolines, and quaternary ammonium salts. Drawbacks of these compounds in practical applications and potentials of future developments are discussed

Effects of crystallographic orientation on corrosion behavior of magnesium single crystals

The corrosion behavior of magnesium single crystals with various crystallographic orientations was examined in this study. To identify the effects of surface orientation on the corrosion behavior in a systematic manner, single-crystal specimens with ten different rotation angles of the plane normal from the [0001] direction to the [1010] direction at intervals of 10&deg; were prepared and subjected to potentiodynamic polarization and potentiostatic tests as well as electrochemical impedance spectroscopy (EIS) measurements in 3.5 wt.% NaCl solution. Potentiodynamic polarization results showed that the pitting potential (E pit) first decreased from &minus;1.57 V SCE to &minus;1.64 V SCE with an increase in the rotation angle from 0&deg; to 40&deg;, and then increased to &minus;1.60 V SCE with a further increase in the rotation angle to 90&deg;. The results obtained from potentiostatic tests are also in agreement with the trend in potentiodynamic polarization tests as a function of rotation angle. A similar trend was also observed for the depressed semicircle and the total resistances in the EIS measurements due to the facile formation of MgO and Mg(OH)2 passive films on the magnesium surface. In addition, the amount of chloride in the passive film was found first to increase with an increase in rotation angle from 0&deg; to 40&deg;, then decrease with a further increase in rotation angle, indicating that the tendency to form a more protective passive film increased for rotation angle near 0&deg; [the (0001) plane] or 90&deg; [the (1010) plane]. <br /