104 research outputs found
Formation of instrumental executive skills of student-bachelors in music pedagogical education
The article actualizes the problem of forming instrumental performing skills for bachelor students of music and pedagogical education. The notion Β«instrumental performing skillsΒ» is formulated, stages of their formation are offered. The possibilities of introduction of modern computer tools in the educational process are consideredΠ ΡΡΠ°ΡΡΠ΅ Π°ΠΊΡΡΠ°Π»ΠΈΠ·ΠΈΡΡΠ΅ΡΡΡ ΠΏΡΠΎΠ±Π»Π΅ΠΌΠ° ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΈΠ½ΡΡΡΡΠΌΠ΅Π½ΡΠ°Π»ΡΠ½ΡΡ
ΠΈΡΠΏΠΎΠ»Π½ΠΈΡΠ΅Π»ΡΡΠΊΠΈΡ
Π½Π°Π²ΡΠΊΠΎΠ² Ρ ΡΡΡΠ΄Π΅Π½ΡΠΎΠ²-Π±Π°ΠΊΠ°Π»Π°Π²ΡΠΎΠ² ΠΌΡΠ·ΡΠΊΠ°Π»ΡΠ½ΠΎ-ΠΏΠ΅Π΄Π°Π³ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ. Π€ΠΎΡΠΌΡΠ»ΠΈΡΡΠ΅ΡΡΡ ΠΏΠΎΠ½ΡΡΠΈΠ΅ Β«ΠΈΠ½ΡΡΡΡΠΌΠ΅Π½ΡΠ°Π»ΡΠ½ΡΠ΅ ΠΈΡΠΏΠΎΠ»Π½ΠΈΡΠ΅Π»ΡΡΠΊΠΈΠ΅ Π½Π°Π²ΡΠΊΠΈΒ», ΠΏΡΠ΅Π΄Π»Π°Π³Π°ΡΡΡΡ ΡΡΠ°ΠΏΡ ΠΈΡ
ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ. Π Π°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°ΡΡΡΡ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ Π²Π½Π΅Π΄ΡΠ΅Π½ΠΈΡ ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΡ
ΠΊΠΎΠΌΠΏΡΡΡΠ΅ΡΠ½ΡΡ
ΡΡΠ΅Π΄ΡΡΠ² Π² ΡΡΠ΅Π±Π½ΡΠΉ ΠΏΡΠΎΡΠ΅Ρ
The problem of performing skillsβ formation of undergraduate students in the realities of the existing teaching methods
The article describes the main reasons for reducing the rate of performing skillsβ development of undergraduate students within a modern education system. Possibilities of educational programβs reforming by applying the musical-computer technology as a part of a curriculum and teacherβs tool used to increase the level of studentβs interest in a self-learning are concerned. The examples of the base used by the software to achieve the main objectives β good fundamental understanding of the subject and facilitation of the performance skillsβ acquisition by increasing the personal interest of the student in this process are given. The author of the article does not aim to identify and list specific technological achievements which allow to accelerate the process of performing skillsβ development, as well as to adapt them according to the current trends, since the technological possibilities are endless, but offers to evaluate and implement a fundamentally new approach in teachingΠ ΡΡΠ°ΡΡΠ΅ ΡΠ°ΡΠΊΡΡΠ²Π°ΡΡΡΡ ΠΎΡΠ½ΠΎΠ²Π½ΡΠ΅ ΠΏΡΠΈΡΠΈΠ½Ρ ΡΠ½ΠΈΠΆΠ΅Π½ΠΈΡ ΡΠΊΠΎΡΠΎΡΡΠΈ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΈΡΠΏΠΎΠ»Π½ΠΈΡΠ΅Π»ΡΡΠΊΠΈΡ
Π½Π°Π²ΡΠΊΠΎΠ² Ρ ΡΡΡΠ΄Π΅Π½ΡΠΎΠ²-Π±Π°ΠΊΠ°Π»Π°Π²ΡΠΎΠ² Π² ΡΠ°ΠΌΠΊΠ°Ρ
ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΡ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ. Π Π°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°ΡΡΡΡ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ ΡΠ΅ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°ΡΠ΅Π»ΡΠ½ΠΎΠΉ ΠΏΡΠΎΠ³ΡΠ°ΠΌΠΌΡ ΠΏΡΡΠ΅ΠΌ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΡ ΠΌΡΠ·ΡΠΊΠ°Π»ΡΠ½ΠΎ-ΠΊΠΎΠΌΠΏΡΡΡΠ΅ΡΠ½ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ, ΠΊΠ°ΠΊ ΡΠΎΡΡΠ°Π²Π½ΠΎΠΉ ΡΠ°ΡΡΠΈ ΡΡΠ΅Π±Π½ΠΎΠ³ΠΎ ΠΏΠ»Π°Π½Π° ΠΈ ΠΈΠ½ΡΡΡΡΠΌΠ΅Π½ΡΠ° ΠΏΠ΅Π΄Π°Π³ΠΎΠ³Π°, ΠΈΡΠΏΠΎΠ»ΡΠ·ΡΠ΅ΠΌΠΎΠ³ΠΎ Π΄Π»Ρ ΠΏΠΎΠ²ΡΡΠ΅Π½ΠΈΡ ΡΡΠΎΠ²Π½Ρ Π·Π°ΠΈΠ½ΡΠ΅ΡΠ΅ΡΠΎΠ²Π°Π½Π½ΠΎΡΡΠΈ ΡΡΡΠ΄Π΅Π½ΡΠ° Π² ΡΠ°ΠΌΠΎΠΎΠ±ΡΡΠ΅Π½ΠΈΠΈ. ΠΡΠΈΠ²ΠΎΠ΄ΡΡΡΡ ΠΏΡΠΈΠΌΠ΅ΡΡ ΠΈΡΠΏΠΎΠ»ΡΠ·ΡΠ΅ΠΌΠΎΠΉ ΠΏΡΠΎΠ³ΡΠ°ΠΌΠΌΠ½ΠΎΠΉ Π±Π°Π·Ρ Π΄Π»Ρ Π΄ΠΎΡΡΠΈΠΆΠ΅Π½ΠΈΡ ΠΎΡΠ½ΠΎΠ²Π½ΠΎΠΉ Π·Π°Π΄Π°ΡΠΈ β ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΠΈ Π³Π»ΡΠ±ΠΎΠΊΠΎΠ³ΠΎ ΠΏΠΎΠ½ΠΈΠΌΠ°Π½ΠΈΡ ΠΏΡΠ΅Π΄ΠΌΠ΅ΡΠ° ΠΈ ΡΠΏΡΠΎΡΠ΅Π½ΠΈΡ ΠΏΡΠΈΠΎΠ±ΡΠ΅ΡΠ΅Π½ΠΈΡ ΠΈΡΠΏΠΎΠ»Π½ΠΈΡΠ΅Π»ΡΡΠΊΠΈΡ
Π½Π°Π²ΡΠΊΠΎΠ² ΠΏΡΡΠ΅ΠΌ ΠΏΠΎΠ²ΡΡΠ΅Π½ΠΈΡ Π»ΠΈΡΠ½ΠΎΠΉ Π·Π°ΠΈΠ½ΡΠ΅ΡΠ΅ΡΠΎΠ²Π°Π½Π½ΠΎΡΡΠΈ ΡΡΡΠ΄Π΅Π½ΡΠ° Π² Π΄Π°Π½Π½ΠΎΠΌ ΠΏΡΠΎΡΠ΅ΡΡΠ΅. ΠΠ²ΡΠΎΡ ΡΡΠ°ΡΡΠΈ Π½Π΅ ΡΡΠ°Π²ΠΈΡ ΡΠ΅Π»ΡΡ ΠΎΠΏΡΠ΅Π΄Π΅Π»ΠΈΡΡ ΠΈ ΠΏΠ΅ΡΠ΅ΡΠΈΡΠ»ΠΈΡΡ ΠΊΠΎΠ½ΠΊΡΠ΅ΡΠ½ΡΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π΄ΠΎΡΡΠΈΠΆΠ΅Π½ΠΈΡ, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡΡΠΈΠ΅ ΡΡΠΊΠΎΡΠΈΡΡ ΠΏΡΠΎΡΠ΅ΡΡ ΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΈΡΠΏΠΎΠ»Π½ΠΈΡΠ΅Π»ΡΡΠΊΠΈΡ
Π½Π°Π²ΡΠΊΠΎΠ², Π° ΡΠ°ΠΊΠΆΠ΅ Π°Π΄Π°ΠΏΡΠΈΡΠΎΠ²Π°ΡΡ ΠΈΡ
ΠΏΠΎΠ΄ ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΠ΅ ΡΠ΅Π½Π΄Π΅Π½ΡΠΈΠΈ, ΡΠ°ΠΊ ΠΊΠ°ΠΊ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ Π±Π΅Π·Π³ΡΠ°Π½ΠΈΡΠ½Ρ, Π½ΠΎ ΠΏΡΠ΅Π΄Π»Π°Π³Π°Π΅Ρ ΠΎΡΠ΅Π½ΠΈΡΡ ΠΈ Π²Π½Π΅Π΄ΡΠΈΡΡ ΠΏΡΠΈΠ½ΡΠΈΠΏΠΈΠ°Π»ΡΠ½ΠΎ Π½ΠΎΠ²ΡΠΉ ΠΏΠΎΠ΄Ρ
ΠΎΠ΄ Π² ΠΎΠ±ΡΡΠ΅Π½ΠΈ
Porous Silicon Photonic Crystal as a Substrate for High Efficiency Biosensing
Photonic crystals offer great possibilities for the improvement of performance of different kinds of devices. Due to the ability to control the light propagation and to change optical properties via interaction with the media photonic crystals have been widely used to increase the sensitivity of biosensing in many experimental setups. Among them some of the most interesting for practical applications are one-dimensional porous silicon photonic crystals. They could be easily fabricated, have big surface area, high sorption abilities, and have been shown to be able to change the emission of embedded luminophores. In this study we have fabricatedand performed the comprehensive investigation of the properties of hybrid system consisting of the porous silicon one-dimensional photonic crystals embedded with semiconductor quantum dots as the luminophores. We have demonstrated the ability of these systems to enhance the photoluminescence of luminophores and serve as the substrate for the high efficient biosensing.
Keywords: Porous silicon, microcavity, quantum dots, luminescence enhancemen
Modeling and Optimization of the Porous Silicon Photonic Structures
Photonic crystals and optical devices based on them are of great interest nowadays and are widely used in photonics, optoelectronics, and biosensing. One of the most practically using materials to fabricate one-dimensional photonic crystal is porous silicon due to the simple fabrication process, high porosity and ability to select precisely the refractive index by controlling the porosity. It has already been shown as the suitable material to be used as an element of many photonic devices including gas sensors and biosensors. However, because of the complicated porous structure, and silicon oxidation, occurring at the atmosphere conditions, optical properties of porous silicon photonic structures need to be stabilized by preventive oxidation. In order to predict eventual optical properties of fabricated photonic structures an adequate modeling should be performed. In our study we have developed a calculation model based on the combination of effective media approximations and transfer matrix method, which could precisely predict the reflection, transmission of the porous silicon photonic structures taking into account the dispersion of the refractive index of silicon and silicon oxide, and the oxidation degree. We also used numerical finite-difference time-domain calculations in order to investigate the luminescent properties of the lumiphores embedded into the porous photonic structure.
Keywords: Porous silicon, microcavity, transfer matrix, effective media, FDT
Nonsteady condensation and evaporation waves
We study motion of a phase transition front at a constant temperature between
stable and metastable states in fluids with the universal Van der Waals
equation of state (which is valid sufficiently close to the fluid's critical
point). We focus on a case of relatively large metastability and low viscosity,
when it can be shown analytically that no steadily moving phase-transition
front exists. Numerically simulating a system of the one-dimensional
Navier-Stokes and continuity equations, we find that, in this case, the
nonsteady phase-transition front emits acoustic shocks in forward and backward
directions. Through this mechanism, the front drops its velocity and eventually
comes to a halt. The acoustic shock wave may shuttle, bouncing elastically from
the system's edge and strongly inelastically from the phase transition front.
Nonsteady rarefaction shock waves appear in the shuttle process, despite the
fact that the model does not admit steady rarefaction waves propagating between
stationary states. If the viscosity is below a certain threshold, an
instability sets in, driving the system into a turbulent state. This work was
supported by the Japan Society for Promotion of Science.Comment: revtex text file and four eps files with figures. Physical Review
Letters, in pres
Π’Π΅ΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠ°Ρ Π³ΡΡΠΏΠΏΠ° Β«ΠΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΠ΅ ΡΠ΅Ρ Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² Π°Π½Π³Π»ΠΈΠΉΡΠΊΠΎΠΌ ΡΠ·ΡΠΊΠ΅
The article deals with the national specificity of the English thematic group Β«Information technologiesΒ». The aim of the undertaken research was to describe and analyze the composition of the group. The components of this group were selected from the Dictionary of the information security terms. The research has shown that the English thematic group Β«Information technologiesΒ» comprises 519 lexical units, which were categorized according to the semantic criteria into six subgroups: 1) The names of people involved in the sphere of the information technologies (IT); 2) The names of the attributes of the IT; 3) The names of the attacks in the sphere of the IT; 4) The names of the documents connected with the IT; 5) The names of actions performed in the sphere of the IT; 6) The names of the IT characteristics. The group structure analysis has revealed 6 subgroups, 24 minigroups, 10 microgroups, thus 40 structural elements in total.Π ΡΡΠ°ΡΡΠ΅ ΡΠ°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°Π΅ΡΡΡ Π½Π°ΡΠΈΠΎΠ½Π°Π»ΡΠ½Π°Ρ ΡΠΏΠ΅ΡΠΈΡΠΈΠΊΠ° ΡΠ΅ΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π³ΡΡΠΏΠΏΡ Β«ΠΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² Π°Π½Π³Π»ΠΈΠΉΡΠΊΠΎΠΌ ΡΠ·ΡΠΊΠ΅. Π¦Π΅Π»Ρ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½Π½ΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ β ΠΎΠΏΡΠ΅Π΄Π΅Π»ΠΈΡΡ ΡΠΎΡΡΠ°Π² ΡΠ΅ΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π³ΡΡΠΏΠΏΡ Β«ΠΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² Π°Π½Π³Π»ΠΈΠΉΡΠΊΠΎΠΌ ΡΠ·ΡΠΊΠ΅ ΠΈ ΡΡΡΡΠΊΡΡΡΠΈΡΠΎΠ²Π°ΡΡ Π΅Π΅ ΠΏΠΎ ΡΠ΅ΠΌΠ°Π½ΡΠΈΡΠ΅ΡΠΊΠΎΠΌΡ ΠΊΡΠΈΡΠ΅ΡΠΈΡ. ΠΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠΌ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΏΠΎΡΠ»ΡΠΆΠΈΠ»ΠΈ ΡΡΠ±ΡΡΠ°Π½ΡΠΈΠ²Π½ΡΠ΅ Π΅Π΄ΠΈΠ½ΠΈΡΡ, ΠΎΡΠΎΠ±ΡΠ°Π½Π½ΡΠ΅ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ ΡΠΏΠ»ΠΎΡΠ½ΠΎΠΉ Π²ΡΠ±ΠΎΡΠΊΠΈ ΠΈΠ· Π‘Π»ΠΎΠ²Π°ΡΡ ΡΠ΅ΡΠΌΠΈΠ½ΠΎΠ² ΠΏΠΎ ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΠΎΠΉ Π±Π΅Π·ΠΎΠΏΠ°ΡΠ½ΠΎΡΡΠΈ. ΠΠ½Π°Π»ΠΈΠ· ΠΏΠΎΠΊΠ°Π·Π°Π», ΡΡΠΎ ΡΠ΅ΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠ°Ρ Π³ΡΡΠΏΠΏΠ° Β«ΠΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² Π°Π½Π³Π»ΠΈΠΉΡΠΊΠΎΠΌ ΡΠ·ΡΠΊΠ΅ Π²ΠΊΠ»ΡΡΠ°Π΅Ρ Π² ΡΠ΅Π±Ρ 519 Π»Π΅ΠΊΡΠΈΡΠ΅ΡΠΊΠΈΡ
Π΅Π΄ΠΈΠ½ΠΈΡ, ΠΊΠΎΡΠΎΡΡΠ΅ ΠΏΠΎΠ΄ΡΠ°Π·Π΄Π΅Π»ΡΡΡΡΡ Π½Π° 6 ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏ: 1) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ Π»ΠΈΡ, ΡΠΏΠ΅ΡΠΈΠ°Π»ΠΈΠ·ΠΈΡΡΡΡΠΈΡ
ΡΡ Π² ΡΡΠ΅ΡΠ΅ ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ (ΠΠ’); 2) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ ΡΡΠ΅Π΄ΡΡΠ², ΠΏΡΠΈΠΌΠ΅Π½ΡΠ΅ΠΌΡΡ
Π² ΡΡΠ΅ΡΠ΅ ΠΠ’; 3) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ Π²ΠΈΠ΄ΠΎΠ² Π°ΡΠ°ΠΊ Π½Π° ΠΏΡΠΎΠ³ΡΠ°ΠΌΠΌΠ½ΠΎΠ΅ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠ΅Π½ΠΈΠ΅; 4) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ Π΄ΠΎΠΊΡΠΌΠ΅Π½ΡΠ°ΡΠΈΠΈ, ΡΠ²ΡΠ·Π°Π½Π½ΠΎΠΉ Ρ ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΠΌΠΈ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠΌΠΈ; 5) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ Π΄Π΅ΠΉΡΡΠ²ΠΈΠΉ, ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΠΌΡΡ
Π² ΡΡΠ΅ΡΠ΅ ΠΠ’; 6) ΠΠ°ΠΈΠΌΠ΅Π½ΠΎΠ²Π°Π½ΠΈΡ ΡΠ²ΠΎΠΉΡΡΠ² ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ. ΠΠ½Π°Π»ΠΈΠ· ΡΡΡΡΠΊΡΡΡΠ½ΠΎΠΉ ΡΠ»ΠΎΠΆΠ½ΠΎΡΡΠΈ Π²ΡΡΠ²ΠΈΠ», ΡΡΠΎ Π΄Π°Π½Π½Π°Ρ Π³ΡΡΠΏΠΏΠ° Π»Π΅ΠΊΡΠΈΠΊΠΈ ΡΠΎΡΡΠΎΠΈΡ ΠΈΠ· 6 ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏ, 24 ΠΌΠΈΠ½ΠΈΠ³ΡΡΠΏΠΏ, 10 ΠΌΠΈΠΊΡΠΎΠ³ΡΡΠΏΠΏ, ΠΈΡΠΎΠ³ΠΎ β 40 ΡΡΡΡΠΊΡΡΡΠ½ΡΡ
Π΅Π΄ΠΈΠ½ΠΈΡ
Fine-tuning of Silica Coating Procedure for Preparation of Biocompatible and Bright Pbs/Sio2 Qds
Near-infrared semiconductor PbS quantum dots (QDs) with emission in biological transparency window are promising material for in vivo biolabelling and deep-tissue imaging of biological specimen. Among various approaches that render initially hydrophobic and toxic QDs biocompatible, the growth of a silica shell on the QD surface represents an efficient method to minimize QD toxicity. Nevertheless, it is important to preserve QDs emission properties after the silica coating procedure. Here we report on the optimal parameters of this procedure which allow to obtain a stable silica shell and maintain the optical properties of initial PbS QDs. Furthermore, we show that PbS QDs with the optimal SiO2 shell retain their luminescence quantum yield even after condensation into a solid film. Thus, our procedure can become a basis in development of bright, receptor-targeted NIR fluorescent probes for in vivo tumor imaging.
Keywords: quantum dot, SiO2 shell, bioimagin
Π Π°Π·Π»ΠΈΡΠ½ΡΠ΅ ΠΌΠ΅ΡΠΎΠ΄Ρ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ ΡΠ΅ΠΌΠ°Π½ΡΠΈΠΊΠΈ Π»Π΅ΠΊΡΠ΅ΠΌΡ
The article analyzes the ways of studying the semantics of a word. At the current stage of development of the linguistic science various methods of studying the meaning of a lexeme have been proposed by different linguistic schools. The peculiarities of the component, contrastive and contextual analysis of the lexeme Β«battleΒ» are described in this article. The undertaken research shows that different methods of linguistic analysis of a word are aimed at different semantic aspects. Due to the component analysis the semantically closest lexemes have been identified. The contrastive analysis has identified the best translation of the lexeme Β«battleΒ». The contextual analysis has shown how the meaning of the lexeme Β«battleΒ» changes depending on the context. As a result, all the semantic components, the lexicographic and communicative meanings of the word βbattleβ have been identified. The research shows that all these methods are interrelated and allow to perform deeper analysis of a lexeme.Π ΡΡΠ°ΡΡΠ΅ Π°Π½Π°Π»ΠΈΠ·ΠΈΡΡΡΡΡΡ ΡΠ°Π·Π»ΠΈΡΠ½ΡΠ΅ ΡΠΏΠΎΡΠΎΠ±Ρ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ ΡΠ΅ΠΌΠ°Π½ΡΠΈΠΊΠΈ Π»Π΅ΠΊΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π΅Π΄ΠΈΠ½ΠΈΡΡ. ΠΠ° Π΄Π°Π½Π½ΠΎΠΌ ΡΡΠ°ΠΏΠ΅ ΡΠ°Π·Π²ΠΈΡΠΈΡ Π»ΠΈΠ½Π³Π²ΠΈΡΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π½Π°ΡΠΊΠΈ ΡΠ°Π·Π½ΡΠΌΠΈ Π»ΠΈΠ½Π³Π²ΠΈΡΡΠΈΡΠ΅ΡΠΊΠΈΠΌΠΈ ΡΠΊΠΎΠ»Π°ΠΌΠΈ ΠΏΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ ΡΠ°Π·Π»ΠΈΡΠ½ΡΠ΅ ΠΌΠ΅ΡΠΎΠ΄Ρ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ Π·Π½Π°ΡΠ΅Π½ΠΈΡ Π»Π΅ΠΊΡΠ΅ΠΌΡ. Π Π΄Π°Π½Π½ΠΎΠΉ ΡΡΠ°ΡΡΠ΅ ΡΠ°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°ΡΡΡΡ ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠΈ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½ΠΎΠ³ΠΎ, ΠΊΠΎΠ½ΡΡΠ°ΡΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΠΈ ΠΊΠΎΠ½ΡΠ΅ΠΊΡΡΡΠ°Π»ΡΠ½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° Π»Π΅ΠΊΡΠ΅ΠΌΡ βbattleβ. ΠΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΏΠΎΠΊΠ°Π·Π°Π»ΠΎ, ΡΡΠΎ ΡΠ°Π·Π»ΠΈΡΠ½ΡΠ΅ ΠΌΠ΅ΡΠΎΠ΄Ρ Π»ΠΈΠ½Π³Π²ΠΈΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½Ρ Π½Π° ΡΠ°Π·Π»ΠΈΡΠ½ΡΠ΅ ΡΠ΅ΠΌΠ°Π½ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π°ΡΠΏΠ΅ΠΊΡΡ. Π Ρ
ΠΎΠ΄Π΅ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Ρ ΡΠ΅ΠΌΠ°Π½ΡΠΈΡΠ΅ΡΠΊΠΈ Π±Π»ΠΈΠ·ΠΊΠΈΠ΅ Π»Π΅ΠΊΡΠ΅ΠΌΡ. ΠΠΎΠ½ΡΡΠ°ΡΡΠΈΠ²Π½ΡΠΉ Π°Π½Π°Π»ΠΈΠ· ΠΏΠΎΠΌΠΎΠ³Π°Π΅Ρ Π²ΡΠ±ΡΠ°ΡΡ Π»ΡΡΡΠΈΠΉ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ΄ Π»Π΅ΠΊΡΠ΅ΠΌΡ Β«battleΒ». ΠΠΎΠ½ΡΠ΅ΠΊΡΡΡΠ°Π»ΡΠ½ΡΠΉ Π°Π½Π°Π»ΠΈΠ· Π΄Π΅ΠΌΠΎΠ½ΡΡΡΠΈΡΡΠ΅Ρ ΠΊΠ°ΠΊ Π·Π½Π°ΡΠ΅Π½ΠΈΠ΅ Π»Π΅ΠΊΡΠ΅ΠΌΡ Β«battleΒ» ΠΌΠ΅Π½ΡΠ΅ΡΡΡ Π² Π·Π°Π²ΠΈΡΠΈΠΌΠΎΡΡΠΈ ΠΎΡ ΠΊΠΎΠ½ΡΠ΅ΠΊΡΡΠ°. Π ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π±ΡΠ»ΠΈ Π²ΡΡΠ²Π»Π΅Π½Ρ Π²ΡΠ΅ ΡΠ΅ΠΌΠ°Π½ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΡ, Π»Π΅ΠΊΡΠΈΠΊΠΎΠ³ΡΠ°ΡΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΈ ΠΊΠΎΠΌΠΌΡΠ½ΠΈΠΊΠ°ΡΠΈΠ²Π½ΠΎΠ΅ Π·Π½Π°ΡΠ΅Π½ΠΈΡ Π»Π΅ΠΊΡΠ΅ΠΌΡ Β«battleΒ». ΠΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΏΠΎΠΊΠ°Π·ΡΠ²Π°Π΅Ρ, ΡΡΠΎ Π²ΡΠ΅ ΠΌΠ΅ΡΠΎΠ΄Ρ Π²Π·Π°ΠΈΠΌΠΎΡΠ²ΡΠ·Π°Π½Ρ ΠΈ ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡΡ ΠΎΡΡΡΠ΅ΡΡΠ²ΠΈΡΡ Π±ΠΎΠ»Π΅Π΅ Π³Π»ΡΠ±ΠΎΠΊΠΈΠΉ Π°Π½Π°Π»ΠΈΠ· ΡΠ»ΠΎΠ²Π°
Highly Stable, Water-Soluble CdSe/ZnS/CdS/ZnS Quantum Dots with Additional SiO2 shell
Quantum dots (QDs) are fluorescent nanocrystals extensively used today in research and applications. They attract much interest due to the high photostability and fluorescence quantum yields close to 100%. The best QDs are made by synthesis in organic media, and they have to be transferred into aqueous solutions if biomedical applications are concerned. An advanced method for rendering QDs water-soluble is to coat them with hydrophilic SiO2 -layer. However, growing a silica shell with a predetermined thickness is a problem, because uncertain values of the molar extinction coefficients (Ξ΅) of core/shell QDs made it impossible to calculate precise yields of the chemical reactions involved. Here we suggest an approach to solving this problem by constructing the structural models of per se and silica-coated QDs followed by measuring Ξ΅ in a course of the QD synthesis, thus carrying out precise quantitative reactions. Proceeding in such a way, we prepared the CdSe/ZnS/CdS/ZnS QDs with the structure predicted by the model and coated by silica shell. Prepared QDs are characterized by a narrow size distribution and the same fluorescence parameters as the original QDs in the organic medium. Developed approach permitted efficient QDs water-solubilisation and preparation of stable nanoparticles for plethora of biomedical applications.
Keywords: Quantum dots, QD, silica shell, core-shel
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