104 research outputs found

    Formation of instrumental executive skills of student-bachelors in music pedagogical education

    Full text link
    The article actualizes the problem of forming instrumental performing skills for bachelor students of music and pedagogical education. The notion Β«instrumental performing skillsΒ» is formulated, stages of their formation are offered. The possibilities of introduction of modern computer tools in the educational process are consideredΠ’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ актуализируСтся ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌΠ° формирования ΠΈΠ½ΡΡ‚Ρ€ΡƒΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Ρ… ΠΈΡΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΡΠΊΠΈΡ… Π½Π°Π²Ρ‹ΠΊΠΎΠ² Ρƒ студСнтов-Π±Π°ΠΊΠ°Π»Π°Π²Ρ€ΠΎΠ² ΠΌΡƒΠ·Ρ‹ΠΊΠ°Π»ΡŒΠ½ΠΎ-пСдагогичСского образования. ЀормулируСтся понятиС Β«ΠΈΠ½ΡΡ‚Ρ€ΡƒΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Π΅ ΠΈΡΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΡΠΊΠΈΠ΅ Π½Π°Π²Ρ‹ΠΊΠΈΒ», ΠΏΡ€Π΅Π΄Π»Π°Π³Π°ΡŽΡ‚ΡΡ этапы ΠΈΡ… формирования. Π Π°ΡΡΠΌΠ°Ρ‚Ρ€ΠΈΠ²Π°ΡŽΡ‚ΡΡ возмоТности внСдрСния соврСмСнных ΠΊΠΎΠΌΠΏΡŒΡŽΡ‚Π΅Ρ€Π½Ρ‹Ρ… срСдств Π² ΡƒΡ‡Π΅Π±Π½Ρ‹ΠΉ процСс

    The problem of performing skills’ formation of undergraduate students in the realities of the existing teaching methods

    Full text link
    The article describes the main reasons for reducing the rate of performing skills’ development of undergraduate students within a modern education system. Possibilities of educational program’s reforming by applying the musical-computer technology as a part of a curriculum and teacher’s tool used to increase the level of student’s interest in a self-learning are concerned. The examples of the base used by the software to achieve the main objectives – good fundamental understanding of the subject and facilitation of the performance skills’ acquisition by increasing the personal interest of the student in this process are given. The author of the article does not aim to identify and list specific technological achievements which allow to accelerate the process of performing skills’ development, as well as to adapt them according to the current trends, since the technological possibilities are endless, but offers to evaluate and implement a fundamentally new approach in teachingΠ’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ Ρ€Π°ΡΠΊΡ€Ρ‹Π²Π°ΡŽΡ‚ΡΡ основныС ΠΏΡ€ΠΈΡ‡ΠΈΠ½Ρ‹ сниТСния скорости формирования ΠΈΡΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΡΠΊΠΈΡ… Π½Π°Π²Ρ‹ΠΊΠΎΠ² Ρƒ студСнтов-Π±Π°ΠΊΠ°Π»Π°Π²Ρ€ΠΎΠ² Π² Ρ€Π°ΠΌΠΊΠ°Ρ… соврСмСнной систСмы образования. Π Π°ΡΡΠΌΠ°Ρ‚Ρ€ΠΈΠ²Π°ΡŽΡ‚ΡΡ возмоТности рСформирования ΠΎΠ±Ρ€Π°Π·ΠΎΠ²Π°Ρ‚Π΅Π»ΡŒΠ½ΠΎΠΉ ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΡ‹ ΠΏΡƒΡ‚Π΅ΠΌ примСнСния ΠΌΡƒΠ·Ρ‹ΠΊΠ°Π»ΡŒΠ½ΠΎ-ΠΊΠΎΠΌΠΏΡŒΡŽΡ‚Π΅Ρ€Π½Ρ‹Ρ… Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ, ΠΊΠ°ΠΊ составной части ΡƒΡ‡Π΅Π±Π½ΠΎΠ³ΠΎ ΠΏΠ»Π°Π½Π° ΠΈ инструмСнта ΠΏΠ΅Π΄Π°Π³ΠΎΠ³Π°, ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΠ΅ΠΌΠΎΠ³ΠΎ для ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡ уровня заинтСрСсованности студСнта Π² самообучСнии. ΠŸΡ€ΠΈΠ²ΠΎΠ΄ΡΡ‚ΡΡ ΠΏΡ€ΠΈΠΌΠ΅Ρ€Ρ‹ ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΠ΅ΠΌΠΎΠΉ ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½ΠΎΠΉ Π±Π°Π·Ρ‹ для достиТСния основной Π·Π°Π΄Π°Ρ‡ΠΈ – качСствСнного ΠΈ Π³Π»ΡƒΠ±ΠΎΠΊΠΎΠ³ΠΎ понимания ΠΏΡ€Π΅Π΄ΠΌΠ΅Ρ‚Π° ΠΈ упрощСния приобрСтСния ΠΈΡΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΡΠΊΠΈΡ… Π½Π°Π²Ρ‹ΠΊΠΎΠ² ΠΏΡƒΡ‚Π΅ΠΌ ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡ Π»ΠΈΡ‡Π½ΠΎΠΉ заинтСрСсованности студСнта Π² Π΄Π°Π½Π½ΠΎΠΌ процСссС. Автор ΡΡ‚Π°Ρ‚ΡŒΠΈ Π½Π΅ ставит Ρ†Π΅Π»ΡŒΡŽ ΠΎΠΏΡ€Π΅Π΄Π΅Π»ΠΈΡ‚ΡŒ ΠΈ ΠΏΠ΅Ρ€Π΅Ρ‡ΠΈΡΠ»ΠΈΡ‚ΡŒ ΠΊΠΎΠ½ΠΊΡ€Π΅Ρ‚Π½Ρ‹Π΅ тСхнологичСскиС достиТСния, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡŽΡ‰ΠΈΠ΅ ΡƒΡΠΊΠΎΡ€ΠΈΡ‚ΡŒ процСсс формирования ΠΈΡΠΏΠΎΠ»Π½ΠΈΡ‚Π΅Π»ΡŒΡΠΊΠΈΡ… Π½Π°Π²Ρ‹ΠΊΠΎΠ², Π° Ρ‚Π°ΠΊΠΆΠ΅ Π°Π΄Π°ΠΏΡ‚ΠΈΡ€ΠΎΠ²Π°Ρ‚ΡŒ ΠΈΡ… ΠΏΠΎΠ΄ соврСмСнныС Ρ‚Π΅Π½Π΄Π΅Π½Ρ†ΠΈΠΈ, Ρ‚Π°ΠΊ ΠΊΠ°ΠΊ тСхнологичСскиС возмоТности Π±Π΅Π·Π³Ρ€Π°Π½ΠΈΡ‡Π½Ρ‹, Π½ΠΎ ΠΏΡ€Π΅Π΄Π»Π°Π³Π°Π΅Ρ‚ ΠΎΡ†Π΅Π½ΠΈΡ‚ΡŒ ΠΈ Π²Π½Π΅Π΄Ρ€ΠΈΡ‚ΡŒ ΠΏΡ€ΠΈΠ½Ρ†ΠΈΠΏΠΈΠ°Π»ΡŒΠ½ΠΎ Π½ΠΎΠ²Ρ‹ΠΉ ΠΏΠΎΠ΄Ρ…ΠΎΠ΄ Π² ΠΎΠ±ΡƒΡ‡Π΅Π½ΠΈ

    Porous Silicon Photonic Crystal as a Substrate for High Efficiency Biosensing

    Get PDF
    Photonic crystals offer great possibilities for the improvement of performance of different kinds of devices. Due to the ability to control the light propagation and to change optical properties via interaction with the media photonic crystals have been widely used to increase the sensitivity of biosensing in many experimental setups. Among them some of the most interesting for practical applications are one-dimensional porous silicon photonic crystals. They could be easily fabricated, have big surface area, high sorption abilities, and have been shown to be able to change the emission of embedded luminophores. In this study we have fabricatedand performed the comprehensive investigation of the properties of hybrid system consisting of the porous silicon one-dimensional photonic crystals embedded with semiconductor quantum dots as the luminophores. We have demonstrated the ability of these systems to enhance the photoluminescence of luminophores and serve as the substrate for the high efficient biosensing. Keywords: Porous silicon, microcavity, quantum dots, luminescence enhancemen

    Modeling and Optimization of the Porous Silicon Photonic Structures

    Get PDF
    Photonic crystals and optical devices based on them are of great interest nowadays and are widely used in photonics, optoelectronics, and biosensing. One of the most practically using materials to fabricate one-dimensional photonic crystal is porous silicon due to the simple fabrication process, high porosity and ability to select precisely the refractive index by controlling the porosity. It has already been shown as the suitable material to be used as an element of many photonic devices including gas sensors and biosensors. However, because of the complicated porous structure, and silicon oxidation, occurring at the atmosphere conditions, optical properties of porous silicon photonic structures need to be stabilized by preventive oxidation. In order to predict eventual optical properties of fabricated photonic structures an adequate modeling should be performed. In our study we have developed a calculation model based on the combination of effective media approximations and transfer matrix method, which could precisely predict the reflection, transmission of the porous silicon photonic structures taking into account the dispersion of the refractive index of silicon and silicon oxide, and the oxidation degree. We also used numerical finite-difference time-domain calculations in order to investigate the luminescent properties of the lumiphores embedded into the porous photonic structure. Keywords: Porous silicon, microcavity, transfer matrix, effective media, FDT

    Nonsteady condensation and evaporation waves

    Full text link
    We study motion of a phase transition front at a constant temperature between stable and metastable states in fluids with the universal Van der Waals equation of state (which is valid sufficiently close to the fluid's critical point). We focus on a case of relatively large metastability and low viscosity, when it can be shown analytically that no steadily moving phase-transition front exists. Numerically simulating a system of the one-dimensional Navier-Stokes and continuity equations, we find that, in this case, the nonsteady phase-transition front emits acoustic shocks in forward and backward directions. Through this mechanism, the front drops its velocity and eventually comes to a halt. The acoustic shock wave may shuttle, bouncing elastically from the system's edge and strongly inelastically from the phase transition front. Nonsteady rarefaction shock waves appear in the shuttle process, despite the fact that the model does not admit steady rarefaction waves propagating between stationary states. If the viscosity is below a certain threshold, an instability sets in, driving the system into a turbulent state. This work was supported by the Japan Society for Promotion of Science.Comment: revtex text file and four eps files with figures. Physical Review Letters, in pres

    ВСматичСская Π³Ρ€ΡƒΠΏΠΏΠ° Β«Π˜Π½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Π΅ Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² английском языкС

    Full text link
    The article deals with the national specificity of the English thematic group Β«Information technologiesΒ». The aim of the undertaken research was to describe and analyze the composition of the group. The components of this group were selected from the Dictionary of the information security terms. The research has shown that the English thematic group Β«Information technologiesΒ» comprises 519 lexical units, which were categorized according to the semantic criteria into six subgroups: 1) The names of people involved in the sphere of the information technologies (IT); 2) The names of the attributes of the IT; 3) The names of the attacks in the sphere of the IT; 4) The names of the documents connected with the IT; 5) The names of actions performed in the sphere of the IT; 6) The names of the IT characteristics. The group structure analysis has revealed 6 subgroups, 24 minigroups, 10 microgroups, thus 40 structural elements in total.Π’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ рассматриваСтся Π½Π°Ρ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½Π°Ρ спСцифика тСматичСской Π³Ρ€ΡƒΠΏΠΏΡ‹ Β«Π˜Π½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Π΅ Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² английском языкС. ЦСль ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½Π½ΠΎΠ³ΠΎ исслСдования – ΠΎΠΏΡ€Π΅Π΄Π΅Π»ΠΈΡ‚ΡŒ состав тСматичСской Π³Ρ€ΡƒΠΏΠΏΡ‹ Β«Π˜Π½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Π΅ Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² английском языкС ΠΈ ΡΡ‚Ρ€ΡƒΠΊΡ‚ΡƒΡ€ΠΈΡ€ΠΎΠ²Π°Ρ‚ΡŒ Π΅Π΅ ΠΏΠΎ сСмантичСскому ΠΊΡ€ΠΈΡ‚Π΅Ρ€ΠΈΡŽ. ΠœΠ°Ρ‚Π΅Ρ€ΠΈΠ°Π»ΠΎΠΌ исслСдования послуТили субстантивныС Π΅Π΄ΠΈΠ½ΠΈΡ†Ρ‹, ΠΎΡ‚ΠΎΠ±Ρ€Π°Π½Π½Ρ‹Π΅ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ сплошной Π²Ρ‹Π±ΠΎΡ€ΠΊΠΈ ΠΈΠ· Бловаря Ρ‚Π΅Ρ€ΠΌΠΈΠ½ΠΎΠ² ΠΏΠΎ ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½ΠΎΠΉ бСзопасности. Анализ ΠΏΠΎΠΊΠ°Π·Π°Π», Ρ‡Ρ‚ΠΎ тСматичСская Π³Ρ€ΡƒΠΏΠΏΠ° Β«Π˜Π½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Π΅ Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈΒ» Π² английском языкС Π²ΠΊΠ»ΡŽΡ‡Π°Π΅Ρ‚ Π² сСбя 519 лСксичСских Π΅Π΄ΠΈΠ½ΠΈΡ†, ΠΊΠΎΡ‚ΠΎΡ€Ρ‹Π΅ ΠΏΠΎΠ΄Ρ€Π°Π·Π΄Π΅Π»ΡΡŽΡ‚ΡΡ Π½Π° 6 ΠΏΠΎΠ΄Π³Ρ€ΡƒΠΏΠΏ: 1) НаимСнования Π»ΠΈΡ†, ΡΠΏΠ΅Ρ†ΠΈΠ°Π»ΠΈΠ·ΠΈΡ€ΡƒΡŽΡ‰ΠΈΡ…ΡΡ Π² сфСрС ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Ρ… Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ (ИВ); 2) НаимСнования срСдств, примСняСмых Π² сфСрС ИВ; 3) НаимСнования Π²ΠΈΠ΄ΠΎΠ² Π°Ρ‚Π°ΠΊ Π½Π° ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½ΠΎΠ΅ обСспСчСниС; 4) НаимСнования Π΄ΠΎΠΊΡƒΠΌΠ΅Π½Ρ‚Π°Ρ†ΠΈΠΈ, связанной с ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹ΠΌΠΈ тСхнологиями; 5) НаимСнования дСйствий, ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΠΌΡ‹Ρ… Π² сфСрС ИВ; 6) НаимСнования свойств ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Ρ… Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ. Анализ структурной слоТности выявил, Ρ‡Ρ‚ΠΎ данная Π³Ρ€ΡƒΠΏΠΏΠ° лСксики состоит ΠΈΠ· 6 ΠΏΠΎΠ΄Π³Ρ€ΡƒΠΏΠΏ, 24 ΠΌΠΈΠ½ΠΈΠ³Ρ€ΡƒΠΏΠΏ, 10 ΠΌΠΈΠΊΡ€ΠΎΠ³Ρ€ΡƒΠΏΠΏ, ΠΈΡ‚ΠΎΠ³ΠΎ – 40 структурных Π΅Π΄ΠΈΠ½ΠΈΡ†

    Fine-tuning of Silica Coating Procedure for Preparation of Biocompatible and Bright Pbs/Sio2 Qds

    Get PDF
    Near-infrared semiconductor PbS quantum dots (QDs) with emission in biological transparency window are promising material for in vivo biolabelling and deep-tissue imaging of biological specimen. Among various approaches that render initially hydrophobic and toxic QDs biocompatible, the growth of a silica shell on the QD surface represents an efficient method to minimize QD toxicity. Nevertheless, it is important to preserve QDs emission properties after the silica coating procedure. Here we report on the optimal parameters of this procedure which allow to obtain a stable silica shell and maintain the optical properties of initial PbS QDs. Furthermore, we show that PbS QDs with the optimal SiO2 shell retain their luminescence quantum yield even after condensation into a solid film. Thus, our procedure can become a basis in development of bright, receptor-targeted NIR fluorescent probes for in vivo tumor imaging. Keywords: quantum dot, SiO2 shell, bioimagin

    Π Π°Π·Π»ΠΈΡ‡Π½Ρ‹Π΅ ΠΌΠ΅Ρ‚ΠΎΠ΄Ρ‹ изучСния сСмантики лСксСмы

    Full text link
    The article analyzes the ways of studying the semantics of a word. At the current stage of development of the linguistic science various methods of studying the meaning of a lexeme have been proposed by different linguistic schools. The peculiarities of the component, contrastive and contextual analysis of the lexeme Β«battleΒ» are described in this article. The undertaken research shows that different methods of linguistic analysis of a word are aimed at different semantic aspects. Due to the component analysis the semantically closest lexemes have been identified. The contrastive analysis has identified the best translation of the lexeme Β«battleΒ». The contextual analysis has shown how the meaning of the lexeme Β«battleΒ» changes depending on the context. As a result, all the semantic components, the lexicographic and communicative meanings of the word β€œbattle” have been identified. The research shows that all these methods are interrelated and allow to perform deeper analysis of a lexeme.Π’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ Π°Π½Π°Π»ΠΈΠ·ΠΈΡ€ΡƒΡŽΡ‚ΡΡ Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Π΅ способы изучСния сСмантики лСксичСской Π΅Π΄ΠΈΠ½ΠΈΡ†Ρ‹. На Π΄Π°Π½Π½ΠΎΠΌ этапС развития лингвистичСской Π½Π°ΡƒΠΊΠΈ Ρ€Π°Π·Π½Ρ‹ΠΌΠΈ лингвистичСскими школами ΠΏΡ€Π΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ‹ Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Π΅ ΠΌΠ΅Ρ‚ΠΎΠ΄Ρ‹ изучСния значСния лСксСмы. Π’ Π΄Π°Π½Π½ΠΎΠΉ ΡΡ‚Π°Ρ‚ΡŒΠ΅ Ρ€Π°ΡΡΠΌΠ°Ρ‚Ρ€ΠΈΠ²Π°ΡŽΡ‚ΡΡ особСнности ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ‚Π½ΠΎΠ³ΠΎ, контрастивного ΠΈ ΠΊΠΎΠ½Ρ‚Π΅ΠΊΡΡ‚ΡƒΠ°Π»ΡŒΠ½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° лСксСмы β€œbattle”. ИсслСдованиС ΠΏΠΎΠΊΠ°Π·Π°Π»ΠΎ, Ρ‡Ρ‚ΠΎ Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Π΅ ΠΌΠ΅Ρ‚ΠΎΠ΄Ρ‹ лингвистичСского Π°Π½Π°Π»ΠΈΠ·Π° Π½Π°ΠΏΡ€Π°Π²Π»Π΅Π½Ρ‹ Π½Π° Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Π΅ сСмантичСскиС аспСкты. Π’ Ρ…ΠΎΠ΄Π΅ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ‚Π½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° ΠΎΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½Ρ‹ сСмантичСски Π±Π»ΠΈΠ·ΠΊΠΈΠ΅ лСксСмы. ΠšΠΎΠ½Ρ‚Ρ€Π°ΡΡ‚ΠΈΠ²Π½Ρ‹ΠΉ Π°Π½Π°Π»ΠΈΠ· ΠΏΠΎΠΌΠΎΠ³Π°Π΅Ρ‚ Π²Ρ‹Π±Ρ€Π°Ρ‚ΡŒ Π»ΡƒΡ‡ΡˆΠΈΠΉ ΠΏΠ΅Ρ€Π΅Π²ΠΎΠ΄ лСксСмы Β«battleΒ». ΠšΠΎΠ½Ρ‚Π΅ΠΊΡΡ‚ΡƒΠ°Π»ΡŒΠ½Ρ‹ΠΉ Π°Π½Π°Π»ΠΈΠ· дСмонстрируСт ΠΊΠ°ΠΊ Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ лСксСмы Β«battleΒ» мСняСтся Π² зависимости ΠΎΡ‚ контСкста. Π’ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π΅ исслСдования Π±Ρ‹Π»ΠΈ выявлСны всС сСмантичСскиС ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ‚Ρ‹, лСксикографичСскоС ΠΈ ΠΊΠΎΠΌΠΌΡƒΠ½ΠΈΠΊΠ°Ρ‚ΠΈΠ²Π½ΠΎΠ΅ значСния лСксСмы Β«battleΒ». ИсслСдованиС ΠΏΠΎΠΊΠ°Π·Ρ‹Π²Π°Π΅Ρ‚, Ρ‡Ρ‚ΠΎ всС ΠΌΠ΅Ρ‚ΠΎΠ΄Ρ‹ взаимосвязаны ΠΈ ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡŽΡ‚ ΠΎΡΡƒΡ‰Π΅ΡΡ‚Π²ΠΈΡ‚ΡŒ Π±ΠΎΠ»Π΅Π΅ Π³Π»ΡƒΠ±ΠΎΠΊΠΈΠΉ Π°Π½Π°Π»ΠΈΠ· слова

    Highly Stable, Water-Soluble CdSe/ZnS/CdS/ZnS Quantum Dots with Additional SiO2 shell

    Get PDF
    Quantum dots (QDs) are fluorescent nanocrystals extensively used today in research and applications. They attract much interest due to the high photostability and fluorescence quantum yields close to 100%. The best QDs are made by synthesis in organic media, and they have to be transferred into aqueous solutions if biomedical applications are concerned. An advanced method for rendering QDs water-soluble is to coat them with hydrophilic SiO2 -layer. However, growing a silica shell with a predetermined thickness is a problem, because uncertain values of the molar extinction coefficients (Ξ΅) of core/shell QDs made it impossible to calculate precise yields of the chemical reactions involved. Here we suggest an approach to solving this problem by constructing the structural models of per se and silica-coated QDs followed by measuring Ξ΅ in a course of the QD synthesis, thus carrying out precise quantitative reactions. Proceeding in such a way, we prepared the CdSe/ZnS/CdS/ZnS QDs with the structure predicted by the model and coated by silica shell. Prepared QDs are characterized by a narrow size distribution and the same fluorescence parameters as the original QDs in the organic medium. Developed approach permitted efficient QDs water-solubilisation and preparation of stable nanoparticles for plethora of biomedical applications.     Keywords: Quantum dots, QD, silica shell, core-shel
    • …
    corecore