26 research outputs found
The effect of graphene oxide (GO) nanoparticles on the processing of epoxy/glass fiber composites using resin infusion
In this paper, the effects of graphene oxide (GO) nanoparticles on glass fiber composite processing by incorporating them into epoxy resin were investigated. GO was synthesized from graphite powder and was mixed with epoxy resin. Three different GO contents of 0.05, 0.1, and 0.2 wt% were used. Epoxy/GO samples were tested for rheology and cure kinetics to evaluate the effects of GO content on important resin infusion processing parameters. The results show that adding GO to neat epoxy resin increased the viscosity and affected the resin cure reaction by reducing the resin gel time. After that, glass fiber composites were prepared using the resin infusion process. Samples with 0.2 wt% GO result in very slow resin infiltration time with premature resin gelation. A 30 % increase in flexural strength and a 21 % increase in flexural modulus are manifested by adding GO as the secondary reinforcement to glass fiber composites
(KES-SDM 19)
Among the various applications of graphene is the heating purpose due to its promising thermal conductivity. This paper presents a life cycle model of graphene, capturing the “cradle to gate” approach, focusing on energy consumption and environmental impact of gra-phene. The embodied energy consumption was calculated based on em-pirical data in scientific papers, patents and databases while life cycle assessment modelling software was utilised for analysing its environ-mental impact. The result from the analysis shows that, the embodied energy for the synthesis of 1 kg of graphene ranges between 264-304 MJ. Further analysis shows that, 42% of graphene embodied energy is consumed from powder preparation through to graphitization process. Moreover, the result obtained from the modelling shows dust particles and CO2 emissions into air during graphene production. This paper should be followed by further study on graphene use and end of life phases to establish a comparison with the traditional heating materials
Electrochemical analysis of Co3(PO4)2·4H2O/graphene foam composite for enhanced capacity and long cycle life hybrid asymmetric capacitors
In this paper, we explore the successful hydrothermal approach to make Co3(PO4)2·4H2O/GF micro-flakes composite material. The unique sheet-like structure of the graphene foam (GF) significantly improved the conductivity of the pristine Co-based material, which is a key limitation in supercapacitors application. The composite electrode material exhibited superior capacitive conduct in 6 M KOH aqueous electrolyte in a 3-electrode set-up as compared to the pristine cobalt phosphate material. The material was subsequently adopted as a cathode in an asymmetric cell configuration with carbonization of Fe cations adsorbed onto polyaniline (PANI) (C-Fe/PANI), as the anode. The Co3(PO4)2·4H2O/GF//C-FP hybrid device showed outstanding long life cycling stability of approximately 99% without degradation up to 10000 cycles. A specific energy density as high as 24 W h kg−1, with a corresponding power density of 468 W kg−1 was achieved for the device. The results demonstrated the efficient utilization of the faradic-type Co3(PO4)2·4H2O/GF composite along with a functionalized carbonaceous electric double layer (EDL)-type material to produce a hybrid device with promising features suitable for energy storage applications.The South African Research Chairs Initiative (SARChI) of the Department of Science and Technology and the National Research Foundation (NRF) of South Africa (Grant No. 61056). Abdulmajid A. Mirghni acknowledges the financial support from University of Pretoria, the NRF through the SARChI in Carbon Technology and Materials, and also Al Fashir University, Sudan.http://www.elsevier.com/locate/electacta2019-09-01hj2018Physic