Mott transition in Cr-doped V2O3 studied by ultrafast reflectivity: electron correlation effects on the transient response

The ultrafast response of the prototype Mott-Hubbard system (V1-xCrx)2O3 was systematically studied with fs pump-probe reflectivity, allowing us to clearly identify the effects of the metal-insulator transition on the transient response. The isostructural nature of the phase transition in this material made it possible to follow across the phase diagram the behaviour of the detected coherent acoustic wave, whose average value and lifetime depend on the thermodynamic phase and on the correlated electron density of states. It is also shown how coherent lattice oscillations can play an important role in some changes affecting the ultrafast electronic peak relaxation at the phase transition, changes which should not be mistakenly attributed to genuine electronic effects. These results clearly show that a thorough understanding of the ultrafast response of the material over several tenths of ps is necessary to correctly interpret its sub-ps excitation and relaxation regime, and appear to be of general interest also for other strongly correlated materials.Comment: 6 pages, 3 figures. Europhysics Letters (in press

Powder bed monitoring via digital image analysis in additive manufacturing

Due to the nature of Selective Laser Melting process, the built parts suffer from high chances of defects formation. Powders quality have a significant impact on the final attributes of SLM-manufactured items. From a processing standpoint, it is critical to ensure proper powder distribution and compaction in each layer of the powder bed, which is impacted by particle size distribution, packing density, flowability, and sphericity of the powder particles. Layer-by-layer study of the process can provide better understanding of the effect of powder bed on the final part quality. Image-based processing technique could be used to examine the quality of parts fabricated by Selective Laser Melting through layerwise monitoring and to evaluate the results achieved by other techniques. In this paper, a not supervised methodology based on Digital Image Processing through the build-inmachine camera is proposed. Since the limitation of the optical system in terms of resolution, positioning, lighting, field-of-view, many efforts were paid to the calibration and to the data processing. Its capability to individuate possible defects on SLM parts was evaluated by a Computer Tomography results verification

Investigation via morphological analysis of aluminium foams produced by replication casting

Foams and porous materials with cellular structure have many interesting combinations of physical and mechanical properties coupled with low specific weight. By means of replication casting it is possible to manufacture foams from molten metal without direct foaming. A soluble salt is used as space holder, which is removed by leaching in water. This can be done successfully if the content of space holding fillers is so high that all the granules are interconnected. One of the main advantages of using the replication casting is a close control of pore sizes which is given by the distribution of particle sizes of the filler material. This contrasts with the pore size distribution of the materials foamed by other processes where a wider statistical distribution of pores is found. On the other hand, the maximum porosities that can be achieved using space holders are limited to values below 60%, whereas the other methods allow for porosities up to 98%. Temperature of the mould and infiltration pressure are critical process parameters: a typical problem encountered is the premature solidification of the melt, especially due to the high heat capacity of the salt. In this work foam properties such as cell shape, distribution and anisotropy and defect presence are investigated by using digital image processing technique. For this purpose replicated AlSi7Mg0.3 alloy foams are produced by infiltrating preforms of NaCl particles, varying the metal infiltration pressure and the mould preheating temperature. An original procedure based on image analysis has been set up to determine size, morphology and distribution of cells. The paper demonstrates that this methodology, coupled with microstructural analysis, is a useful tool for investigating the effects of process parameters on foam properties

Selective laser melting process of Al–based pyramidal horns for the w-band: fabrication and testing

In the context of exploring the possibility of using Al-powder Selective Laser Meltingto fabricate horn antennas for astronomical applications at millimeter wavelengths,we describe the design, the fabrication, the mechanical characterization, and theelectromagnetic performance of additive manufactured horn antennas for the W-band. Our aim, in particular, is to evaluate the performance impact of two basickinds of surface post-processing (manual grinding and sand-blasting) to deal withthe well-known issue of high surface roughness in 3D printed devices. We performedcomparative tests of co-polar and cross-polar angular response across the whole W-band, assuming a commercially available rectangular horn antenna as a reference.Based on gain and directivity measurements of the manufactured samples, we finddecibel-level detectable deviations from the behavior of the reference horn antenna,and marginal evidence of performance degradation at the top edge of the W-band.We conclude that both kinds of post-processing allow achieving good performancefor the W-band, but the higher reliability and uniformity of the sand-blasting post-process encourage exploring similar techniques for further development of aluminumdevices at these frequencies

How regulating and cultural services of ecosystems have changed over time in Italy

In this experimental study, different components are computed for three different ecosystem services (ES). Specifically, supply, demand and use are estimated for pollination service, flood risk regulation service and nature-based tourism. These are analysed and assessed in 2012 and 2018 for the Italian context, in order to estimate the evolution over this period and to allow a significant comparison of results. The same methodology and models are applied for the selected accounting years and accounting tables and tend to reflect as closely as possible the System of Environmental-Economic Accounting-Ecosystem Accounting (SEEA EA), which is the international standard endorsed by the United Nations to compile Natural Capital Accounting in 2021. Both biophysical and monetary assessments are performed using the ARIES technology, an integrated modelling platform providing automatic and flexible integration of data and models, via its semantic modelling nature. Models have been run adjusting the components of the global modelling approach to the Italian context and, whenever available, prioritising the use of local data to carry out the study. This approach is particularly useful to analyse trends over time, as potentially biased components of models and data are substantially mitigated when the same biases is constant over time. This study finds an increase in benefits over the period analysed for the ES examined. The main contribution of this pioneering work is to support the idea that ES accounting or Natural Capital Accounting can provide a very useful tool to improve economic and environmental information at national and regional level. This can support processes to provide the necessary incentives to steer policy-making towards preventative rather than corrective actions, which are usually much less effective and more costly, both at environmental and economic levels. Nevertheless, particular attention must be paid to the meaning of the estimates and the drivers of these values to derive a direct or indirect relationship between the benefits observable and the actual Italian ecosystems condition. © Capriolo A et al

Women and Informatics: The Ada Web Portal

The gender gap in Informatics education is becoming a crucial issue. Over the last four years, the number of women enrolled in IT-related bachelor programs in Italian universities has dramatically decreased, by around 30%. Today, only 15% of Informatics students are female, while the overall percentage of females enrolled at Italian universities is more than 55%. The aim of the Ada Web Portal we present in this paper is to facilitate communication and to share experiences between women (students, teachers, and professionals) working in the IT area

Donne e Tecnologie Informatiche

Un approfondimento quantitativo e qualitativo del gender gap esistente nelle ICT attraverso dati statistici, analisi del web, rapporti ufficiali, norme e politiche, con particolare attenzione alla realta' del Veneto

Antifibrotic treatment response and prognostic predictors in patients with idiopathic pulmonary fibrosis and exposed to occupational dust

BACKGROUND: Idiopathic Pulmonary Fibrosis (IPF) is an aggressive interstitial lung disease with an unpredictable course. Occupational dust exposure may contribute to IPF onset, but its impact on antifibrotic treatment and disease prognosis is still unknown. We evaluated clinical characteristics, respiratory function and prognostic predictors at diagnosis and at 12 month treatment of pirfenidone or nintedanib in IPF patients according to occupational dust exposure. METHODS: A total of 115 IPF patients were recruited. At diagnosis, we collected demographic, clinical characteristics, occupational history. Pulmonary function tests were performed and two prognostic indices [Gender, Age, Physiology (GAP) and Composite Physiologic Index (CPI)] calculated, both at diagnosis and after the 12 month treatment. The date of long-term oxygen therapy (LTOT) initiation was recorded during the entire follow-up (mean = 37.85, range 12-60 months). RESULTS: At baseline, patients exposed to occupational dust [≥ 10 years (n = 62)] showed a lower percentage of graduates (19.3% vs 54.7%; p = 0.04) and a higher percentage of asbestos exposure (46.8% vs 18.9%; p 0.002) than patients not exposed [< 10 years (n = 53)]. Both at diagnosis and after 12 months of antifibrotics, no significant differences for respiratory function and prognostic predictors were found. The multivariate analysis confirmed that occupational dust exposure did not affect neither FVC and DLCO after 12 month therapy nor the timing of LTOT initiation. CONCLUSION: Occupational dust exposure lasting 10 years or more does not seem to influence the therapeutic effects of antifibrotics and the prognostic predictors in patients with IPF

Tuning a Schottky barrier in a photoexcited topological insulator with transient Dirac cone electron-hole asymmetry

The advent of Dirac materials has made it possible to realize two dimensional gases of relativistic fermions with unprecedented transport properties in condensed matter. Their photoconductive control with ultrafast light pulses is opening new perspectives for the transmission of current and information. Here we show that the interplay of surface and bulk transient carrier dynamics in a photoexcited topological insulator can control an essential parameter for photoconductivity - the balance between excess electrons and holes in the Dirac cone. This can result in a strongly out of equilibrium gas of hot relativistic fermions, characterized by a surprisingly long lifetime of more than 50 ps, and a simultaneous transient shift of chemical potential by as much as 100 meV. The unique properties of this transient Dirac cone make it possible to tune with ultrafast light pulses a relativistic nanoscale Schottky barrier, in a way that is impossible with conventional optoelectronic materials.Comment: Nature Communications, in press (12 pages, 6 figures