1,324 research outputs found

    Interplay of Pi-Pi stacking and hydrogen bonding in conjugated supramolecular systems studied by solid-state NMR

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    Smectic and columnar ordering in length-polydisperse fluids of parallel hard cylinders

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    We apply a recently proposed density functional for mixtures of parallel hard cylinders, based on Rosenfeld's fundamental measure theory, to study the effect of length-polydispersity on the relative stability between the smectic and columnar liquid crystal phases.To this purpose we derive from this functional an expression for the direct correlation function and use it to perform a bifurcation analysis. We compare the results with those obtained with a second and a third virial approximation of this function. All three approximations lead to the same conclusion: there is a terminal polydispersity beyond which the smectic phase is less stable than the columnar phase. This result is in agreement with previous Monte Carlo simulations conducted on a freely rotating length-polydisperse hard spherocylinder fluid, although the theories always overestimate the terminal polydispersity because the nematic-columnar phase transition is first order and exhibits a wide coexistence gap. Both, the fundamental-measure functional and the third virial approximation, predict a metastable nematic-nematic demixing. Conversely, according to second virial approximation this demixing might be stable at high values of the polydispersity, something that is observed neither in simulations nor in experiments. The results of the fundamental-measure functional are quantitatively superior to those obtained from the other two approximations. Thus this functional provides a promising route to map out the full phase diagram of this system.Comment: 7 pages, 2 figure

    Competing electric and magnetic excitations in backward electron scattering from heavy deformed nuclei

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    Important E2E2 contributions to the (e,e)(e,e^{\prime}) cross sections of low-lying orbital M1M1 excitations are found in heavy deformed nuclei, arising from the small energy separation between the two excitations with IπK=2+1I^{\pi}K = 2^+1 and 1+1^+1, respectively. They are studied microscopically in QRPA using DWBA. The accompanying E2E2 response is negligible at small momentum transfer qq but contributes substantially to the cross sections measured at θ=165\theta = 165 ^{\circ} for 0.6<qeff<0.90.6 < q_{\rm eff} < 0.9 fm1^{-1} (40Ei7040 \le E_i \le 70 MeV) and leads to a very good agreement with experiment. The electric response is of longitudinal C2C2 type for θ175\theta \le 175 ^{\circ} but becomes almost purely transverse E2E2 for larger backward angles. The transverse E2E2 response remains comparable with the M1M1 response for qeff>1.2q_{\rm eff} > 1.2 fm1^{-1} (Ei>100E_i > 100 MeV) and even dominant for Ei>200E_i > 200 MeV. This happens even at large backward angles θ>175\theta > 175 ^{\circ}, where the M1M1 dominance is limited to the lower qq region.Comment: RevTeX, 19 pages, 8 figures included Accepted for publication in Phys Rev

    The Role of Social Perspective-Taking in Developing Students\u27 Leadership Capacities

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    This study examined relationships between social perspective-taking (SPT) and the individual, group, and societal domains of socially responsible leadership. SPT is a higher-order cognitive skill linked to moral development and social coordination, but never empirically connected to leadership development. Analyses determined SPT has a strong direct effect on group-level leadership values and an indirect effect on societallevel leadership values. Results offer critical new insights into directionality in the social change model

    Collective Excitations of (154)Sm nucleus at FEL{gamma}+LHC Collider

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    The production of collective excitations of the (154)Sm at FEL{gamma}+LHC collider is investigated. We show that this machine will be a powerful tool for investigation of high energy level excitations.Comment: 6 pages, 1 figure, 4 table

    Large-Scale Transition of Economic Systems Do CEECs Converge Towards Western Prototypes?

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    In order to identify convergence patterns among the group of Central and Eastern European Countries (CEECs) we analyze clusters of traditional OECD countries, i.e. EU-15 plus Norway and Switzerland, Anglo-Saxon non-EU countries plus Japan, and CEECs based on macro data on government regulation and spending instead of micro data on firm relations and market characteristics as is usually applied in Varieties-of-Capitalism (VoC) analysis. This framework is supposed to incorporate some of the critique that has been expressed towards the traditional VoCapproach, especially its ignorance of government spending and performance. We acknowledge for the transition aspect by looking at cluster history and principal component analysis for periods of transition. Our analysis reveals that there is consolidation rather than convergence with CEECs being divided in clusters leaning towards CME and LME prototypes respectively. Overall, there are worlds of redistribution within which clusters differ with respect to their mix of - negatively correlated - regulation and innovation. Interestingly, CEECs do not mix up with Mediterranean MMEs, which indeed provide a kind of worst case setting, while Scandinavian CMEs as well as traditional LMEs provide a kind of role model within their respective worlds of redistribution

    F-spin as a Partial Symmetry

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    We use the empirical evidence that F-spin multiplets exist in nuclei for only selected states as an indication that F-spin can be regarded as a partial symmetry. We show that there is a class of non-F-scalar IBM-2 Hamiltonians with partial F-spin symmetry, which reproduce the known systematics of collective bands in nuclei. These Hamiltonians predict that the scissors states have good F-spin and form F-spin multiplets, which is supported by the existing data.Comment: 14 pages, 1 figur
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