Microcavity effects in the photoluminescence of hydrogenated amorphous silicon nitride

Fabry-Perot microcavities are used for the alteration of photoluminescence in hydrogenated amorphous silicon nitride grown with and without ammonia. The photoluminescence is red-near-infrared for the samples grown without ammonia, and blue-green far the samples grown with ammonia. In the Fabry-Perot microcavities, the amplitude of the photoluminescence is enhanced, while its linewidth is reduced with respect to the bulk hydrogenated amorphous silicon nitride. The microcavity was realized by a metallic back mirror and a hydrogenated amorphous silicon nitride - air or a metallic front mirror. The transmittance, reflectance, and absorbance spectra were also measured and calculated. The calculated spectra agree well with the experimental spectra. The hydrogenated amorphous silicon nitride microcavity has potential for becoming a versatile silicon based optoelectronic device such as a colot flat panel display, a resonant cavity enhanced light emitting diode, or a laser

Fairtrade, place and moral economy: between abstract ethical discourse and the moral experience of Northern Cape farmers

This paper explores the significance of the relationships and disjunctures between the global moral discourses of Fairtrade that are articulated through ethics of fairness in supply chains and the everyday moral experiences, discourses and practices of producers that shape moral economies in specific localities. Due to increased governance through universal codes, standards and certification, Fairtrade risks becoming an abstract ethical and regulatory tool, disconnected from the moral economies of those poor farmers it is intended to benefit. In response, the paper makes a case for a deeper understanding of the moral economies of farmers involved in Fairtrade networks and the ways in which these emerge out of moral experiences that are deeply embedded in local social and cultural relations. Through a case study of Eksteenskuil Agricultural Cooperative in South Africa’s Northern Cape, it seeks to demonstrate the importance of understanding the moral experiences of producers to better consider what is at stake for them, focusing on notions of cooperation, fairness and the ‘good farmer’, perceptions of community, and concerns with survival and self-sufficiency. The paper concludes that working in culturally-sensitive ways with producer communities and understanding how their local moral worlds are structured is vital in bridging the gap between abstract ethical discourses and the place-based moral experiences of producers, and to ensuring the effectiveness of Fairtrade initiatives

Spatial distribution of early red lesions is a risk factor for development of vision-threatening diabetic retinopathy

Aims/hypothesis Diabetic retinopathy is characterised by morphological lesions related to disturbances in retinal blood flow. It has previously been shown that the early development of retinal lesions temporal to the fovea may predict the development of treatment-requiring diabetic maculopathy. The aim of this study was to map accurately the area where lesions could predict progression to vision-threatening retinopathy. Methods The predictive value of the location of the earliest red lesions representing haemorrhages and/or microaneurysms was studied by comparing their occurrence in a group of individuals later developing vision-threatening diabetic retinopathy with that in a group matched with respect to diabetes type, age, sex and age of onset of diabetes mellitus who did not develop vision-threatening diabetic retinopathy during a similar observation period. Results The probability of progression to vision-threatening diabetic retinopathy was higher in a circular area temporal to the fovea, and the occurrence of the first lesions in this area was predictive of the development of vision-threatening diabetic retinopathy. The calculated peak value showed that the risk of progression was 39.5% higher than the average. There was no significant difference in the early distribution of lesions in participants later developing diabetic maculopathy or proliferative diabetic retinopathy. Conclusions/interpretation The location of early red lesions in diabetic retinopathy is predictive of whether or not individuals will later develop vision-threatening diabetic retinopathy. This evidence should be incorporated into risk models used to recommend control intervals in screening programmes for diabetic retinopathy

Visible photoluminescence from planar amorphous silicon nitride microcavities

Fabry-Perot microcavities were used for the enhancement and inhibition of photoluminescence (PL) in a hydrogenated amorphous silicon nitride (a-SiNx:H) microcavity fabricated with and without ammonia. A planar microcavity was realized that included a metallic back mirror and an a-SiNx:H-air or a metallic front mirror. The PL extends from the red part of the spectrum to the near infrared for the samples grown without ammonia. The PL is in the blue-green part of the spectrum for the samples grown with ammonia. The PL amplitude is enhanced and the PL linewidth is reduced with respect to those in bulk a-SiNx:H. The numerically calculated transmittance, reflectance, and absorbance spectra agree well with the experimentally measured spectra. (C) 1998 Optical Society of America [S0740-3224(98)00211-2] OCIS codes: 230.5750, 250.5230, 310.0310

Low temperature photoluminescence spectra of layered semiconductor TlGaS2

Cataloged from PDF version of article.Photoluminescence (PL) spectra of TlGaS2 layered single crystals were studied in the wavelength region 500-860 nm and in the temperature range 9.5-293 K. We observed a total of three PL bands centered at 568 nm (2.183 eV, A-band), 718 nm (1.727 eV, B-band) and 780 nm (1.590 eV, C-band) at various temperatures. We have also studied the variations of the A- and B-band intensities vs excitation laser density in the range from 7 × 10-2 to 9 W cm-2. The A- and B-bands were found to be due to radiative transitions from the deep donor levels located at 0.362 and 0.738 eV below the bottom of the conduction band to the shallow acceptor levels at 0.005 and 0.085 eV located above the top of the valence band, respectively. The proposed energy-level diagram permits us to interpret the recombination processes in TlGaS2 layered single crystals. © 1997 Elsevier Science Ltd

TE INTEGRATION OF WATER HYDRODYNAMICS MODELLING AND REMOTE SENSING DATA TO IMPROVE THE WATER CIRCULATION OF LAKE MANZALA, EGYPT

This paper presents the preliminary results of the application of the ocean model (FVCOM) to replicate the hydrodynamic flows experienced within Lake El-Manzala, Egypt. The construction of this model is used to characterize the ecosystem of this shallow brackish lake and assess a range of sustainable water management strategies. Lake El-Manzala is the largest of the Egyptian shallow coastal lakes on the fringe of the Mediterranean Sea. The lake currently supports 30% of the fresh water fish farm production of Egypt. In recent years the aquatic health of the lake has significantly deteriorated due to an increase in the contamination of the lake by polluted inflows and over intensive aquaculture. The focus of this study is to develop a model that may be employed to investigate the causes, effects and potential solutions to the pollutant loads imposed on the lake. The model has been used to study the hydrodynamic effect that a 40% reduction in the polluted drain water inflows to the lake due to a diversion of this water towards the Sinai for land development. This study concluded that in the western zone of the lake this action slightly changed the magnitude and direction of the water flows and an increase in the salinity levels. Several other lake management scenarios were proposed and the environmental effects on the lake water quality are under investigation. It is concluded that the hydrodynamic models developed may be used to study the cause and effects of other aquatic pollution problems and permit the investigation of potential engineering solutions to improve water quality management