Understanding the interactions of cellulose fibres and deep eutectic solvent of choline chloride and urea

This is the author accepted manuscript. The final version is available from Springer Verlag via the DOI in this record.A deep eutectic solvent composed of choline chloride (ChCl) and urea has been recently introduced as a promising cellulose compatible medium that enables e.g. fibre spinning. This paper clarifies the influence of such a solvent system on the structure and chemical composition of the cellulosic pulp fibres. Special emphasis was placed on the probable alterations of the chemical composition due to the dissolution of the fibre components and/or due to the chemical derivatisation taking place during the DES treatment. Possible changes in fibre morphology were studied with atomic force microscopy and scanning electron microscopy. Chemical compositions of pulp fibres were determined from the carbohydrate content, and by analysing the elemental content. Detailed structural characterisation of the fibres was carried out using spectroscopic methods; namely X-Ray Photoelectron Spectroscopy, solid state Nuclear Magnetic Resonance and Raman Spectroscopy. No changes with respect to fibre morphology were revealed and negligible changes in the carbohydrate composition were noted. The most significant change was related to the nitrogen content of the pulp after the DES treatment. Comprehensive examination using spectroscopic methods revealed that the nitrogen originated from strongly bound ChCl residuals that could not be removed with a mild ethanol washing procedure. According to Raman spectroscopic data and methylene blue adsorption tests, the cationic groups of ChCl seems to be attached to the anionic groups of pulp by electrostatic forces. These findings will facilitate the efficient utilisation of DES as a cellulose compatible medium without significantly affecting the native fibre structure.The authors acknowledge the Finnish Funding Agency for Innovation (TEKES) for funding the work via Design Driven Value Chains in the World of Cellulose 2.0 project. The Academy of Finland (Project ID 300367) is acknowledged for enabling the research mobility of T.T. to the University of Exeter, UK. Unto Tapper (VTT) is thanked for the SEM imaging, Atte Mikkelson, Ritva Heinonen and Marita Ikonen (VTT) for the chemical analysis and Robertus Nugroho (Aalto University) for the AFM imaging

Evidence for non-exponential elastic proton proton differential cross-section at low vertical bar t vertical bar and √ s = 8 TeV by TOTEM

The TOTEM experiment has made a precise measurement of the elastic proton proton differential cross-section at the centre-of-mass energy root s = 8 TeV based on a high-statistics data sample obtained with the beta* = 90 m optics. Both the statistical and systematic uncertainties remain below 1%, except for the t-independent contribution from the overall normalisation. This unprecedented precision allows to exclude a purely exponential differential cross-section in the range of four-momentum transfer squared 0.027 <vertical bar t vertical bar <0.2 GeV2 with a significance greater than 7 sigma. Two extended parametrisations, with quadratic and cubic polynomials in the exponent, are shown to be well compatible with the data. Using them for the differential cross-section extrapolation to t = 0, and further applying the optical theorem, yields total cross-section estimates of (101.5 +/- 2.1) mb and (101.9 +/- 2.1) mb, respectively, in agreement with previous TOTEM measurements. (C) 2015 The Authors. Published by Elsevier B.V.Peer reviewe

Pressure Induced Hydration Dynamics of Membranes

Pressure-jump initiated time-resolved x-ray diffraction studies of dynamics of the hydration of the hexagonal phase in biological membranes show that (i) the relaxation of the unit cell spacing is non-exponential in time; (ii) the Bragg peaks shift smoothly to their final positions without significant broadening or loss in crystalline order. This suggests that the hydration is not diffusion limited but occurs via a rather homogeneous swelling of the whole lattice, described by power law kinetics with an exponent $\beta = 1.3 \pm 0.2$.Comment: REVTEX 3, 10 pages,3 figures(available on request),#

First measurement of elastic, inelastic and total cross-section at √s = 13TeV by TOTEM and overview of cross-section data at LHC energies : TOTEM Collaboration

The TOTEM collaboration has measured the proton- proton total cross section at v s = 13 TeV with a luminosity- independent method. Using dedicated ss * = 90m beam optics, the Roman Pots were inserted very close to the beam. The inelastic scattering rate has been measured by the T1 and T2 telescopes during the same LHC fill. After applying the optical theorem the total proton- proton cross section is stot = (110.6 +/- 3.4) mb, well in agreement with the extrapolation from lower energies. This method also allows one to derive the luminosity- independent elastic and inelastic cross sections: sel = (31.0 +/- 1.7) mband sinel = (79.5 +/- 1.8) mb.Peer reviewe

Diffraction and Total Cross-Section at the Tevatron and the LHC

At the Tevatron, the total p_bar-p cross-section has been measured by CDF at 546 GeV and 1.8 TeV, and by E710/E811 at 1.8 TeV. The two results at 1.8 TeV disagree by 2.6 standard deviations, introducing big uncertainties into extrapolations to higher energies. At the LHC, the TOTEM collaboration is preparing to resolve the ambiguity by measuring the total p-p cross-section with a precision of about 1 %. Like at the Tevatron experiments, the luminosity-independent method based on the Optical Theorem will be used. The Tevatron experiments have also performed a vast range of studies about soft and hard diffractive events, partly with antiproton tagging by Roman Pots, partly with rapidity gap tagging. At the LHC, the combined CMS/TOTEM experiments will carry out their diffractive programme with an unprecedented rapidity coverage and Roman Pot spectrometers on both sides of the interaction point. The physics menu comprises detailed studies of soft diffractive differential cross-sections, diffractive structure functions, rapidity gap survival and exclusive central production by Double Pomeron Exchange.Peer reviewe

New physics, the cosmic ray spectrum knee, and pppp cross section measurements

We explore the possibility that a new physics interaction can provide an explanation for the knee just above $10^6$ GeV in the cosmic ray spectrum. We model the new physics modifications to the total proton-proton cross section with an incoherent term that allows for missing energy above the scale of new physics. We add the constraint that the new physics must also be consistent with published $pp$ cross section measurements, using cosmic ray observations, an order of magnitude and more above the knee. We find that the rise in cross section required at energies above the knee is radical. The increase in cross section suggests that it may be more appropriate to treat the scattering process in the black disc limit at such high energies. In this case there may be no clean separation between the standard model and new physics contributions to the total cross section. We model the missing energy in this limit and find a good fit to the Tibet III cosmic ray flux data. We comment on testing the new physics proposal for the cosmic ray knee at the Large Hadron Collider.Comment: 17 pages, 4 figure

Geographical distribution of salmonella infected pig, cattle and sheep herds in Sweden 1993-2010

<p>Abstract</p> <p>Background</p> <p>The Swedish salmonella control programme covers the entire production chain, from feed to food. All salmonella serotypes are notifiable. On average, less than 20 cases of salmonella in food-producing animals are reported every year. In some situations, the cases would be expected to cluster geographically. The aim of this study was to illustrate the geographic distribution of the salmonella cases detected in pigs, cattle and sheep.</p> <p>Methods</p> <p>Data on all herds with pigs, cattle and sheep found to be infected with salmonella during the time period from 1993 to 2010 were obtained from the Swedish Board of Agriculture. Using the ArcGIS software, various maps were produced of infected herds, stratified on animal species as well as salmonella serotype. Based on ocular inspection of all maps, some were collapsed and some used separately. Data were also examined for temporal trends.</p> <p>Results</p> <p>No geographical clustering was observed for ovine or porcine cases. Cattle herds infected with Salmonella Dublin were mainly located in the southeast region and cattle herds infected with Salmonella Typhimurium in the most southern part of the country. Some seasonal variation was seen in cattle, but available data was not sufficient for further analyses.</p> <p>Conclusions</p> <p>Analyses of data on salmonella infected herds revealed some spatial and temporal patterns for salmonella in cattle. However, despite using 18 years' of data, the number of infected herds was too low for any useful statistical analyses.</p

Search for MSSM Higgs bosons decaying to μ+μ− in proton-proton collisions at s√= 13 TeV

A search is performed for neutral non-standard-model Higgs bosons decaying to two muons in the context of the minimal supersymmetric standard model (MSSM). Proton-proton collision data recorded by the CMS experiment at the CERN Large Hadron Collider at a center-of-mass energy of 13 TeV were used, corresponding to an integrated luminosity of 35.9. The search is sensitive to neutral Higgs bosons produced via the gluon fusion process or in association with a quark pair. No significant deviations from the standard model expectation are observed. Upper limits at 95% confidence level are set in the context of the and phenomenological MSSM scenarios on the parameter as a function of the mass of the pseudoscalar A boson, in the range from 130 to 600 GeV. The results are also used to set a model-independent limit on the product of the branching fraction for the decay into a muon pair and the cross section for the production of a scalar neutral boson, either via gluon fusion, or in association with b quarks, in the mass range from 130 to 1000 GeV.Peer reviewe

Search for anomalous triple gauge couplings in WW and WZ production in lepton + jet events in proton-proton collisions at s√= 13 TeV

A search is presented for three additional operators that would lead to anomalous WWγ or WWZ couplings with respect to those in the standard model. They are constrained by studying events with two vector bosons; a W boson decaying to eν or μν, and a W or Z boson decaying hadronically, reconstructed as a single, massive, large- radius jet. The search uses a data set of proton-proton collisions at a centre-of-mass energy of 13 TeV, recorded by the CMS experiment at the CERN LHC in 2016, and corresponding to an integrated luminosity of 35.9 fb−1. Using the reconstructed diboson invariant mass, 95% confidence intervals are obtained for the anomalous coupling parameters of −1.58 < cWWW/Λ2< 1.59 TeV−2, −2.00 < cW/Λ2< 2.65 TeV−2, and −8.78 < cB/Λ2< 8.54 TeV−2, in agreement with standard model expectations of zero for each parameter. These are the strictest bounds on these parameters to date.Peer reviewe