Nuclear Physics for Cultural Heritage

Nuclear physics applications in medicine and energy are well known and widely reported. Less well known are the many important nuclear and related techniques used for the study, characterization, assessment and preservation of cultural heritage. There has been enormous progress in this field in recent years and the current review aims to provide the public with a popular and accessible account of this work. The Nuclear Physics Division of the EPS represents scientists from all branches of nuclear physics across Europe. One of its aims is the dissemination of knowledge about nuclear physics and its applications. This review is led by Division board member Anna Macková, Head of the Tandetron Laboratory at the Nuclear Physics Institute of the Czech Academy of Sciences, and the review committee includes four other members of the nuclear physics board interested in this area: Faiçal Azaiez, Johan Nyberg, Eli Piasetzky and Douglas MacGregor. To create a truly authoritative account, the Scientific Editors have invited contributions from leading experts across Europe, and this publication is the combined result of their work. The review is extensively illustrated with important discoveries and examples from archaeology, pre-history, history, geography, culture, religion and curation, which underline the breadth and importance of this field. The large number of groups and laboratories working in the study and preservation of cultural heritage across Europe indicate the enormous effort and importance attached by society to this activity

Mobile spectroscopic instrumentation in archaeometry research

Mobile instrumentation is of growing importance to archaeometry research. Equipment is utilized in the field or at museums, thus avoiding transportation or risk of damage to valuable artifacts. Many spectroscopic techniques are nondestructive and micro-destructive in nature, which preserves the cultural heritage objects themselves. This review includes over 160 references pertaining to the use of mobile spectroscopy for archaeometry. Following a discussion of terminology related to mobile instrumental methods, results of a literature survey on their applications for cultural heritage objects is presented. Sections devoted to specific techniques are then provided: Raman spectroscopy, X-ray fluorescence spectrometry, Fourier transform infrared spectroscopy, laser-induced breakdown spectroscopy, and less frequently used techniques. The review closes with a discussion of combined instrumental approaches

Laser-Accelerated proton beams as diagnostics for cultural heritage

This paper introduces the first use of laser-generated proton beams as diagnostic for materials of interest in the domain of Cultural Heritage. Using laser-accelerated protons, as generated by interaction of a high-power short-pulse laser with a solid target, we can produce proton-induced X-ray emission spectroscopies (PIXE). By correctly tuning the proton flux on the sample, we are able to perform the PIXE in a single shot without provoking more damage to the sample than conventional methodologies. We verify this by experimentally irradiating materials of interest in the Cultural Heritage with laser-accelerated protons and measuring the PIXE emission. The morphological and chemical analysis of the sample before and after irradiation are compared in order to assess the damage provoked to the artifact. Montecarlo simulations confirm that the temperature in the sample stays safely below the melting point. Compared to conventional diagnostic methodologies, laser-driven PIXE has the advantage of being potentially quicker and more efficien

Relations between static-structural aspects, construction phases and building materials of San Saturnino Basilica (Cagliari, Italy)

The construction site was used several times: in a first phase, in the republican era of Roman domination it hosted, probably, a temple whose height could reach 25 meters; in a second phase, during the Roman Empire, it was used as a burial area. Then around IV-V century AD a first Christian Basilica made of a naved building with an apse was built there, at the center of a large monastery. Subsequently in a third phase in VI century AD a Byzantine Martyrium, with a Greek cross-shaped plan, was built: the central part of it, supporting a dome is still standing. Finally after 1089 the church was given to Marsilian monks who deeply renovated it and changed its shape converting the plan to a Latin cross. A macroscopic material analysis shows the presence of various rocks, whose use appears to be inhomogeneous during all construction phases. Sedimentary rocks (limestones, sandstones, calcarenites etc belonging to local geological formations) are generally used for masonry structures. Marbles, mostly coming from abroad and previously used in Roman buildings have been adopted for architectural elements (columns, capitals, and so on). At a lower extent there are masonry blocks in Oligo-Miocenic volcanic rocks and seldom stone materials which are not originally from Sardinia. Both mineralogical and petrographic tests (e.g. XRF, XRD) and the most important physical properties (porosity, density, water absorption coefficients, compressive, flexural and tensile strength, etc) show that many of the more representative samples of rock materials (like limestonss, calcarenits) are often highly decayed, with a corresponding reduction of their mechanical strength. A structural analysis is particularly useful for helping in clarifying the historical evolution of the building, checking reconstruction hypotheses and assessing the true residual strength of the more important parts. An example, a FEM analysis of the Byzantine domed part is presented here

Statistical Image Reconstruction for High-Throughput Thermal Neutron Computed Tomography

Neutron Computed Tomography (CT) is an increasingly utilised non-destructive analysis tool in material science, palaeontology, and cultural heritage. With the development of new neutron imaging facilities (such as DINGO, ANSTO, Australia) new opportunities arise to maximise their performance through the implementation of statistically driven image reconstruction methods which have yet to see wide scale application in neutron transmission tomography. This work outlines the implementation of a convex algorithm statistical image reconstruction framework applicable to the geometry of most neutron tomography instruments with the aim of obtaining similar imaging quality to conventional ramp filtered back-projection via the inverse Radon transform, but using a lower number of measured projections to increase object throughput. Through comparison of the output of these two frameworks using a tomographic scan of a known 3 material cylindrical phantom obtain with the DINGO neutron radiography instrument (ANSTO, Australia), this work illustrates the advantages of statistical image reconstruction techniques over conventional filter back-projection. It was found that the statistical image reconstruction framework was capable of obtaining image estimates of similar quality with respect to filtered back-projection using only 12.5% the number of projections, potentially increasing object throughput at neutron imaging facilities such as DINGO eight-fold

Three-dimensional reconstruction of a masonry building through electrical and seismic tomography validated by biological analyses

In this paper, we present an integrated approach, for assessing the condition of an ancient Roman building, affected by rising damp and cracking phenomena. The combination of high-resolution geophysical methods, such as seismic and electrical tomography, with biological information, allowed a more detailed evaluation of the state of conservation of the masonry building. A preliminary three-dimensional electrical survey was conducted to detect the existing building foundations and to determine the variation of the resistivity in the ground. Then, electrical and seismic tomography investigations were carried out on an inner wall of opus caementicium, subjected to rising damp effects and cracks. This approach was adopted to obtain a high-resolution image of the wall, which allowed to identify the inner mortar and the outer brick component from resistivity and velocity contrasts. Furthermore, the geophysical results revealed evidence of wall fractures (indicated by low velocity and high resistivity values) and a significant volume where rising of damp was taking place (resulting in a low resistivity zone). Biological analyses validated the geophysical model: in fact, the biological proliferation occurred up to a height of 0.75 m, where the interface between high and low resistivity values was recovered. This approach can be employed to reconstruct a three-dimensional model of masonry structures in order to plan recovery actions

Characterization of a Pre-Trajan wall by integrated geophysical methods

The purpose of this study was to characterize a pre-Trajan mosaic-decorated wall structure located beneath the Cryptoporticus of the 'Baths of Trajan' complex in Rome. The surveyed wall is 15m long, 0.9m wide and 3 to 5m high. Ground penetrating radar (GPR) and P-wave seismic refraction tomography profiles were used to reconstruct the wall's inner structure, generate a map of the fractures and to evaluate the seismic velocities of the building materials. The wall was surveyed with horizontally and vertically dense GPR profiles and two seismic lines. The seismic lines and GPR profiles were capable of detecting a discontinuity between brick and travertine materials that compose the wall. The combined interpretation of the two non-invasive techniques allowed us to locate weak zones and fractures. This rapid, non-destructive and multi-parametric approach has proved to be effective for characterizing the current status of the wall and the results will be used by archaeologists to evaluate the wall's integrity and to preserve the structure in the future archaeological excavations

Characterization and digital restauration of XIV-XV centuries written parchments by means of non-destructive techniques. Three case studies

Parchment is the primary writing medium of the majority of documents with cultural importance. Unfortunately, this material suffers of several mechanisms of degradation that affect its chemical-physical structure and the readability of text. Due to the unique and delicate character of these objects, the use of nondestructive techniques is mandatory. In this work, three partially degraded handwritten parchments dating back to the XIV-XV centuries were analyzed by means of X-ray fluorescence spectroscopy, µ-ATR Fourier transform infrared spectroscopy, and reflectance and UV-induced fluorescence spectroscopy. 'e elemental and molecular results provided the identification of the inks, pigments, and superficial treatments. In particular, all manuscripts have been written with iron gall inks, while the capital letters have been realized with cinnabar and azurite. Furthermore, multispectral UV fluorescence imaging and multispectral VIS-NIR imaging proved to be a good approach for the digital restoration of manuscripts that suffer from the loss of inked areas or from the presence of brown spotting. Indeed, using ultraviolet radiation and collecting the images at different spectral ranges is possible to enhance the readability of the text, while by illuminating with visible light and by collecting the images at longer wavelengths, the hiding effect of brown spots can be attenuated