Electrodeposition and characterisation of lead-free solder alloys for electronics interconnection

Conventional tin-lead solder alloys have been widely used in electronics interconnection owing to their properties such as low melting temperature, good ductility and excellent wettability on copper and other substrates. However, due to the worldwide legislation addressing the concern over the toxicity of lead, the usage of lead-containing solders has been phased out, thus stimulating substantial efforts on lead-free alternatives, amongst which eutectic Sn-Ag and Sn-Cu, and particularly Sn-Ag-Cu alloys, are promising candidates as recommended by international parties. To meet the increasing demands of advanced electronic products, high levels of integration of electronic devices are being developed and employed, which is leading to a reduction in package size, but with more and more input/output connections. Flip chip technology is therefore seen as a promising technique for chip interconnection compared with wire bonding, enabling higher density, better heat dissipation and a smaller footprint. This thesis is intended to investigate lead-free (eutectic Sn-Ag, Sn-Cu and Sn-Ag-Cu) wafer level solder bumping through electrodeposition for flip chip interconnection, as well as electroplating lead-free solderable finishes on electronic components. The existing knowledge gap in the electrochemical processes as well as the fundamental understanding of the resultant tin-based lead-free alloys electrodeposits are also addressed. For the electrodeposition of the Sn-Cu solder alloys, a methanesulphonate based electrolyte was established, from which near-eutectic Sn-Cu alloys were achieved over a relatively wide process window of current density. The effects of methanesulphonic acid, thiourea and OPPE (iso-octyl phenoxy polyethoxy ethanol) as additives were investigated respectively by cathodic potentiodynamic polarisation curves, which illustrated the resultant electrochemical changes to the electrolyte. Phase identification by X-ray diffraction showed the electrodeposits had a biphasic structure (β-Sn and Cu6Sn5). Microstructures of the Sn-Cu electrodeposits were comprehensively characterised, which revealed a compact and crystalline surface morphology under the effects of additives, with cross-sectional observations showing a uniform distribution of Cu6Sn5 particles predominantly along β-Sn grain boundaries. The electrodeposition of Sn-Ag solder alloys was explored in another pyrophosphate based system, which was further extended to the application for Sn-Ag-Cu solder alloys. Cathodic potentiodynamic polarisation demonstrated the deposition of noble metals, Ag or Ag-Cu, commenced before the deposition potential of tin was reached. The co-deposition of Sn-Ag or Sn-Ag-Cu alloy was achieved with the noble metals electrodepositing at their limiting current densities. The synergetic effects of polyethylene glycol (PEG) 600 and formaldehyde, dependent on reaching the cathodic potential required, helped to achieve a bright surface, which consisted of fine tin grains (~200 nm) and uniformly distributed Ag3Sn particles for Sn-Ag alloys and Ag3Sn and Cu6Sn5 for Sn-Ag-Cu alloys, as characterised by microstructural observations. Near-eutectic Sn-Ag and Sn-Ag-Cu alloys were realised as confirmed by compositional analysis and thermal measurements. Near-eutectic lead-free solder bumps of 25 μm in diameter and 50 μm in pitch, consisting of Sn-Ag, Sn-Cu or Sn-Ag-Cu solder alloys depending on the process and electrolyte employed, were demonstrated on wafers through the electrolytic systems developed. Lead-free solder bumps were further characterised by material analytical techniques to justify the feasibility of the processes developed for lead-free wafer level solder bumping

Semiconductor Packaging

In semiconductor manufacturing, understanding how various materials behave and interact is critical to making a reliable and robust semiconductor package. Semiconductor Packaging: Materials Interaction and Reliability provides a fundamental understanding of the underlying physical properties of the materials used in a semiconductor package. By tying together the disparate elements essential to a semiconductor package, the authors show how all the parts fit and work together to provide durable protection for the integrated circuit chip within as well as a means for the chip to communicate with the outside world. The text also covers packaging materials for MEMS, solar technology, and LEDs and explores future trends in semiconductor packages

High-frequency characterization of embedded components in printed circuit boards

The embedding of electronic components is a three-dimensional packaging technology, where chips are placed inside of the printed circuit board instead of on top. The advantage of this technology is the reduced electronic interconnection length between components. The shorter this connection, the faster the signal transmission can occur. Different high-frequency aspects of chip embedding are investigated within this dissertation: interconnections to the embedded chip, crosstalk between signals on the chip and on the board, and interconnections running on top of or underneath embedded components. The high-frequency behavior of tracks running near embedded components is described using a broadband model for multilayer microstrip transmission lines. The proposed model can be used to predict the characteristic impedance and the loss of the lines. The model is based on two similar approximations that reduce the multilayer substrate to an equivalent single-layer structure. The per-unit-length shunt impedance parameters are derived from the complex effective dielectric constant, which is obtained using a variational method. A complex image approach results in the calculation of a frequency-dependent effective height that can be used to determine the per-unit-length resistance and inductance. A deliberate choice was made for a simple but accurate model that could easily be implemented in current high-frequency circuit simulators. Next to quasi-static electromagnetic simulations, a dedicated test vehicle that allows for the direct extraction of the propagation constant of these multilayer microstrips is manufactured and used to verify the model. The verification of the model using simulation and measurements shows that the proposed model slightly overestimates the loss of the measured multilayer microstrips, but is more accurate than the simulations in predicting the characteristic impedance

Semiconductor Packaging

In semiconductor manufacturing, understanding how various materials behave and interact is critical to making a reliable and robust semiconductor package. Semiconductor Packaging: Materials Interaction and Reliability provides a fundamental understanding of the underlying physical properties of the materials used in a semiconductor package. By tying together the disparate elements essential to a semiconductor package, the authors show how all the parts fit and work together to provide durable protection for the integrated circuit chip within as well as a means for the chip to communicate with the outside world. The text also covers packaging materials for MEMS, solar technology, and LEDs and explores future trends in semiconductor packages

Evaluation of Anisotropic Conductive Films Based on Vertical Fibers for Post-CMOS Wafer-Level Packaging

In this paper, we investigate the mechanical and electrical properties of an anisotropic conductive film (ACF) on the basis of high-density vertical fibers for a wafer-level packaging (WLP) application. As part of the WaferBoard, a\ud reconfigurable circuit platform for rapid system prototyping,\ud ACF is used as an intermediate film providing compliant and\ud vertical electrical connection between chip contacts and a top surface of an active wafer-size large-area IC. The chosen ACF is first tested by an indentation technique. The results show that the elastic–plastic deformation mode as well as the Young’s modulus and the hardness depend on the indentation depth. Second, the efficiency of the electrical contact is tested using a uniaxial compression on a stack comprising a dummy ball grid array (BGA) board, an ACF, and a thin Al film. For three bump diameters, as the compression increases, the resistance values decrease before reaching low and stable values. Despite the BGA solder bumps exhibit plastic deformation after compression, no damage is found on the ACF film. These results show that vertical fiber ACFs can be used for nonpermanent bonding in a WLP application

All-copper chip-to-substrate interconnects for high performance integrated circuit devices

In this work, all-copper connections between silicon microchips and substrates are developed. The semiconductor industry advances the transistor density on a microchip based on the roadmap set by Moore's Law. Communicating with a microprocessor which has nearly one billion transistors is a daunting challenge. Interconnects from the chip to the system (i.e. memory, graphics, drives, power supply) are rapidly growing in number and becoming a serious concern. Specifically, the solder ball connections that are formed between the chip itself and the package are challenging to make and still have acceptable electrical and mechanical performance. These connections are being required to increase in number, increase in power current density, and increase in off-chip operating frequency. Many of the challenges with using solder connections are limiting these areas. In order to advance beyond the limitations of solder for electrical and mechanical performance, a novel approach to creating all-copper connections from the chip-to-substrate has been developed. The development included characterizing the electroless plating and annealing process used to create the connections, designing these connections to be compatible with the stress requirements for fragile low-k devices, and finally by improving the plating/annealing process to become process time competitive with solder. It was found that using a commercially available electroless copper bath for the plating, followed by annealing at 180 C for 1 hour, the shear strength of the copper-copper bond was approximately 165 MPa. This work resulted in many significant conclusions about the mechanism for bonding in the all-copper process and the significance of materials and geometry on the mechanical design for these connections.Ph.D.Committee Chair: Kohl, Paul; Committee Member: Bidstrup Allen, Sue Ann; Committee Member: Fuller, Thomas; Committee Member: Hesketh, Peter; Committee Member: Hess, Dennis; Committee Member: Meindl, Jame

Beam lead technology

Beam lead technology for microcircuit interconnections with applications to metallization, passivation, and bondin

Trends in assembling of advanced IC packages, Journal of Telecommunications and Information Technology, 2005, nr 1

In the paper, an overview of the current trends in the development of advanced IC packages will be presented. It will be shown how switching from peripheral packages (DIP, QFP) to array packages (BGA, CSP) and multichip packages (SiP, MCM) affects the assembly processes of IC and performance of electronic systems. The progress in bonding technologies for semiconductor packages will be presented too. The idea of wire bonding, flip chip and TAB assembly will be shown together with the boundaries imposed by materials and technology. The construction of SiP packages will be explained in more detail. The paper addresses also the latest solutions in MCM packages

Bed of nails(B0N) - 100 microns pitch wafer level off-chip interconnects for microelectronic packaging applications

Master'sMASTER OF ENGINEERIN

End-of-Life and Constant Rate Reliability Modeling for Semiconductor Packages Using Knowledge-Based Test Approaches

End-of-life and constant rate reliability modeling for semiconductor packages are the focuses of this dissertation. Knowledge-based testing approaches are applied and the test-to-failure approach is approved to be a reliable approach. First of all, the end-of-life AF models for solder joint reliability are studied. The research results show using one universal AF model for all packages is flawed approach. An assessment matrix is generated to guide the application of AF models. The AF models chosen should be either assessed based on available data or validated through accelerated stress tests. A common model can be applied if the packages have similar structures and materials. The studies show that different AF models will be required for SnPb solder joints and SAC lead-free solder joints. Second, solder bumps under power cycling conditions are found to follow constant rate reliability models due to variations of the operating conditions. Case studies demonstrate that a constant rate reliability model is appropriate to describe non solder joint related semiconductor package failures as well. Third, the dissertation describes the rate models using Chi-square approach cannot correlate well with the expected failure mechanisms in field applications. The estimation of the upper bound using a Chi-square value from zero failure is flawed. The dissertation emphasizes that the failure data is required for the failure rate estimation. A simple but tighter approach is proposed and provides much tighter bounds in comparison of other approaches available. Last, the reliability of solder bumps in flip chip packages under power cycling conditions is studied. The bump materials and underfill materials will significantly influence the reliability of the solder bumps. A set of comparable bump materials and the underfill materials will dramatically improve the end-of-life solder bumps under power cycling loads, and bump materials are one of the most significant factors. Comparing to the field failure data obtained, the end-of-life model does not predict the failures in the field, which is more close to an approximately constant failure rate. In addition, the studies find an improper underfill material could change the failure location from solder bump cracking to ILD cracking or BGA solder joint failures