Concentrations of VOCs and ozone in indoor environments: A case study in two Mediterranean cities during winter period

Building materials represent the largest surfaces indoors and are the major contributors of volatile organic compounds (VOCs) in the indoor environment. This study which is conducted in the frame of BUMA project (Prioritization of Building Materials Emissions), aims at assessing the human exposure to air hazards emitted by building materials. In this study, indoor and outdoor VOCs and ozone measurements from field campaigns in two Mediterranean cities (Nicosia and Athens in winter period) are presented and discussed. The field campaigns concern weekly measurements. The campaigns were conducted in four buildings in each city (1 Public building, 1 school and 2 houses) and concern weekly measurements. Passive samplers were used for collecting VOCs and ozone. Eight (8) hydrocarbons (benzene, toluene, ethylbenzene, m,p-xylene, a-pinene, o-xylene and d-limonene), five (5) carbonyl compounds (formaldehyde, acetaldehyde, proprionaldehyde, acetone and hexanaldehyde) and ozone have been measured. Additional air exchange measurements have been conducted using tracer gas techniques. Hazardous substances such as benzene, formaldehyde and acetaldehyde present indoor concentrations that range between 1.5-10.2, 5.8-43.2 and 4.5-15 μg/m3, respectively. VOC concentration data show a considerable variability due to the different indoor emission sources, ventilation rates and outdoor environment's influence. A significant contribution to indoor measured concentrations seems to come from the building materials. Ozone outdoor concentrations are reduced substantially inside, indicating relatively strong indoor ozone sinks

The Evaluation of Exposure to Benzene among Children in Indoor Environments: A Review

Benzene has been measured in indoor environments for many decades and has been identified to cause variety of health effects. Children spend most of their time indoors such as daycare centre, preschool and school, they are more likely to be exposed to indoor air pollutants. This paper was aimed to review the exposure to benzene among children within indoor environments from worldwide studies from 2003 to 2018. Based on 24 papers evaluated, 54% were conducted in primary schools. The highest concentration of benzene was found in preschools in China at 148.0 µg/m3. The benzene levels were found higher in indoors than outdoors for most of the studies. Active sampling techniques were used in 42% of studies that enable the determination of acute health effects on children during short-period of exposure time. Differences in sampling techniques and durations make it hard to compare the outcomes of the studies with health-effect guidelines. This review indicated a diversity of sampling approaches and techniques, pointing to the importance of establishment of standard method for collecting and reporting data

Oxidative potential and chemical composition of PM2.5 in office buildings across Europe - The OFFICAIR study

In the frame of the OFFICAIR project, indoor and outdoor PM2.5 samples were collected in office buildings across Europe in two sampling campaigns (summer and winter). The ability of the particles to deplete physiologically relevant antioxidants (ascorbic acid (AA), reduced glutathione (GSH)) in a synthetic respiratory tract lining fluid, i.e., oxidative potential (OP), was assessed. Furthermore, the link between particulate OP and the concentration of the PM constituents was investigated.The mean indoor PM2.5 mass concentration values were substantially lower than the related outdoor values with a mean indoor/outdoor PM2.5 mass concentration ratio of 0.62 and 0.61 for the summer and winter campaigns respectively. The OP of PM2.5 varied markedly across Europe with the highest outdoor OPAA m-3 and OPGSH m-3 (% antioxidant depletion/m3 air) values obtained for Hungary, while PM2.5 collected in Finland exhibited the lowest values. Seasonal variation could be observed for both indoor and outdoor OPAA m-3 and OPGSH m-3 with higher mean values during winter. The indoor/outdoor OPAA m-3 and OPGSH m-3 ratios were less than one with 4 and 17 exceptions out of the 40 cases respectively. These results indicate that indoor air is generally less oxidatively challenging than outdoors. Correlation analysis revealed that trace elements play an important role in determining OP, in particular, the Cu content. Indoor air chemistry might affect OP since weaker correlations were obtained for indoor PM2.5. Our findings also suggest that office workers may be exposed to health relevant PM constituents to a different extent within the same building

Indoor and outdoor air quality: a university cafeteria as a case study

A short but exhaustive air sampling campaign was conducted in a university cafeteria, an occupational environmental not yet studied. Carbonyls and volatile organic compounds were collected by passive diffusion samplers. Temperature, relative humidity, CO2, CO and particulate matter were continuously monitored indoors and outdoors. Simultaneous PM10 sampling with high and low volume instruments, equipped with quartz and Teflon filters, respectively, was performed during working hours and at night. The quartz filters were analysed for their carbonaceous content by a thermo-optical technique and organic constituents by GC-MS. Water-soluble ions and elements were analysed in the Teflon filters by ion chromatography and PIXE, respectively. Low air change rates (0.31–1.5 h−1) and infiltration factors of 0.14, for both PM2.5 and PM10, indicate poor ventilation conditions. Concentrations of both gaseous pollutants and particulate matter were much higher in the cafeteria than outdoors, showing strong variations throughout the day depending on occupancy and activities. The average concentration of indoor-generated PM10 was estimated to be 32 μg m−3. Organic compounds in PM10 included alkanes, PAHs, saccharides, phenolics, alcohols, acids, alkyl esters, triterpenoids, sterols, among others. The complex particle composition reveals the multiplicity of sources, formation reactions and removal processes, not yet fully known, and suggests the contribution from dust resuspension, abrasion and off-gassing of building materials, cooking emissions, tobacco smoke, and several consumer products. Many compounds are in the list of ingredients of personal care products, pesticides, plasticisers, flame retardants and psychoactive drugs. The inhalation cancer risks of metals and PAHs were found to be negligible.publishe

Evaluating the impact of air purifiers and window operation upon indoor air quality - UK nurseries during Covid-19

Many indoor air pollutants have been demonstrated to have a negative impact on occupants and due to physiological and behavioural differences, young children are more vulnerable to these effects than adults. Millions of children in the UK spend large parts of the day in nurseries, where occupant density is high, and indoor air quality can be poor. Therefore, it is imperative to understand the quality of indoor air in nurseries and how to improve it. The aims of the research presented here were to explore the indoor air quality (IAQ) in nurseries and the impact of both the use of air purifiers and window operations on IAQ. Three nurseries in London were selected and monitored via both continuous air quality sensors and passive sampling covering a total of 21 pollutants. Key findings include that mean reduction rate of PM2.5 by using air purifier was 63% with window closed, and 46% with window open. The results also highlight the impacts of operational changes implemented during the Covid-19 pandemic. Windows were operated more frequently for ventilation needs rather than being driven by temperature alone. The increased ventilation in the monitored nurseries in London led to low levels of VOCs and aldehydes (except for formaldehyde and 2-ethylhexanol) but could bring thermal discomfort to occupants. Both temperature and noise levels were shown to be relevant factors impacting the operation of air purifiers. Air purifiers can be effective at reducing PM2.5 when combined with proper window operation and have potential to bring substantial health benefits

What do we know about indoor air quality of nurseries? A review of the literature

Considering the alarming rise in the rate of asthma and respiratory diseases among school children, it is of great importance to investigate all probable causes. Outside of the home, children spend most of their time in school. Many studies have researched the indoor environmental quality of primary and secondary school buildings to determine the exposure of school children to indoor air pollution. However, studies of very young children in nurseries are scarce. Unlike at elementary schools or universities, children in nurseries are more vulnerable due to their physiology, inability to articulate discomfort and to adapt their behaviour to avoid exposures. This article reviews current studies on the indoor environment in nurseries. It summarizes air pollution levels and related environmental and behavioural factors in nurseries that have been reported in the literature. Additionally, exposure to indoor air pollution and related potential health outcomes are examined. This review concludes that indoor air pollution in nurseries often exceeds current guidelines, and designers and policymakers should be made aware of the impact on the health and wellbeing of children in nurseries. Proper interventions and guidelines should be considered to create a healthy indoor environment for nursery children. Practical application : Previous IAQ assessments have mainly focused on indoor temperatures and CO levels. Data on comprehensive monitoring (including PMs, NO , O and other pollutants) of indoor air quality of nurseries are scarce. Particularly in the UK, studies about indoor air quality in nurseries have not been founded. This paper categorized relevant articles according to the focus of the study, to provide evidence to a better understanding of current indoor air quality in nursery environments. 2 2

Indoor air quality and health in schools: a critical review for developing the roadmap for the future school environment

Several research studies have ranked indoor pollution among the top environmental risks to public health in recent years. Good indoor air quality is an essential component of a healthy indoor environment and significantly affects human health and well-being. Poor air quality in such environments may cause respiratory disease for millions of pupils around the globe and, in the current pandemic-dominated era, require ever more urgent actions to tackle the burden of its impacts. The poor indoor quality in such environments could result from poor management, operation, maintenance, and cleaning. Pupils are a different segment of the population from adults in many ways, and they are more exposed to the poor indoor environment: They breathe in more air per unit weight and are more sensitive to heat/cold and moisture. Thus, their vulnerability is higher than adults, and poor conditions may affect proper development. However, a healthy learning environment can reduce the absence rate, improves test scores, and enhances pupil/teacher learning/teaching productivity. In this article, we analyzed recent literature on indoor air quality and health in schools, with the primary focus on ventilation, thermal comfort, productivity, and exposure risk. This study conducts a comprehensive review to summarizes the existing knowledge to highlight the latest research and solutions and proposes a roadmap for the future school environment. In conclusion, we summarize the critical limitations of the existing studies, reveal insights for future research directions, and propose a roadmap for further improvements in school air quality. More parameters and specific data should be obtained from in-site measurements to get a more in-depth understanding at contaminant characteristics. Meanwhile, site-specific strategies for different school locations, such as proximity to transportation routes and industrial areas, should be developed to suit the characteristics of schools in different regions. The socio-economic consequences of health and performance effects on children in classrooms should be considered. There is a great need for more comprehensive studies with larger sample sizes to study on environmental health exposure, student performance, and indoor satisfaction. More complex mitigation measures should be evaluated by considering energy efficiency, IAQ and health effects

Energy upgrade existing kindergarten and landscaping

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