Advanced Liquid Crystal Materials For Display And Photonic Applications

Thin-film-transistor (TFT) liquid crystal display (LCD) has been widely used in smartphones, pads, laptops, computer monitors, and large screen televisions, just to name a few. A great deal of effort has been delved into wide viewing angle, high resolution, low power consumption, and vivid color. However, relatively slow response time and low transmittance remain as technical challenges. To improve response time, several approaches have been developed, such as low viscosity liquid crystals, overdrive and undershoot voltage schemes, thin cell gap with a high birefringence liquid crystal, and elevated temperature operation. The state-of-the-art gray-to-gray response time of a nematic LC device is about 5 ms, which is still not fast enough to suppress the motion picture image blur. On the other hand, the LCD panel\u27s transmittance is determined by the backlight, polarizers, TFT aperture ratio, LC transmittance, and color filters. Recently, a fringe-field-switching mode using a negative dielectric anisotropy (Δε) LC (n-FFS) has been demonstrated, showing high transmittance (98%), single gamma curve, and cell gap insensitivity. It has potential to replace the commonly used p-FFS (FFS using positive Δε LC) for mobile displays. With the urgent need of submillisecond response time for enabling color sequential displays, polymer-stabilized blue phase liquid crystal (PS-BPLC) has become an increasingly important technology trend for information display and photonic applications. BPLCs exhibit several attractive features, such as reasonably wide temperature range, submillisecond gray-to-gray response time, no need for alignment layer, optically isotropic voltage-off state, and large cell gap tolerance. However, some bottlenecks such as high operation voltage, hysteresis, residual birefringence, and slow charging issue due to the large capacitance, remain to be overcome before their widespread applications can be realized. The material system of PS-BPLC, including nematic LC host, chiral dopant, and polymer network, are discussed in detail. Each component plays an essential role affecting the electro-optic properties and the stability of PS-BPLC. In a PS-BPLC system, in order to lower the operation voltage the host LC usually has a very large dielectric anisotropy (Δε \u3e 100), which is one order of magnitude larger than that of a nematic LC. Such a large Δε not only leads to high viscosity but also results in a large capacitance. High viscosity slows down the device fabrication process and increases device response time. On the other hand, large capacitance causes slow charging time to each pixel and limits the frame rate. To reduce viscosity, we discovered that by adding a small amount (~6%) of diluters, the response time of the PS-BPLC is reduced by 2X-3X while keeping the Kerr constant more or less unchanged. Besides, several advanced PS-BPLC materials and devices have been demonstrated. By using a large Δε BPLC, we have successfully reduced the voltage to \u3c10V while maintaining submillisecond response time. Finally we demonstrated an electric fieldindeced monodomain PS-BPLC, which enables video-rate reflective display with vivid colors. The highly selective reflection in polarization makes it promising for photonics application. Besides displays in the visible spectral region, LC materials are also very useful electro-optic media for near infrared and mid-wavelength infrared (MWIR) devices. However, large absorption has impeded the widespread application in the MWIR region. With delicate molecular design strategy, we balanced the absorption and liquid crystal phase stability, and proposed a fluoro-terphenyl compound with low absorption in both MWIR and near IR regions. This compound serves as an important first example for future development of low-loss MWIR liquid crystals, which would further expand the application of LCs for amplitude and/or phase modulation in MWIR region

Microstructure-Stabilized Blue Phase Liquid Crystals

We show that micron-scale two-dimensional (2D) honeycomb microwells can significantly improve the stability of blue phase liquid crystals (BPLCs). Polymeric microwells made by direct laser writing improve various features of the blue phase (BP) including a dramatic extension of stable temperature range and a large increase both in reflectivity and thermal stability of the reflective peak wavelength. These results are mainly attributed to the omni-directional anchoring of the isotropically oriented BP molecules at the polymer walls of the hexagonal microwells and at the top and bottom substrates. This leads to an omni-directional stabilization of the entire BPLC system. This study not only provides a novel insight into the mechanism for the BP formation in the 2D microwell but also points to an improved route to stabilize BP using 2D microwell arrays.Comment: 16 pages, 5 figure

Nematic Liquid Crystal Carbon Nanotube Composite Materials for Designing RF Switching Devices

Radio frequency microelectromechanical systems (RF MEMS) devices are microdevices used to switch or modify signals from the RF to millimeter wave (mmWave) frequency range. Liquid crystals (LCs) are widely used as electro-optic modulators for display devices. An electric field-induced electrical conductivity modulation of pure LC media is quite low which makes it difficult to use for RF MEMS switching applications. Currently, RF MEMS devices are characterized as an excellent option between solid-state and electromechanical RF switches to provide high isolation, low insertion loss, low power usage, excellent return loss, and large frequency band. However, commercial usage is low due to their lower switching speed, reliability, and repeatability. This research presents an electrical conductivity enhancement through the use of carbon nanotube (CNT) doping of LCs to realize a high-performance RF LC-CNT switching device. This thesis presents simulations of an RF switch using a coplanar waveguide (CPW) with a LC-CNT composite called 4-Cyano-4’-pentylbiphenyl multi-walled nanotube (5CB-MWNT) that is suitable for RF applications. The electrical conductivity modulation and RF switch performance of the 5CB-MWNT composite is determined using Finite Element Analysis (FEA). The simulations will present data on the coplanar waveguide’s s-parameters at the input and output ports S11 and S21 to measure return and insertion loss respectively, two key parameters for determining any RF switch’s performance. Furthermore, this thesis presents applications for improving tunable phased antenna arrays using the LC-CNT composite to allow for beam steering with high-gain and directivity to provide a broad 3D scannable coverage of an area. Tunable antennas are an important characteristic for 5G applications to achieve an optimal telecommunication system to prevent overcrowding of antennas and reduce overall system costs. This research investigates various device geometries with 5CB-MWNT to realize the best performing RF device for RF applications and 5G telecommunication systems. This research presents return and insertion loss data for three waveguide device configurations: CPW, coplanar waveguide grounded (CPWG), and finite ground coplanar waveguide grounded (FG-CPWG). The best results are shown using the CPW configuration. The return loss for the LC-CNT device showed a 5 dB improvement from -7.5 dB to -12.5 dB when using the LC-CNT signal line device. The insertion loss for this configuration showed a much more consistent 0 to -0.3 dB insertion loss value with much less noise when using the LC-CNT device compared to the -0.3 to -1 dB insertion loss value with heavy noise when using the Au signal line device. For the other two configurations the return loss and insertion loss value stayed the same indicating there is no loss in performance when using the LC-CNT switching mechanism. This is ideal due to the benefits that the LC-CNT switching mechanism provides like device reliability and increased switching speeds

Old cellulose for new multifunctional networks

Dissertação para obtenção do Grau de Doutor em Ciência e Engenharia de MateriaisCellulose is considered to be the most abundant and renewable natural polymer on earth. It is the main component of plant cells. The exploration of the utility and applications of this material and its derivatives has never stopped since human´s birth. It is well known that cellulose based materials can generate films and fibers, which can be, for instance, produced from cellulosic solutions. The Cellulose rich chemical structure allows different behaviors of the polymer in solution, which is the driving force for diverse films and fibers features. The main goal of this work is the manufacture and characterization of new application of the renewable cellulosic-based materials, which are at the origin of stimuli-responsive and/or functional soft films and fibers. The several materials obtained have in common the main chain cellulose backbone but present different liquid crystalline properties. Firstly rheology coupled to nuclear magnetic resonance techniques (rheo-NMR) were used to characterize a cellulose-water based liquid crystalline solution in order to establish structure/properties relationships, which were the basis to improve the design of films and fibers produced in the framework of this work. The results achieved were at the origin of a paper published in Macromolecules. Then films were produced and due to their structure and enhanced mechanical properties, different applications were realized by producing cellulosic gratings, which mimic the periodic structures that can be found in some petals of plants and a soft cellulose moisture motor was built for the first time. Two manuscripts were published, one related to the grating mimics, in Macromolecular Chemistry and Physics, and the other one dedicated to the mechanical properties and the bending of a cellulosic film controlled by moisture action in Scientific Reports (Nature Publishing Group). Concerning cellulosic fibers, two methods were selected to fabricate micro/nano networks. In order to produce suspended aligned arrays, electrospinning was chosen due to its versatility. On the obtained nano/micro cylinders, nematic and cholesteric droplets were threaded producing necklaces of liquid crystal beads for the first time. The fiber changes not only the topology of the droplet but also distorts its spherical shape to an approximately ellipsoidal droplet. An additional cylindrical surface with planar anchoring along the droplet’s long axis was also added. Designing nematic and cholesteric liquid crystal microdroplets on thin long threads opened new routes to produce fiber waveguides decorated with complex microresonators. Two Soft Matter scientific papers were published based on this work (One was chosen as the cover of that issue). Finally, nano-fibers produced by cellulose acid hydrolises were prepared and a new electro-optical sensor was built up and characterized and the results published in Liquid Crystals journal. Throughout this work Landau-de-Gennes theory was used in order to interpret and understand some of the experimental results achieved.Portuguese Science and Technology Foundation - SFRH/BD/63574/2009, PTDC/CTM/099595/2008, PTDC/CTM-POL/1484/2012, PTDC/CTM/101776/2008, PTDC/FIS/110132/2009, and PEst- C/CTM/LA0025/2011 (Strategic Project - LA 25-2011-2012