The Steady State Fluctuation Relation for the Dissipation Function

We give a proof of transient fluctuation relations for the entropy production (dissipation function) in nonequilibrium systems, which is valid for most time reversible dynamics. We then consider the conditions under which a transient fluctuation relation yields a steady state fluctuation relation for driven nonequilibrium systems whose transients relax, producing a unique nonequilibrium steady state. Although the necessary and sufficient conditions for the production of a unique nonequilibrium steady state are unknown, if such a steady state exists, the generation of the steady state fluctuation relation from the transient relation is shown to be very general. It is essentially a consequence of time reversibility and of a form of decay of correlations in the dissipation, which is needed also for, e.g., the existence of transport coefficients. Because of this generality the resulting steady state fluctuation relation has the same degree of robustness as do equilibrium thermodynamic equalities. The steady state fluctuation relation for the dissipation stands in contrast with the one for the phase space compression factor, whose convergence is problematic, for systems close to equilibrium. We examine some model dynamics that have been considered previously, and show how they are described in the context of this work.Comment: 30 pages, 1 figur

On the Fluctuation Relation for Nose-Hoover Boundary Thermostated Systems

We discuss the transient and steady state fluctuation relation for a mechanical system in contact with two deterministic thermostats at different temperatures. The system is a modified Lorentz gas in which the fixed scatterers exchange energy with the gas of particles, and the thermostats are modelled by two Nos\'e-Hoover thermostats applied at the boundaries of the system. The transient fluctuation relation, which holds only for a precise choice of the initial ensemble, is verified at all times, as expected. Times longer than the mesoscopic scale, needed for local equilibrium to be settled, are required if a different initial ensemble is considered. This shows how the transient fluctuation relation asymptotically leads to the steady state relation when, as explicitly checked in our systems, the condition found in [D.J. Searles, {\em et al.}, J. Stat. Phys. 128, 1337 (2007)], for the validity of the steady state fluctuation relation, is verified. For the steady state fluctuations of the phase space contraction rate \zL and of the dissipation function \zW, a similar relaxation regime at shorter averaging times is found. The quantity \zW satisfies with good accuracy the fluctuation relation for times larger than the mesoscopic time scale; the quantity \zL appears to begin a monotonic convergence after such times. This is consistent with the fact that \zW and \zL differ by a total time derivative, and that the tails of the probability distribution function of \zL are Gaussian.Comment: Major revision. Fig.10 was added. Version to appear in Journal of Statistical Physic

Dissipative Dicke Model with Collective Atomic Decay: Bistability, Noise-Driven Activation and Non-Thermal First Order Superradiance Transition

The Dicke model describes the coherent interaction of a laser-driven ensemble of two level atoms with a quantized light field. It is realized within cavity QED experiments, which in addition to the coherent Dicke dynamics feature dissipation due to e.g. atomic spontaneous emission and cavity photon loss. Spontaneous emission supports the uncorrelated decay of individual atomic excitations as well as the enhanced, collective decay of an excitation that is shared by $N$ atoms and whose strength is determined by the cavity geometry. We derive a many-body master equation for the dissipative Dicke model including both spontaneous emission channels and analyze its dynamics on the basis of Heisenberg-Langevin and stochastic Bloch equations. We find that the collective loss channel leads to a region of bistability between the empty and the superradiant state. Transitions between these states are driven by non-thermal, markovian noise. The interplay between dissipative and coherent elements leads to a genuine non-equilibrium dynamics in the bistable regime, which is expressed via a non-conservative force and a multiplicative noise kernel appearing in the stochastic Bloch equations. We present a semiclassical approach, based on stochastic nonlinear optical Bloch equations, which for the infinite-range Dicke Model become exact in the large-$N$-limit. The absence of an effective free energy functional, however, necessitates to include fluctuation corrections with $\mathcal{O}(1/N)$ for finite $N<\infty$ to locate the non-thermal first-order phase transition between the superradiant and the empty cavity.Comment: as published in Physical Review

Fluctuations and response in a non-equilibrium micron-sized system

The linear response of non-equilibrium systems with Markovian dynamics satisfies a generalized fluctuation-dissipation relation derived from time symmetry and antisymmetry properties of the fluctuations. The relation involves the sum of two correlation functions of the observable of interest: one with the entropy excess and the second with the excess of dynamical activity with respect to the unperturbed process, without recourse to anything but the dynamics of the system. We illustrate this approach in the experimental determination of the linear response of the potential energy of a Brownian particle in a toroidal optical trap. The overdamped particle motion is effectively confined to a circle, undergoing a periodic potential and driven out of equilibrium by a non-conservative force. Independent direct and indirect measurements of the linear response around a non-equilibrium steady state are performed in this simple experimental system. The same ideas are applicable to the measurement of the response of more general non-equilibrium micron-sized systems immersed in Newtonian fluids either in stationary or non-stationary states and possibly including inertial degrees of freedom.Comment: 12 pages, submitted to J. Stat. Mech., revised versio