Carnot Cycle and Heat Engine Fundamentals and Applications II

This second Special Issue connects both the fundamental and application aspects of thermomechanical machines and processes. Among them, engines have the largest place (Diesel, Lenoir, Brayton, Stirling), even if their environmental aspects are questionable for the future. Mechanical and chemical processes as well as quantum processes that could be important in the near future are considered from a thermodynamical point of view as well as for applications and their relevance to quantum thermodynamics. New insights are reported regarding more classical approaches: Finite Time Thermodynamics F.T.T.; Finite Speed thermodynamics F.S.T.; Finite Dimensions Optimal Thermodynamics F.D.O.T. The evolution of the research resulting from this second Special Issue ranges from basic cycles to complex systems and the development of various new branches of thermodynamics

ECOS 2012

The 8-volume set contains the Proceedings of the 25th ECOS 2012 International Conference, Perugia, Italy, June 26th to June 29th, 2012. ECOS is an acronym for Efficiency, Cost, Optimization and Simulation (of energy conversion systems and processes), summarizing the topics covered in ECOS: Thermodynamics, Heat and Mass Transfer, Exergy and Second Law Analysis, Process Integration and Heat Exchanger Networks, Fluid Dynamics and Power Plant Components, Fuel Cells, Simulation of Energy Conversion Systems, Renewable Energies, Thermo-Economic Analysis and Optimisation, Combustion, Chemical Reactors, Carbon Capture and Sequestration, Building/Urban/Complex Energy Systems, Water Desalination and Use of Water Resources, Energy Systems- Environmental and Sustainability Issues, System Operation/ Control/Diagnosis and Prognosis, Industrial Ecology

ECOS 2010 Volume III (Cycles & Buildings)

ECOS2010 - 23rd International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, June 14-17 2010, Lausanne, Switzerland Ecoefficiency and renewable energy for a sustainable world + Developments, application and teaching of methods in: - Basic and applied thermodynamics - Thermoeconomics and environomics - Simulation, improvement and optimization of energy conversion systems - Process design, analysis and integration of thermal and chemical systems - Diagnostic and control of thermal systems - Environmental impact and sustainability of energy systems + Relevant physical systems - Conventional and advanced power plants - Polygeneration and District heating/cooling systems - New technologies in heat pumps, refrigeration and air conditioning - New technologies for electricity (co)generation - Industrial process plants - Energy storage - Carbon Capture and Storage - Hydrogen and natural gas technologies - Biomass conversion systems - Energy conversion systems for transportation - Water Desalination and Treatment + Focus points - Technology, environmental and economical aspects of biofuels and other renewable energies (biomass, geothermal, thermal solar) - Fuel cells systems - Heat pumps and Organic Rankine Cycle

Book of abstracts of the 10th International Chemical and Biological Engineering Conference: CHEMPOR 2008

This book contains the extended abstracts presented at the 10th International Chemical and Biological Engineering Conference - CHEMPOR 2008, held in Braga, Portugal, over 3 days, from the 4th to the 6th of September, 2008. Previous editions took place in Lisboa (1975, 1889, 1998), Braga (1978), Póvoa de Varzim (1981), Coimbra (1985, 2005), Porto (1993), and Aveiro (2001). The conference was jointly organized by the University of Minho, “Ordem dos Engenheiros”, and the IBB - Institute for Biotechnology and Bioengineering with the usual support of the “Sociedade Portuguesa de Química” and, by the first time, of the “Sociedade Portuguesa de Biotecnologia”. Thirty years elapsed since CHEMPOR was held at the University of Minho, organized by T.R. Bott, D. Allen, A. Bridgwater, J.J.B. Romero, L.J.S. Soares and J.D.R.S. Pinheiro. We are fortunate to have Profs. Bott, Soares and Pinheiro in the Honor Committee of this 10th edition, under the high Patronage of his Excellency the President of the Portuguese Republic, Prof. Aníbal Cavaco Silva. The opening ceremony will confer Prof. Bott with a “Long Term Achievement” award acknowledging the important contribution Prof. Bott brought along more than 30 years to the development of the Chemical Engineering science, to the launch of CHEMPOR series and specially to the University of Minho. Prof. Bott’s inaugural lecture will address the importance of effective energy management in processing operations, particularly in the effectiveness of heat recovery and the associated reduction in greenhouse gas emission from combustion processes. The CHEMPOR series traditionally brings together both young and established researchers and end users to discuss recent developments in different areas of Chemical Engineering. The scope of this edition is broadening out by including the Biological Engineering research. One of the major core areas of the conference program is life quality, due to the importance that Chemical and Biological Engineering plays in this area. “Integration of Life Sciences & Engineering” and “Sustainable Process-Product Development through Green Chemistry” are two of the leading themes with papers addressing such important issues. This is complemented with additional leading themes including “Advancing the Chemical and Biological Engineering Fundamentals”, “Multi-Scale and/or Multi-Disciplinary Approach to Process-Product Innovation”, “Systematic Methods and Tools for Managing the Complexity”, and “Educating Chemical and Biological Engineers for Coming Challenges” which define the extended abstracts arrangements along this book. A total of 516 extended abstracts are included in the book, consisting of 7 invited lecturers, 15 keynote, 105 short oral presentations given in 5 parallel sessions, along with 6 slots for viewing 389 poster presentations. Full papers are jointly included in the companion Proceedings in CD-ROM. All papers have been reviewed and we are grateful to the members of scientific and organizing committees for their evaluations. It was an intensive task since 610 submitted abstracts from 45 countries were received. It has been an honor for us to contribute to setting up CHEMPOR 2008 during almost two years. We wish to thank the authors who have contributed to yield a high scientific standard to the program. We are thankful to the sponsors who have contributed decisively to this event. We also extend our gratefulness to all those who, through their dedicated efforts, have assisted us in this task. On behalf of the Scientific and Organizing Committees we wish you that together with an interesting reading, the scientific program and the social moments organized will be memorable for all.Fundação para a Ciência e a Tecnologia (FCT

Proceedings of the 10th International Chemical and Biological Engineering Conference - CHEMPOR 2008

This volume contains full papers presented at the 10th International Chemical and Biological Engineering Conference - CHEMPOR 2008, held in Braga, Portugal, between September 4th and 6th, 2008.FC

Rock bed thermal storage for concentrating solar power plants

Thesis (PhD)--Stellenbosch University, 2014.ENGLISH ABSTRACT: Concentrating solar power plants are a promising means of generating electricity. However, they are dependent on the sun as a source of energy, and require thermal storage to supply power on demand. At present thermal storage – usually molten salt – although functional, is expensive, and a cheaper solution is desired. It is proposed that sensible heat storage in a packed bed of rock, with air as heat transfer medium, is suitable at temperatures of 500 – 600 °C. To determine if this concept is technically feasible and economically competitive with existing storage, rock properties, packed bed pressure drop and thermal characteristics must be understood. This work addresses these topics. No previously published data is available on thermal cycling resistance of South African rock, and there is limited data from other countries in the proposed temperature range for long-term thermal cycling, so samples were thermally cycled. There is rock which is suitable for thermal storage applications at temperatures of 500 – 600 °C. New maps of South Africa showing where potentially suitable rock is available were produced. Dolerite, found extensively in the Karoo, is particularly suitable. Friction factors were measured for beds of different particles to determine the importance of roughness, shape, and packing arrangement. Five sets of rock were also tested, giving a combined dataset broader than published in any previous study. Limitations of existing correlations are shown. The friction factor is highly dependent on particle shape and, in the case of asymmetric particles, packing method. The friction factor varied by up to 70 % for crushed rock depending on the direction in which it was poured into the test section, probably caused by the orientation of the asymmetric rock relative to the air flow direction. This has not been reported before for rock beds. New isothermal correlations using the volume equivalent particle diameter are given: they are within 15 % of the measurements. This work will allow a techno-economic evaluation of crushed rock beds using more accurate predictions of pumping power than could previously be made. Thermal tests below 80 °C show that bed heat transfer is insensitive to particle shape or type. A heat transfer correlation for air in terms of the volume equivalent diameter was formulated and combined with the E-NTU method. The predicted bed outlet temperatures are within 5 °C of the measurements for tests at 530 °C, showing that the influence of thermal conduction and radiation can be reasonably negligible for a single charge/discharge cycle at mass fluxes around 0.2 kg/m2s. A novel method for finding the optimum particle size and bed length is given: The Biot number is fixed, and the net income (income less bed cost) from a steam cycle supplied by heat from the bed is calculated. A simplified calculation using the method shows that the optimum particle size is approximately 20 mm for bed lengths of 6 – 7 m. Depending on the containment design and cost, the capital cost could be an order of magnitude lower than a nitrate salt system.AFRIKAANSE OPSOMMING: Gekonsentreerde son-energie kragstasies is n belowende manier om elektrisiteit op te wek, maar hulle is afhanklik van die son as n bron van energie. Om drywing op aanvraag te voorsien moet hulle energie stoor. Tans is termiese stoor – gewoonlik gesmelte sout – hoewel funksioneel, duur, en n goedkoper oplossing word gesoek. Daar word voorgestel dat stoor van voelbare warmte-energie in n gepakte rotsbed met lug as warmteoordrag medium geskik is by temperature van 500 – 600 °C. Om te bepaal of dié konsep tegnies gangbaar en ekonomies mededingend met bestaande stoorstelsels is, moet rotseienskappe, gepakte bed drukval en hitteoordrag verstaan word. Hierdie werk spreek hierdie aspekte aan. Geen voorheen gepubliseerde data is beskikbaar oor die termiese siklus weerstand van Suid-Afrikaanse rots nie, en daar is beperkte data van ander lande in die voorgestelde temperatuurbereik, dus is monsters onderwerp aan termiese siklusse. Daar bestaan rots wat geskik is vir termiese stoor toepassings by temperature van 500 – 600 °C. Nuwe kaarte van Suid-Afrika is opgestel om te wys waar potensieel geskikte rots beskikbaar is. Doleriet, wat wyd in die Karoo voor kom, blyk om veral geskik te wees. Wrywingsfaktore is gemeet vir beddens van verskillende partikels om die belangrikheid van grofheid, vorm en pak-rangskikking te bepaal. Vyf rotsstelle is ook getoets, wat n saamgestelde datastel gee wyer as in enige gepubliseerde studie. Beperkings van bestaande korrelasies word aangetoon. Die wrywingsfaktor is hoogs sensitief vir partikelvorm en, in die geval van asimmetriese partikels, pakkings metode. Die wrywingsfaktor het met tot 70 % gevarieer vir gebreekte rots, afhanklik van die rigting waarin dit in die toetsseksie neergelê is. Dit is waarskynlik veroorsaak deur die oriëntasie van die asimmetriese rots relatief tot die lugvloei rigting, en is nie voorheen vir rotsbeddens gerapporteer nie. Nuwe isotermiese korrelasies wat gebruik maak van die volume-ekwivalente partikel deursnee word gegee: hulle voorspel binne 15 % van die gemete waardes. Hierdie werk sal n tegno-ekonomiese studie van rotsbeddens toelaat wat meer akkurate voorspellings van pompdrywing gebruik as voorheen moontlik was. Termiese toetse onder 80 °C wys dat die warmteoordrag nie baie sensitief is vir partikelvorm en -tipe nie. n Warmte-oordragskorrelasie vir lug in terme van die volume-ekwivalente deursnee is ontwikkel en met die E-NTU-metode gekombineer. Die voorspelde lug uitlaat temperatuur is binne 5 °C van die meting vir toetse by 530 °C. Dit wys dat termiese geleiding en straling redelikerwys buite rekening gelaat kan word vir n enkele laai/ontlaai siklus by massa vloeitempos van omtrent 0.2 kg/m2s. n Oorspronklike metode vir die bepaling van die optimum partikelgrootte en bedlengte word gegee: Die Biot-getal is vas, en die netto inkomste (die inkomste minus die bed omkoste) van n stoomsiklus voorsien met warmte van die bed word bereken. n Vereenvoudigde berekening wat die metode gebruik wys dat die optimum grootte en lengte ongeveer 20 mm en 6-7 m is. Afhangende van die behoueringsontwerp en koste, kan die kapitale koste n orde kleiner wees as dié van n gesmelte nitraatsout stelse

Ultra-high temperature concentrated solar thermal energy

Given the extremely high surface temperature of the Sun (~5778 K), solar radiation has the theoretical potential, in accordance with the second law of thermodynamics, to heat a receiver on Earth up to ultra-high temperatures (specified in this thesis as >1300 K). However, there is a gap between theory and practice, as contemporary solar thermal energy systems are still limited to temperatures below 900 K due to material and mechanical limitations. Running solar thermal energy at ultra-high temperatures promises greater energy conversion efficiencies for power plants by upgrading their basic cycles to include more advanced power cycles. Furthermore, the provision of solar thermal energy at ultra-high temperatures can unlock a wide range of energy-intensive industrial applications, including hydrogen and cement production, which can contribute to decarbonising sectors which are difficult to electrify. This thesis proposes a novel concept of an ultra-high temperature solar cavity receiver based on an optically exposed liquid metal heat transfer fluid, which flows down a corrugated back plate. The concept is investigated using a quasi-steady-state analytical energy model, in addition to a radiation-coupled Computational Fluid Dynamics (CFD) solution. The developed analysis methods are tailored to the proposed class of receivers, nonetheless, they can be generalised for broad solar receiver analysis or for analysing similar problems involving volumetric radiation absorption in other thermal applications. The concept is shown implementable at its absorptive cavity configuration with an overall (optical and thermal) receiver efficiency exceeding 70%. The proposed concept is a step towards narrowing the technological mismatch, in terms of temperature and scale, between state-of-the-art thermal energy storage and concentrated solar thermal at ultra-high temperatures. A characterisation of prospective ultra-high temperature receivers is presented, which involved a review of state-of-the-art solar thermal technologies with the purpose of identifying the existing challenges to operating at ultra-high temperatures. Based on this characterisation, the proposed receiver is designed to address the literature concerns. The proposed receiver concept involved novel engineering features, including the use of refractory containment materials and a transparent ceramic window to seal the aperture. Therefore, the conceptual investigation attempted to address possible concerns that might be introduced by the new features. Finally, the proposed receiver is demonstrated in a concentrated solar power plant application to emphasise, using quantitative terms, the benefits of operating the receiver at ultra-high temperatures for large-scale applications

Thermoeconomic Optimization of an Irreversible Novikov Plant Model under Different Regimes of Performance

The so-called Novikov power plant model has been widely used to represent some actual power plants, such as nuclear electric power generators. In the present work, a thermo-economic study of a Novikov power plant model is presented under three different regimes of performance: maximum power (MP), maximum ecological function (ME) and maximum efficient power (EP). In this study, different heat transfer laws are used: The Newton’s law of cooling, the Stefan–Boltzmann radiation law, the Dulong–Petit’s law and another phenomenological heat transfer law. For the thermoeconomic optimization of power plant models, a benefit function defined as the quotient of an objective function and the total economical costs is commonly employed. Usually, the total costs take into account two contributions: a cost related to the investment and another stemming from the fuel consumption. In this work, a new cost associated to the maintenance of the power plant is also considered. With these new total costs, it is shown that under the maximum ecological function regime the plant improves its economic and energetic performance in comparison with the other two regimes. The methodology used in this paper is within the context of finite-time thermodynamics