Study of intermetallic compound layer formation, growth and evaluation of shear strength of lead-free solder joints

Solder joints play a very important role in electronic products as the integrity of electronics packaging and assembly rests on the quality of these connections. The increasing demands for higher performance, lower cost, and miniaturisation in hand-held and consumer electronic products have led to the use of dense interconnections. This miniaturization trend means that solder joint reliability remains an important challenge with surface mount electronics assembly, especially those used in hostile environments, and applications such as automobile, aerospace and other safety critical operations. One of the most important factors which are known to affect solder joint reliability is the thickness of intermetallic compound (IMC) layer formed between the solder and the substrate. Although the formation of an IMC layer signifies good bonding between the solder and substrate, its main disadvantage is that it is also known to be the most brittle part of the solder joint. Thus as the miniaturisation trend continues, and solder joints become even smaller in size, the nature and impact of IMC layer thickness on solder joint reliability becomes even more of a concern with the introduction of new lead-free soldering. Other factors which are known to affect solder joint reliability include the bonding strength, the voiding percentage in joints, the size of the voids and their location within the joint. The work reported in this thesis on formation and growth of intermetallic compound layer, and evaluation of the shear strength of lead-free solder joints is divided into four main parts. The first part of the study is concerned with understanding of the effect of pad sizes on Inter-metallic compound layer formation and growth for lead-free solder joints. The second part concerns the study of the effect of temperature cycling and reflow profiles on intermetallic growth between Sn-Ag-Cu alloy and Cu substrate. The third part of the study concerns the investigation of the effect of reflow soldering profile optimization on solder volumes using design of experiment technique. The focus of the final part of the study is the investigation of the effect of Inter-metallic Compound thickness on shear strength of 1206 surface mount chip resistor. The results from the experimental work showed that the pad size has very little influence on the growth of the IMC. The result also shows that the growth of IMC depends on diffusion rate, temperature and time according to the power-law model; and that the IMC layer thickness is independent of pad size. The significance of this result is that with further reductions in joint size (with IMC layer thickness remaining the same), the ratio of the IMC layer thickness to solder joint size will increase and adversely impact the joint reliability. The work carried out on ageing temperatures and reflow profiles of Sn-Ag-Cu alloy and Cu substrate also showed the reaction-diffusion mechanism of intermetallic compound formation and growth in solder joints. The study also showed that the most significant factor in achieving lower IMC layer thickness and fine microstructures is the time to peak temperature of the reflow soldering process. The effect of IMC layer thickness on the shear strength of Sn-Ag-Cu solder joints was investigated. The relationship of shear strength, interfacial microstructures and fracture surfaces was considered. It is clear that formation of continuous Cu-Sn and SnNiCu layers are the reason for the weak interface strength. The results show that the shear strength of solder joints decreases with increasing ageing time. The results of this study have been disseminated through journal and conference publications and will be of interest to R&D personnel working in the area of high temperature electronics and in particular those working in the field of automotive electronics

Properties and behaviour of Pb-free solders in flip-chip scale solder interconnections

Due to pending legislations and market pressure, lead-free solders will replace Sn–Pb solders in 2006. Among the lead-free solders being studied, eutectic Sn–Ag, Sn–Cu and Sn–Ag–Cu are promising candidates and Sn–3.8Ag–0.7Cu could be the most appropriate replacement due to its overall balance of properties. In order to garner more understanding of lead-free solders and their application in flip-chip scale packages, the properties of lead free solders, including the wettability, intermetallic compound (IMC) growth and distribution, mechanical properties, reliability and corrosion resistance, were studied and are presented in this thesis. [Continues.

NANO-PARTICLE REINFORCED SOLDERS FOR MICROELECTRONIC INTERCONNECT APPLICATIONS

Ph.DDOCTOR OF PHILOSOPH

The durability of solder joints under thermo-mechanical loading; application to Sn-37Pb and Sn-3.8Ag-0.7Cu lead-free replacement alloy

Solder joints in electronic packages provide mechanical, electrical and thermal connections. Hence, their reliability is also a major concern to the electronic packaging industry. Ball Grid Arrays (BGAs) are a very common type of surface mount technology for electronic packaging. This work primarily addresses the thermo-mechanical durability of BGAs and is applied to the exemplar alloys; traditional leaded solder and a popular lead-free solder. Isothermal mechanical fatigue tests were carried out on 4-ball test specimens of the lead-free (Sn-3.8Ag-0.7Cu) and leaded (Sn-37Pb) solder under load control at room temperature, 35°C and 75°C. As well as this, a set of combined thermal and mechanical cycling tests were carried out, again under load control with the thermal cycles either at a different frequency from the mechanical cycles (not-in-phase) or at the same frequency (both in phase and out-of-phase). The microstructural evaluation of both alloys was investigated by carrying out a series of simulated ageing tests, coupled with detailed metallurgical analysis and hardness testing. The results were treated to produce stress-life, cyclic behaviour and creep curves for each of the test conditions. Careful calibration allowed the effects of substrate and grips to be accounted for and so a set of strain-life curves to be produced. These results were compared with other results from the literature taking into account the observations on microstructure made in the ageing tests. It is generally concluded that the TMF performance is better for the Sn-Ag-Cu alloy than for the Sn-Pb alloy, when expressed as stress-life curves. There is also a significant effect on temperature and phase for each of the alloys, the Sn-Ag-Cu being less susceptible to these effects. When expressed as strain life, the effects of temperature, phase and alloy type are much diminished. Many of these conclusions coincided with only parts of the literature and reasons for the remaining differences are advanced

An Investigation of Reliability of High Density Electronic Package-to-Board Interconnections from the Perspective of Solder Joint Metallurgy

The integration and miniaturization trend of the electronic packaging leads to much finer pitch of the device and package lead terminations. Several reliability concerns and issues that were previously not encountered are now surfacing. The objective of this thesis work is to investigate the reliability of the package-to-board interconnection from the perspective of solder joint metallurgy. It was carried out with several advanced packages such as CSP, WLCSP and leadless ceramic packages on organic laminate PWBs using tin-silver-copper based interconnection materials. The assemblies were subjected to several loading conditions and levels such as thermal, mechanical, and environmental stresses. As expected, the board level reliability (BLR) of electronic assemblies strongly depended on microstructure and morphology of the solder joints. Dispersion strengthening effect of the intermetallic compounds (IMCs), coarsening of the IMC particles, strain rate hardening, solder fatigue, and recrystallization of Sn grains in the highly stressed areas were observed. These were found to directly impact Pb-free solder joint reliability. Appropriate thermal aging can improve joint reliability up to 50% due to coarsening of the IMC particles. In addition, other factors such as dissolution of metals, interfacial reactions, IMC spalling, and cross interaction of surface materials on the two sides of the joints were also observed and discussed. The effects can be expressed as a series of interactive relationships: materials (pad surface materials and solder alloy composition) and/or soldering process lead to microstructure change in bulk solder and/or at interface, which in turn leads to joint reliability variation

MICROSTRUCTURAL CHARACTERIZATION AND THERMAL CYCLING RELIABILITY OF SOLDERS UNDER ISOTHERMAL AGING AND ELECTRICAL CURRENT

Solder joints on printed circuit boards provide electrical and mechanical connections between electronic devices and metallized patterns on boards. These solder joints are often the cause of failure in electronic packages. Solders age under storage and operational life conditions, which can include temperature, mechanical loads, and electrical current. Aging occurring at a constant temperature is called isothermal aging. Isothermal aging leads to coarsening of the bulk microstructure and increased interfacial intermetallic compounds at the solder-pad interface. The coarsening of the solder bulk degrades the creep properties of solders, whereas the voiding and brittleness of interfacial intermetallic compounds leads to mechanical weakness of the solder joint. Industry guidelines on solder interconnect reliability test methods recommend preconditioning the solder assemblies by isothermal aging before conducting reliability tests. The guidelines assume that isothermal aging simulates a "reasonable use period," but do not relate the isothermal aging levels with specific use conditions. Studies on the effect of isothermal aging on the thermal cycling reliability of tin-lead and tin-silver-copper solders are limited in scope, and results have been contradictory. The effect of electrical current on solder joints has been has mostly focused on current densities above 104A/cm2 with high ambient temperature (≥100oC), where electromigration, thermomigration, and Joule heating are the dominant failure mechanisms. The effect of current density below 104A/cm2 on temperature cycling fatigue of solders has not been established. This research provides the relation between isothermal aging and the thermal cycling reliability of select Sn-based solders. The Sn-based solders with 3%, 1%, and 0% silver content that have replaced tin-lead are studied and compared against tin-lead solder. The activation energy and growth exponents of the Arrhenius model for the intermetallic growth in the solders are provided. An aging metric to quantify the aging of solder joints, in terms of phase size in the solder bulk and interfacial intermetallic compound thickness at the solder-pad interface, is established. Based on the findings of thermal cycling tests on aged solder assemblies, recommendations are made for isothermal aging of solders before thermal cycling tests. Additionally, the effect of active electrical current at 103 A/cm2 on thermal cycling reliability is reported

An investigation into nano-particulates reinforced SAC305-based composite solders under electro- and thermo-migration conditions

With the rapid development in electronic packaging due to product miniaturisation, the size of solder joints is decreasing considerably, thus the failure of solder interconnects induced by electro-migration (EM) and thermo-migration (TM) became a reliability concern. The incorporation of foreign reinforcement can effectively improve properties of the solder alloys. However, this presents an imperative need for a further investigation to elaborate the underlying fundamentals associated with the reliability of reinforced solders. In this study, the Sn-Ag-Cu (SAC) based solder alloy powders as matrix were incorporated with Fullerene (FNS), TiC and Ni-coated graphene (NG) reinforcements to form composite solders through powder metallurgical method. These composite solders were then characterised in terms of their microstructure, physical property, solderability, followed by a systematic investigation of their performance under isothermal ageing, current stressing and large thermal gradient, respectively. The results showed that three types of reinforcements were successfully incorporated into the solder matrix; with all reinforcements added being embedded in the solder matrix or around the intermetallic compounds (IMC). The average loss of FNS and TiC particles in the solders was approximately 80% after the initial reflow, while this was only 40% for NG particles. It has been observed that β-Sn and Ag3Sn in the SAC solder alloys can be refined by adding appropriate amount of FNS and TiC, which is beneficial to the wettability with a reduced coefficient of thermal expansion (CTE) with the minimal influence on the melting point and electrical resistivity of solder alloys. For the SAC alloys without reinforcements, obvious extrusion of interfacial IMC at the anode was present after 360 hours of current (1.5×104 A/cm2) stressing, while the changes of surface profiles of all reinforced solders were unnoticeable. Under the current stressing regimes, a continuous increase of interfacial IMCs at the anode of the original SAC alloys was observed, but decreased at the cathode with stressing time. For the composite solders, both anode and cathode showed a continuous growth of interfacial IMCs; the growth rates of IMCs at the anode were greater than that at cathode. In addition, NG and TiC were found to be most effective to retard the growth of Cu3Sn IMC under current stressing. A gradient in hardness across the stressed SAC joints was present, where it was harder at anode. However, no such obvious gradient was found in SAC/FNS and SAC/NG solder joints. FNS and NG were proven to be beneficial to prolong the service life of solder joints up to approximately 7.6% and 10.4% improvements, respectively. Thermal stressing made the interfacial IMC in the original SAC joints to grow at the cold end considerably; causing serious damage at the hot end after 600 hours under temperature gradient of 1240K/cm stressing; a large number of IMCs, cracks and voids appeared in the SAC solder joints. However, a uniform increase of IMCs at both sides in the composite solders was observed without apparent damages at the interfaces under the same thermal stressing conditions, indicating an effective reduction of the elemental migration in the reinforced solders. Although there were also some voids and IMCs formed in the composite solder joints after a long-term thermal stressing, the integrity of the composite solder joints was enhanced compared with the SAC alloys. During thermal stressing, the dissolution rate of Cu atom into the SAC solder joints was estimated to be 3.1×10-6 g/h, while the values for SAC/FNS, SAC/NG and SAC/TiC were only 1.22×10-6 g/h, 1.09×10-6 g/h and 1.67×10-6 g/h, respectively

Controlling tin nucleation and grain orientations in Pb-free solders

Lead-free solder joints made with Sn-Ag-Cu or Sn-Ag solders usually contain only a single βSn grain or three twinned βSn grains which are oriented differently in every joint. Due to the anisotropy of βSn every joint therefore has unique thermomechanical properties and, in an array of numerous joints, it is likely that some will be poorly oriented and could cause early failure of a component. The problems of few grains with variable orientation can be attributed to the nucleation of βSn. This thesis explores catalyzing βSn nucleation using heterogeneous nucleation and develops methods to control βSn microstructures and orientations in Sn-3Ag-0.5Cu/Cu solder joints. The developed droplet nucleation technique in this study provides a new ‘motorway’ for heterogeneous nucleation study, and the introduced orientation control method paves the way to solve chronic problems, such as electromigration, thermomechanical fatigue, and shear fatigue in the electronic packaging industry. It is found that Co additions and Co substrates are effective at catalyzing βSn nucleation. This is demonstrated to be due to heterogeneous nucleation on αCoSn3 crystals. By using a ‘droplet nucleation technique’, in which Sn droplets are solidified directly on an intermetallic compound (IMC) particle, it is proved that αCoSn3 forms a reproducible orientation relationship (OR) with βSn that has a good lattice match. Strong grain refinement occurred in 60g Co-microalloyed Sn-3.0Ag-0.5Cu samples but only weak grain refinement occurred in 550μm solder balls and joints. When soldering Sn-3.0Ag-0.5Cu on Co substrates, βSn is always observed to grow from the interfacial αCoSn3 layer with an orientation inherited from the αCoSn3 layer texture. However, it is shown that nucleation on the αCoSn3 layer does not give useful βSn orientation control. The droplet nucleation technique was then applied to gain a deeper understanding of βSn nucleation on a range of IMC phases. A family of transition metal stannides, PtSn4, PdSn4, and βIrSn4 that have similar crystal structures to αCoSn3, were identified as potent nucleants for βSn. The common solder IMCs, Cu6Sn5, Ag3Sn, Ni3Sn4, were also investigated. It was found that reproducible ORs formed on all IMCs studied and the nucleation mechanisms were explored by combining nucleation undercooling measurements with measured ORs. The nucleation potency of all studied intermetallics is: αCoSn3>βIrSn4 >PdSn4>PtSn4 >Ni3Sn4> Ag3Sn, Cu6Sn5. The droplet nucleation technique also generated new insights into solidification twinning in solder joints. It was found that cyclic twins formed in droplets when the undercooling was sufficiently high and the liquid contained Ag, Cu and/or Ni. Complex interrelated cyclic twins were found in droplets on Cu6Sn5, Ag3Sn, and Ni3Sn4 where up to five rings of cyclic twins formed each related by a common . The twinning mechanisms in these cases were explored and discussed. The thesis then applies the new understanding developed in the previous chapters to develop a technique to reliably control the orientation of βSn in solder joints. Ball grid array (BGA) joints were fabricated reproducibly by introducing an extra step into the manufacturing process: bonding a nucleant IMC ‘seed crystal’ onto each Cu pad so as to control the nucleation location, nucleation undercooling and crystallographic orientation of βSn at the moment of nucleation. Each joint made by this technique had a uniform single-grain microstructure with the c-axis of βSn parallel with the substrate plane. This orientation is reported in the literature to give the best resistance to electromigration and shear fatigue.Open Acces

Micromechanical Behaviour of Lead-free Solder Joints Developed for 3D-IC Packaging Applications

Ph.DDOCTOR OF PHILOSOPH

Numerical analysis of lead-free solder joints: effects of thermal cycling and electromigration

To meet the requirements of miniaturization and multifunction in microelectronics, understanding of their reliability and performance has become an important research subject in order to characterise electronics served under various loadings. Along with the demands of the increasing miniaturization of electronic devices, various properties and the relevant thermo-mechanical-electrical response of the lead-free solder joints to thermal cycling and electro-migration become the critical factors, which affect the service life of microelectronics in different applications. However, due to the size and structure of solder interconnects in microelectronics, traditional methods based on experiments are not applicable in the evaluation of their reliability under complex joint loadings. This thesis presents an investigation, which is based on finite-element method, into the performance of lead-free solder interconnects under thermal fatigue and electro-migration, specifically in the areas as follows: (1) the investigation of thermal-mechanical performance and fatigue-life prediction of flip-chip package under different sizes to achieve a further understanding of IMC layer and size effects of a flip chip package under thermal cycling; (2) the establishment of a numerical method, simulating void-formation/crack-propagation based on the results of finite-element analysis, to allow the prediction of crack evolution and failure time for electro-migration reliability of solder bumps; (3) the establishment of a flow-based algorithm for combination effects of thermal-mechanical and electro-migration that was subsequent implemented in to an FE model to evaluate the reliability assessment of service lives associated with a flip chip package